L'air Liquide,societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude

Jean-Philippe Tadiello

Taekyu Kang

Yue Chen

Thomas Wenz

Daniel Gary

Marie Basin

Dieter Ulber

Laurent Prost

Diana Tudorache

Nga Thi Quynh Do

Chen Yue

The invention relates to an electrolysis arrangement for the electrochemical production of hydrogen and oxygen from an alkaline electrolyte having anode and cathode separators for the separation of oxygen and hydrogen from the electrolyte, and an anode and cathode pipe system to circulate electrolyte between anode and cathode sections of an electrolysis stack of the electrolysis arrangement. Control valves and interconnections are configured so that dependent on an electrolyte flow rate passing first, second and third control valve, oxygen and hydrogen depleted electrolyte withdrawn from the separators can be supplied unmixed, partly mixed or fully mixed to the anode and cathode sections of the electrolysis stack to control hydrogen to oxygen and oxygen to hydrogen crossover in the electrolysis arrangement.

Electrolysis arrangement for alkaline electrolysis

The invention relates to a furnace for performing an endothermic process, the furnace including a plurality of process tubes containing a catalyst for converting a gaseous feed, wherein the process tubes are arranged in rows within the furnace, each row of process tubes thereby defining a process tube row, a plurality of inner burners arranged in rows, each row of inner burners being arranged between and parallel to process tube rows, thereby defining an inner burner row, and a plurality of outer burners arranged in rows, each row of outer burners being arranged between and parallel to a process tube row and a furnace wall, thereby defining an outer burner row. A number of burners of an outer burner row is smaller than a number of burners of an inner burner row. The invention also relates to a process for operating a furnace for performing an endothermic process.

Furnace for endothermic process and process for operating a furnace with improved burner arrangement

A plant for producing a synthesis gas chiefly consisting of hydrogen and carbon monoxide by catalytic steam reformation of a hydrocarbonaceous feed gas, wherein the heat of burners required for the chemical reforming reactions to take place is generated by producing a flue gas and wherein, by utilizing the heat contained in the synthesis gas and in the flue gas, a pure steam is generated from boiler feed water and a process steam is generated from process condensate, wherein for the generation of the pure steam synthesis gas and flue gas are used and for the generation of the process steam a part of the pure steam is used as heat-transfer medium and the remaining part of the pure steam is discharged from the process as export steam.

Process and plant for the production of synthesis gas by means of catalytic steam reformation of a hydrocarbonaceous feed gas

The invention relates to an inertization apparatus for inerting a working volume in a chemical production plant by flushing with inert gas, where the chemical production plant comprises a plant-wide inert gas distribution system having pipes for distributing the inert gas and at least one inert gas offtake position which can be connected to a connecting conduit. According to the invention, it is provided that the connecting conduit between inertization apparatus and working volume is connected, at its end nearest the working volume, in a not reversibly detachable manner to an intermediate piece, where the intermediate piece can be connected in a reversibly detachable manner to a counterpiece provided on the working volume.

Safe inertization apparatus

The invention relates to a process for producing hydrogen from a light hydrocarbon source, in which a synthesis gas is generated by steam methane reforming after desulfurization and optionally pre-reforming of the feedstock. The synthesis gas is enriched with hydrogen by steam conversion of carbon monoxide, and is subsequently purified in a pressure swing adsorption unit to give a pure Hproduct and a residual gas mixture containing CH, CO, Hand CO; in accordance with the invention, the conversion step is performed in a cooled reactor in which the heat of the conversion reaction is transferred to a fluid which feeds the burners of the reformer, or to the gas for reforming.

Process for producing hydrogen by steam reforming and conversion of co

Proposed is a process and a plant for production of pure carbon monoxide and hydrogen by steam reforming of hydrocarbons, preferably methane or naphtha, to afford a raw synthesis gas and subsequent, multistage workup, purification and fractionation of the raw synthesis gas to afford the target products, wherein the material streams obtained as by-products of the process chain are also to be advantageously utilized. This is achieved according to the invention by providing the recirculating compressor provided for recycling of the by-product material streams with a plurality of parallel, independently operable compressor stages.

Process and plant for production of pure carbon monoxide and hydrogen

A reformer tube for producing synthesis gas by steam reforming of hydrocarbon-containing feed gases, in which a structured stream reforming catalyst is used, is proposed. According to the invention, a heat exchanger tube is arranged in the interior of the structured catalyst, with the feed gas stream flowing firstly through the structured catalyst and subsequently in countercurrent through the heat exchanger tube. This improves the heat exchange between the synthesis gas product stream and the structured catalyst and the feed gas stream flowing through it, especially in the radial direction.

Reformer tube having a structured catalyst and improved heat balance

Plant and process for the generation of hydrogen from a hydrocarbonaceous feed gas and steam by means of catalytic steam reformation, wherein the heat of the synthesis gas and the flue gas is utilized for generating export steam from boiler feed water and process steam from the condensate separated from the synthesis gas, and wherein the gases expelled from the boiler feed water during its degasification and the vapors obtained during the depressurization of the elutriation waters of the steam boilers for the generation of export and process steam are used for preheating the fuel gas for operation of the burners of the steam reformer.

Process and plant for producing hydrogen by means of catalytic steam reformation of a hydrocarbonaceous feed gas

A process and plant for producing a synthesis gas chiefly consisting of hydrogen and carbon monoxide by catalytic steam reformation of a hydrocarbonaceous feed gas, wherein the heat of burners required for the chemical reforming reactions to take place is generated by producing a flue gas and wherein, by utilizing the heat contained in the synthesis gas and in the flue gas, a pure steam is generated from boiler feed water and a process steam is generated from process condensate, wherein for the generation of the pure steam synthesis gas and flue gas are used and for the generation of the process steam a part of the pure steam is used as heat-transfer medium and the remaining part of the pure steam is discharged from the process as export steam.

A process and a plant for cooling a synthesis gas produced by catalytic steam reformation of a hydrocarbonaceous feed gas, which is cooled by heat exchange with boiler feed water for its conversion into steam, by separating the resulting aqueous condensate, wherein the further cooling is effected in that the gas passes through several series-connected cooling stages and comprises the heat exchange with the feed gas, with degassed and non-degassed boiler feed water for generating the steam required for the steam reformation, and with ambient air, and wherein condensate obtained after the last cooling stage is separated from the gas and the gas is discharged for the further treatment, wherein at least after a further cooling stage upstream of the last cooling stage a hot aqueous condensate is separated from the gas.

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Frankfurt am Main, Germany

Jean-Philippe Tadiello