Institut Francais Du Pe'trole

Rhone-poulenc Industries

Elf France

Institute Francais Du Petrole

Institut Francais Du Petrole, Des Carburants Et Lubrifiants Et

Elf-union

Institut Francais Du Petrole, Des Carburants Et Lubrifiants

Institut Francais Du Petrole, Et L'entreprise De Recherches Et

Jean-Pierre Durand

Francois Dawans

Patrick Gateau

Marie Velly

Daniel Binet

Anne Sinquin

Michel Thomas

Jacques Jarrin

Magali Robine

Anne-Sophie Delion

Alexandre Rojey

Andre Sugier

Bernard Chauvel

Gilbert Chapelet

Denise Nicolas

Bernard Aubin

Maurice Born

Paul Maldonado

Gerard Hillion

Bernard Damin

Guy Parc

Olivier Clause

G&eacute;rard Hotier

Norbert Kohler

Jean-Fran&ccedil;ois Argillier

Sophie Jullian

Annie Audibert-Hayet

Fabrice Paille

Emmanuel Goldenberg

Alain Faure

Eric Robert

Francoise Candau

Karine Ragil

Paul Bourgmayer

Claude Gatellier

Roger Bregent

V&eacute;ronique Ruffier-Meray

Catherine Keromest

Baley: Anne-Sophie

Anne-Sophie Baley

B&eacute;atrice Cingotti

V&eacute;ronique Meyer

Nicole Petroff

Andree Plessis

Ernest Mar/e/ Chal

Maryvonne Brigodiot

Robert L/e/ Ger

In order to improve the transport of oilfield effluents comprising water, a gas and possibly a liquid hydrocarbon phase under thermodynamic conditions which can lead to the formation of hydrates, a formulation containing at least two additives, one of which behaves as a hydrate crystal nucleation agent, is added to the effluent to be transported.

Additive formulation for improving transport of oilfield effluents which may contain hydrates, and a process using this formulation

The invention provides a high octane number gasoline pool comprises at least 2% of di-branched paraffins containing 7 carbon atoms, and a process for producing this gasoline pool by hydro-isomerizing a feed constituted by a C5 to C8 cut which comprises at least one hydro-isomerization section and at least one separation section, in which the hydro-isomerization section and at least one separation section, in which the hydro-isomerization section comprises at least one reactor. The separation section comprises at least one unit and produces at least two streams: a first stream which is rich in di- and tri-branched paraffins, and possibly in naphthenes and aromatic compounds which is sent to the gasoline pool; and in a first version of the process, a second stream is produced which is rich in straight-chain and mono-branched paraffins which is recycled to the inlet of the hydro-isomerization section, while in a second version of the process, a second flux is produced which is rich in straight-chain paraffins which is recycled to the inlet of a first hydro-isomerization section and a third stream is produced which is rich in mono-branched paraffins which is recycled to the inlet of a second hydroisomerization section.

High octane number gasolines and their production using a process associating hydro-isomerization and separation

Hydrosoluble copolymers made of hydrophilic monomers, e.g., acrylamide, and of silane or siloxane derivative-based hydrophobic monomers, e.g., a silane or or siloxane acrylate, is obtained by micellar or heterogeneous radical copolymerization, and such copolymers can be used as rheology control agents in, e.g., a well bore.

Hydrosoluble silane or siloxane derivative-based copolymer

Integrated analysis process and device for characterization of hydrocarbons in a petroleum product, in distillation fractions, by simulated distillation. The hydrocarbons of a petroleum sample are characterized without fractional distillation by coupling gas chromatography (GC) with liquid chromatography (LC) techniques. GC simulated distillation (SD) is carried out. The separation column is preceded by a precolumn of the same nature but shorter. At the outlet of the main column, retention means (CT, AC) allow to collect and to store one or more light fractions that are sent each to a GC analytical column (,) allowing detailed analysis of the hydrocarbons, and one or more middle fractions. The remaining heavy fraction is collected at the precolumn outlet. The middle and heavy fractions are characterized by a combined LC-GC chromatography unit. Several interfaces allowing GC-GC-LC-GC coupling are described. The process and device can be applied for characterization of reservoir fluids or of refining process effluents for example.

Integrated analysis process and device for hydrocarbon characterization by distillation simulation

A process for slowing the growth and/or agglomeration of hydrates in a fluid comprising water and gases by adding at least one essentially water-soluble polyoxyalkylene glycol macromer or at least one essentially water-soluble polymer containing a single macromer or a plurality of different macromer units of polyoxyalkylene glycol or a mixture of essentially water-soluble macromers and/or polymacromers. It is also possible to both retard the formation of hydrates and to substantially slow their growth and limit their agglomeration during crystallization by combining polyoxyalkylene glycol macromer type structures with kinetic additive type structures which are known to inhibit hydrate formation.

Process for slowing the growth and/or agglomeration and possibly

The inhibiting or retarding hydrate formation, growth and/or agglomeration in a fluid comprising water and gases, is accomplished by addition of at least one hydrosoluble homopolymer or copolymer derived from at least one nitrogen-containing monomer selected from cationic monomers, for example those containing at least one quaternary ammonium moiety, amphoteric monomers, for example those containing at least one quaternary ammonium moiety and at least one carboxylate or sulphonate moiety, and various neutral monomers, said hydrosoluble homopolymer or copolymer being neutral or anionic, or consisting of a polyampholyte. The homopolymer, copolymer or mixture of polymers optionally mixed with an alcohol is generally incorporated into the fluid to be treated at a concentration of 0.05% to 5% by weight with respect to the quantity of water in the medium.

Method for inhibiting or retarding hydrate formation or agglomeration in

A method of transporting hydrates suspended in a fluid comprising water, a gas and a liquid hydrocarbon is described in which at least one non-ionic amphiphilic composition obtained by reacting at least one polymerized unsaturated vegetable oil with an aminoalcohol is incorporated into the fluid. The non-ionic amphiphilic composition is generally introduced in a concentration of 0.1% to 5% by weight with respect to the water.

Method of transporting hydrates suspended in production effluents

A process for transporting a fluid in a pipe under conditions where hydrates may form. In the process, the pipe fluid contains at least one of a gaseous hydrocarbon or liquid hydrocarbon and water and the water content is less than the liquid hydrocarbon content. The process includes the steps of 1) adding a dispersive additive in a hydrocarbon solution to the fluid to be transported, so as to form an emulsion, 2) transporting the liquid and gaseous hydrocarbons in the presence of water and the hydrates, 3) separating the gas phase, the hydrocarbon liquid in excess and a liquid hydrocarbon phase comprising the hydrates and the dispersing additive, and 4) separating the liquid hydrocarbon phase comprising the hydrates and the dispersing additives. The liquid hydrocarbon phase comprising the hydrates is separated by dissociating the hydrates to form a water-in-oil emulsion, the additives being solved in the oil or liquid hydrocarbon, and breaking the water-in-oil emulsion so as to obtain an aqueous phase and a liquid hydrocarbon comprising the additives. Finally the liquid hydrocarbon phase containing at least part of the dispersing additive from step 4, is recycled to a point in the pipe.

Process for recycling a dispersing additive used for the transportation

The invention concerns a process for reducing the tendency of hydrates in a fluid comprising at least water, a gas and a paraffin oil to agglomerate, by addition of a mixture of at least two organosoluble additives, namely at least one polyisobutene-polyethyleneglycol block copolymer and at least one copolymer of an alkyl (meth)acrylate and a nitrogen-containing monomer. These organosoluble copolymers are generally introduced at an overall concentration of 0.05% to 5% by weight with respect to the water present in the medium.

Process for reducing the tendency of hydrates to agglomerate in

Process for transporting gas hydrates formed from a natural gas or from a condensate gas, consisting in using a dispersing additive, possibly coupled with a film-forming additive, in solution in a liquid hydrocarbon fraction, this liquid hydrocarbon fraction participating in the formation of an emulsion and/or of a suspension with the condensation water produced and the hydrates. The dispersing additive is recycled after the transportation of the hydrates in the pipe.

Process for transporting a fluid such as a dry gas likely to form

The invention concerns a process for inhibiting or retarding hydrate formation, growth and/or agglomeration in a fluid comprising water and gases, by addition of a hydrosoluble copolymer which does not contain a heterocycle but contains at least one sulphonate group. The copolymer is generally introduced at a concentration of 0.05% to 5% by weight with respect to the quantity of water in the medium. The copolymer can also be mixed with an alcohol (monoalcohol or polyol). In this case, the proportions are generally 0.5% to 20% by weight of alcohol with respect to the water content, for 0.05% to 3% by weight of copolymer with respect to the quantity of water content of the medium.

Method for inhibiting or retarding hydrate formation, growth and/or

An alkenyl anhydride or polyalkenylsuccinic anhydride is prepared without forming resins, by an ene-synthesis reaction between an olefin or a polyolefin and a maleic anhydride, optionally substituted by one or two methyl groups, in an aromatic solvent that is selected from toluene and xylenes, whereby said anhydride is used at a ratio of 30 to 60% by weight relative to the reaction medium. More particularly, polyisobutenylsuccinic anhydrides which can be used to form, by reaction with polyethylene polyamines, compositions that contain polyisobutenylsuccinimides, used as detergent additives for motor fuels or as ashless dispersants for motor oils, are produced.

Process for production of polyisobutenylsuccinic anhydrides without

A simplified process for preparation of an alkenylsuccinimide or a polyalkenylsuccinimide is described, characterized in that it comprises successively: a stage (a) in which an alkenylsuccinic anhydride or a polyalkenylsuccinic anhydride is prepared by bringing about an ene-synthesis reaction between at least one olefin or one polyolefin and at least one unsaturated dicarboxylic anhydride that is selected from maleic anhydride and the maleic anhydrides that are substituted by 1 or 2 methyl groups, characterized in that said reaction is carried out within at least one aromatic solvent that is selected from toluene and the xylenes that are used at a ratio of between 30 to 70% by weight of the reaction mixture and in which a fraction of said unsaturated dicarboxylic anhydride does not react with said olefin or polyolefin; a stage (b) in which the product of stage (a) that contains unsaturated, unreacted dicarboxylic anhydride is reacted with at least one alcohol or an amine; and a stage (c) in which the product that is obtained in stage (b) is reacted with an amine. These succinimides can be used as detergent additives for engine fuels and as ashless dispersing additives for engine lubricants.

Simplified process for production of alkenylsuccinimides or

Chlorine-free polyfunctional polyisobutenes are described that can be modified by amines, alcohols and/or amino alcohols to result in additives that can be used in the petroleum field in particular in fuels and engine lubricants. They are prepared by radical terpolymerization of isobutene, maleic anhydride and polyisobutene having an average content of 'exo' end double bonds of at least 50%.

Polyfunctional polyisobutenes, their preparation, their formulation and

The invention relates to a process for reducing the agglomeration tendency of hydrates within a fluid containing water and gas by adding a nonionic, amphiphilic compound obtained by reacting at least one polyalkenylsuccinic anhydride or acid with a polyethylene glycol monoether. The nonionic, amphiphilic compound is generally introduced in a concentration of 0.1 to 5% by weight, based on the water present.

Method for reducing the agglomeration tendency of hydrates in production

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Chatou, France

Jean-Pierre Durand