Commissariat a L'energie Atomique

Compagnie Francaise De Raffinage

Jean-Marie Martinet

Michel Berardo

Pierre Bergez

Jean Charpin

Jean Maurin

Charles Darnez

Jean Rossarie

Gilbert Roche

Jean Arod

Bernard Bartoli

Philippe Caminade

Jean Biedermann

The invention relates to semipermeable organomineral membranes usable in reverse osmosis. This organomineral semipermeable membrane comprises a porous inorganic material support coated with a vinylidene fluoride polymer or copolymer-based organic layer incorporating functional groups giving the membrane a permeability to water or other solvents. The porous inorganic material support is preferably constituted by a macroporous substrate coated with a microporous layer, e.g. produced from a single or mixed metal oxide or hydroxide. The organic layer can be constituted by polyvinylidene fluoride grafted by an appropriate monomer, such as styrene incorporating functional groups giving it selective permeability, e.g. hydrophilic groups, such as sulphonic groups.

Organomineral semipermeable membrane and its production process

The invention relates to a process for the production of porous, permeable, mineral membranes. According to this process, on a porous, permeable substrate is formed a thin layer of at least one mineral compound chosen from among the simple or mixed metal oxides, except aluminum oxide and mixed aluminium oxides, simple or mixed metal hydroxides, except aluminium hydroxide and mixed aluminium hydroxides and mixtures thereof on the basis of a suspension in a liquid of colloidal or non-colloidal particles, said compound or a precursor thereof having particle sizes below 10 .mu.m. The suspension is kept in the finely divided state by the continuous application of energy to the reaction medium. The thus obtained membrane is dried and then annealed at a temperature between 400.degree. and 1100.degree. C. The use of a suspension of ultrafine colloidal or non-colloidal particles makes it possible to obviate the compression stage and obtain microporous layers with very small pore radii.

Process for the production of porous, permeable mineral membranes

The present invention relates to a process for the treatment of a hydrocarbon charge by high temperature ultrafiltration, said process comprising the steps of circulating said charge in a module comprising at least one mineral ultrafiltration barrier coated with a sensitive mineral layer of at least one metal oxide and of operating at a temperature higher than 100.degree. C. The barrier, which preferably has a ceramic or metallic support, is coated with a sensitive layer selected from the group comprising titanium dioxide, magnesium oxide, aluminium oxide, spinel MgAl.sub.2 O.sub.4, silica. The invention is applicable to the regeneration of a waste oil and to the reduction of the rate of asphaltenes in a hydrocarbon charge.

Process for the treatment of a hydrocarbon charge by high temperature

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Montelimar, France

Jean-Marie Martinet