Battelle Memorial Institute

Jean-Marie Fresnel

Augusto Porta

Antonin Kulhanek

Daniele Trosset

Method for preparing an aqueous treatment solution containing at least

Metal is electrodeposited on conductive granules in apparatus comprising a helical channel with a cathode at its radially outer side and an anode at its radially inner side. A suspension of the granules in an electrolysis solution is fed tangentially into an end of the channel so that the granules are urged by centrifugal force against the cathode and form a mass moving along the channel to its outlet. The emerging granules are separated from the used solution in a cyclone and the solution is recirculated along the axis of the helix.

Process for electro-depositing a metal on conducting granules

Heterogeneous enzymatic catalysis is carried out by means of an enzymatic electrode comprising an enzyme fixed to a solid, conductive support. To govern the reaction rate during continuous transformation of a substrate, the enzymatic activity is regulated by adjusting the potential of the enzyme support so as to transform the substrate at a given rate. The electrode is provided with a particulate enzymatic mass operatively associated with an inert working electrode for contact with this mass to thereby subject the particles thereof to the adjustable potential. Continuous movement of a liquid reaction system is produced so as to provide intimate contact thereof with each particle of the mass, which may be arranged as a fixed bed, an agitated bed or a fluidized bed. The potential of the enzyme support is caused to continually alternate between two levels while adjusting the mean value thereof so as to maintain a corresponding mean enzymatic activity for transforming the substrate at the desired rate.

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Haut-Thoiry, France

Jean-Marie Fresnel