Korea Kumho Petrochemical Co., Ltd.

Jee-Hwan Jang

Hyun-Kyung Sung

Sang-Hyo Ryu

Yevgen Barsukov

Ho-Sull Lee

Hun-Jong Baik

A method for selecting unit cells to make an optimal battery pack improves the performance of the battery pack with primary or secondary batteries connected to one another in series, in parallel, or in a combination of them. The method for selecting unit cells to make the optimal battery pack includes measuring the impedance spectrum of the individual unit cells in a predetermined frequency region, fitting the impedance spectrum to an equivalent circuit model composed of parameters including resistance and capacitance components, calculating total resistances from the fitted parameters, and making the battery pack with unit cells of a similar total resistance.

Method of grouping single cells of power sources to build optimal packs using parameters obtained by analysis of impedance spectrum

The present invention relates to a method for evaluating the crosslink degree of a vulcanized sample in real time during a vulcanization process or diagnosing the electrical properties of the sample after the completion of the vulcanization process, and then determining an optimal vulcanization time and an optimal content of each constituent gradient of a composition for vulcanization that optimize the properties of the composition according to the vulcanization conditions, for the sake of improving the properties of the vulcanized sample prepared from a polymer by vulcanization at a high temperature. The method for determining an optimal vulcanization time and an optimal content of each constituent gradient of a composition for vulcanization that optimize the properties of the composition according to the vulcanization conditions includes: (a) measuring an impedance spectrum in a specific frequency range in the individual vulcanization condition; (b) approximating the measured impedance spectrum to an equivalent circuit model consisting of resistance and capacitance components; (c) determining a polymer resistance Rp (i.e., a value obtained by subtracting a real part of the impedance measurement at a maximum frequency from a real part of the impedance measurement at a minimum frequency, or the magnitude of a real part of the semicircle in a Nyquist diagram) from the determined parameters; (d) determining, as an optimal end point of vulcanization, a time point at which the increasing rate of the polymer resistance Rp rapidly slows down; and (e) determining the optimal content of each constituent ingredient of the composition for vulcanization when the polymer resistance Rp of the sample completely vulcanized is at its minimum.

Method for determining optimal degree of vulcanization and optimal content of constituent ingredient of composition for vulcanization in real time by impedance measurement and analysis

A method for grouping unit cells of a similar impedance spectrum uses pattern matching technology to optimize the performance of a battery pack made of primary or secondary batteries as the unit cells connected in series, in parallel or in combination of them. To make an optimal battery pack with unit cells of a different internal characteristic, the method includes measuring the impedance spectrum of the individual unit cell in a wide frequency region at the same temperature and in the same state of charge (SOC), digitizing the difference in impedance spectrum among the unit cells into a relative value using the pattern matching technology, and selecting unit cells of a most similar impedance spectrum (i.e., a smallest relative difference in impedance spectrum) to make a battery pack.

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Daejeon, South Korea

Jee-Hwan Jang