Monsanto Company

Metabolix, Inc.

General Electric Company

Jean R Pierre

Jawed Asrar

Pol D'Haene

Peter H Th Vollenberg

PHA pellet compositions are provided which are processible into blown and cast free-standing films. The Mw of the PHA in the pellets used to produce the films is at least 470,000, at least 435,000 if PHA thermal stabilizers of the invention are used. In order to achieve a stable, unsupported film having desirable elongational and tensile properties, the Mw of PHA in the film is greater than about 420,000.

PHA compositions and methods for their use in the production of PHA films

Biodegradable polymer blend compositions are provided which contain oligomeric esters. The oligoester compound can compatibilize blends of two or more biodegradable polymers resulting in excellent ductility and reduced tendency to embrittlement of products produced from therefrom. In a preferred embodiment of the invention, the blend composition comprises a PHA, polycaprolactone (PCL) and one or more oligomeric esters. In another preferred embodiment of the invention, the blend composition comprises a PHA, polybutylenesuccinate-adipate (PBSUA), and one or more oligomeric esters.

Polymer blends containing polyhydroxyalkanoates and compositions with good retention of elongation

Disclosed herein is a UV stabilized composition, comprising a polyester resin and a polycarbonate resin; an impact modifier; and an additive composition comprising a hindered amine light stabilizer and another UV absorber. Such compositions find utility in the manufacture of automobile components, for example.

UV stabilized, impact modified polyester/polycarbonate blends, articles, and methods of manufacture thereof

Biodegradable polymer blend compositions are provided which contain oligomeric esters. The oligoester compounds can compatibilize blends of two or more biodegradable polymers resulting in excellent ductility and reduced tendency to embrittlement of products produced from therefrom. In a preferred embodiment of the invention, the blend composition comprises a PHA, polycaprolactone (PCL) and one or more oligomeric esters. In another preferred embodiment of the invention, the blend composition comprises a PHA, polybutylenesuccinate-adipate (PBSUA), and one or more oligomeric esters.

Plasticized PHA pellet compositions are provided which are processible into shaped objects, particularly blown and cast free-standing films. The Mw of the PHA in the pellets used to produce the films is at least 470,000, at least 435,000 if PHA thermal stabilizers of the invention are used.

Plasticized polyhydroxyalkanoate compositions and methods for their use

Methods of making PHA coating compositions having molecular weights greater than about 125,000 are provided. The PHA coating compositions derived therefrom have improved properties suitable for applications in which excellent heat sealability and moisture resistance is desired.

Polyhydroxyalkanoate coatings

A nucleant system for polyhydroxyalkanoates and other thermoplastic polyesters comprises a class of organophosphorous compounds having at least two phosphonic acid moieties. The compounds can be used to effectively increase polymer crystallization rates and result in desirable properties in polymer-derived articles of manufacture, particularly when used in combination with effective nucleating agent solvents, organic metal salts, inorganic metal oxides, metal hydroxides or metal carbonates, and/or weak organic bases.

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St-Denis, Belgium

Jean R Pierre