Colgate Palmolive Company

Jean-Paul M Grandmaire

Anita Hermosilla

Viviane E Tack

Alain Jacques

Eduardo E Puentes-Bravo

Subhash Harmalker

Marcel J Gillis

Pierre M Lambert

Paul A Heckles

Jan R Doms

Amjad Farooq

Leopold Laitem

Myriam Peeters

Nunzio Mineo

Norman Blumenkopf

Jacques Jacques

Anita Hermosilla M

Anita M Hertmosilla

Doris More

Leopld Laitem

Provided are oligomeric amidoamines, an oligomeric amidoamine salt of the oligomeric amidoamine, and/or an oligomeric amidoquat of the oligomeric amidoamine. These materials can be used as fabric softeners in fabric softener compositions or as a hair treatment in hair treatment compositions.

Oligomeric amidoamines or amidoquats for fabric or hair treatment compositions

The application relates to a medium viscosity, clear fabric softening composition, comprising

Aqueous composition comprising oligomeric esterquats

The application relates to a low viscosity and to a stable fabric softening composition process for the preparation of a stable, and particularly to a viscosity stable, fabric softening composition having a low viscosity, said composition comprising from about 1 to 18 wt. % of an oligomeric esteramine or oligomeric esterquat, obtainable by reaction of an alkanol amine with a polycarboxylic acid and with a fatty alcohol and optionally a fatty acid, optionally followed by quaternization. The process comprises melting said oligomeric esteramine or oligomeric esterquat, dispersing said melted material in hot water, and subsequently cooling. In a second aspect, the application relates to a process wherein a thickening agent or mixture of thickening agents is added to the hot water containing the melted material or after the hot water has cooled. This thickening agent is selected from the group consisting of modified cellulosic polymer, non-ionic viscosity modifier, associative thickener and polyacrylate.

Multi-phase clear fabric softening composition

Clear fabric softener microemulsion compositions have been developed for use in the rinse cycle comprising a combination of diester quaternary ammonium surfactants, diamido ammonium surfactants and selected organic solvents. Fatty co-softeners and oil perfumes may be included as optional ingredients. These microemulsions are converted to macroemulsions upon dilution with water in the rinse cycle to provide a fabric softening treatment.

Clear, concentrated liquid fabric softener compositions

This invention relates to fabric conditioning compositions containing inorganic acid salts of defined amidoamine compounds in combination with a carboxylic acid, which compositions are characterized by superior environmental compatibility relative to conventional quaternary ammonium fabric softening compositions concomitant with providing improved calcium salt solubilization and reduction of encrustation on treated fabrics.

Liquid fabric conditioning composition containing amidoamine softening

A fabric softening product is a composition or article that is effective for its fabric softening purpose but preferably excludes ecotoxic quaternary ammonia salt, includes, as a fabric softening component, a PEC, which is an ester of pentaerythritol, an ester of an oligomer of pentaerythritol, an ester of a lower alkoxylated pentaerythritol or an ester of a lower alkoxylated pentaerythritol oligomer, with bentonite, which increases its fabric softening effect remarkably. The PEC is preferably a partial higher fatty acid ester of pentaerythritol or a partial higher fatty acid ester of a pentaerythritol oligomer, the bentonite is preferably sodium bentonite or swellable calcium bentonite, the fabric softening composition is a softergent or a non-detersive composition, both of which may be in solid (preferably particulate solid) or liquid state or form (preferably in aqueous suspension or gel), and the fabric softening article is an absorbent material with bentonite and PEC deposited on it or absorbed by it. Also within the invention are processes for softening fibrous materials of laundry contacting them with such compositions and/or articles during washing, rinsing and/or drying operations.

Fabric softening products based on a combination of pentaerythritol

A particulate fabric softening composition and a particulate fabric softening detergent composition are described, both of which include bentonite powder agglomerated into larger particulate bead or granule form with a normally solid co-melt of a pentaerythritol compound (PEC), such as pentaerythritol ditallowate (PEDT), and a nonionic surfactant, such as a condensation product of a mole of a C.sub.12-15 fatty alcohol with seven moles of ethylene oxide. The fabric softening composition described may be added to wash (or rinse water) but preferably is incorporated in a particulate built synthetic organic anionic and/or nonionic detergent composition to produce a fabric softening detergent composition. The invented detergent compositions are especially suitable for washing laundry in 'cold' water, such as water at 40.degree. C. or thereabout, in which the nonionic surfactant increases the dispersibility of the PEC, improves fabric softening activity thereof, in conjunction with the bentonite, and also prevents excessive whitening or chalking of dark colored laundry by the particulate fabric softening composition. These improved results have been attributed to the nonionic surfactant lowering the co-melt's melting point to about 40.degree. C. or lower, at which temperature the softening composition disperses satisfactorily in the wash water. Additional advantages of the invention are a bonus effect of the nonionic surfactant in increasing detergency of the detergent composition and wash water, and in allowing a decrease in PEC content of the softening and detergent compositions without loss of softening effect.

Particulate fabric softening and detergent compositions

A fabric softening composition or article that is effective for its fabric softening purpose but does not include ecotoxic quaternary ammonium salt, includes, as a fabric softening component, an ester of pentaerythritol, an ester of an oligomer of pentaerythritol, an ester of a lower alkoxylated pentaerythritol or an ester of a lower alkoxylated pentaerythritol oligomer. The fabric softening component is preferably a partial higher fatty acid ester of pentaerythritol or a partial higher fatty acid ester of a pentaerythritol oligomer, the fabric softening composition is an aqueous emulsion or a particulate or powder composition (preferably with the carrier of the powder composition being a fabric softening bentonite) and the fabric softening article is an absorbent material with fabric softening component deposited on it or absorbed by it. Also within the invention are processes for softening fibrous materials, in washed laundry, by employing such compositions and articles, and processes for manufacturing the compositions.

Biodegradable fabric softening compositions based on pentaerythritol

Environmentally compatible and biodegradable fabric conditioning compositions are provided having improved softening properties while providing significant reduction and solubilization of unwanted mineral encrustations on the fabrics to be softened. The compositions comprise mixtures of defined alkanolamine diesters and triesters in combination with at least one of certain organic acids such as citric acid.

Fabric conditioning composition containing alkanol amine ester and acid

Stable pourable aqueous fabric softening compositions based on quaternary ammonium softeners and siloxanes are provided. The softening component comprises from about 1-20% by weight of the composition. Methods for making the composition are also described. Softening performance is superior to that obtained by using quaternary ammonium compound softeners, alone or with other components absent the siloxane. The softener compositions are primarily intended for use in the rinse cycle of an automatic washing machine.

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Andrimont, Belgium

Jean-Paul M Grandmaire