Eastman-Kodak Company

Jean Marie Buongiorne

Michael John Haight

Mary Ellen Craver

Charles M Darmon

Sheridan E Vincent

Ramanuj Goswami

Paul A Schwartz

Charles S Christ, Jr

Barry C Kocher

Erika S McLarney

Stephen J Waffle

Alan S Fitterman

Hugh G McGuckin

Janet M Huston

John S Badger

Valerie Lynn Kuykendall

Richard Thomas Clark

Stable, single-part photographic bleach-fixing &ldquo;precursor&rdquo; compositions comprise one or more iron-ligand complexes, one or more thiosulfates as the sole fixing agents, and optionally, a sulfite preservative. At least 50 mol % of the iron in the composition is in the form of Fe(II). This composition can be used directly in photoprocessing, or used as a regenerator when mixed with bleach-fixing overflow to provide a replenishing solution. Because the Fe(II) compounds are precursor bleaching agents, they must be oxidized to Fe(III) for active bleaching prior to or during the photographic processing operations.

Ferrous photographic bleach-fixing precursor compositions and methods for their use

Concentrated photographic fixer additive and fixing compositions and method of photographic processing

Concentrated photographic color developing composition containing stain reducing agent

A ferric-EDTA bleach regenerator composition can be mixed with bleach overflow to provide a bleach replenisher for reversal color silver halide photographic processes. The bleach regenerator composition has a critically controlled pH between about 6.0 and about 6.5, and comprises a total bromide ion concentration of at least about 210 g/l, and ferric ion in an amount of at least about 50 g/l. At least 50% of the bleach overflow and the bleach regenerator composition are mixed in at least a 1:1 volume ratio. After pH adjustment to from about 5.4 to about 5.6, the pH adjusted replenisher is supplied to the bleach tank for use in the process.

Bleach regenerator composition and its use to process reversal color photographic elements

A multi-part color developing kit includes at least two parts (or solutions) of photochemical compositions that can be mixed to provide a color developing composition useful for obtaining color photographic images. A first aqueous solution is formulated with a color developing agent in free base form, an antioxidant for the color developing agent, an inorganic base, a triazinylstilbene optical brightening agent, an chemical base and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent. A second aqueous solution is formulated with a buffering agent, the same or different chemical base and a phosphonic acid metal ion sequestering agent. Both solutions have a pH and homogeneity to provide a clear color developing composition that is safer for use and disposal.

Multi-part photographic color developing composition and methods of manufacture and use

A homogeneous, ready to use, single-part color developing concentrate comprises a color developing agent in free base form, an antioxidant for the color developing agent, a buffering agent, and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent present in an a concentration such that the weight ratio of water to the organic solvent is from about 15:85 to about 50:50. In addition the concentrate includes a mixture of a specific polyaminopolyphosphonic acid and either a hydroxyalkylidene-diphosphonic acid or morpholinomethanediphosphonic acid (or salt thereof) for stability in the presence of calcium ions. This concentrate is prepared by mixing the components in a unique order for improved safety and manufacturability. It can be used to make a working strength processing solution, or it can be used as a replenishing composition with proper dilution to provide color images in photographic silver halide materials.

Calcium ion stable photographic color developing concentrate and method of manufacture

Solublized 2,6-dinaphthylaminotriazines

A homogeneous color developing concentrate comprises a color developing agent in free base form, an antioxidant for the color developing agent and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent. This concentrate is prepared in a unique manner, namely by combining the noted components and removing the sulfate anions commonly present in color developing agents by precipitation with alkali metal ions. The concentrate can be used to prepare photographic processing concentrates and working strength solutions.

Homogeneous photographic color developing concentrate

A homogeneous, ready to use, single-part color developing concentrate comprises a color developing agent in free base form, an antioxidant for the color developing agent, a buffering agent, and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent present in an a concentration such that the weight ratio of water to the organic solvent is from about 15:85 to about 50:50. In addition the concentrate includes a mixture of a specific polyaminopolyphosphonic acid and either a hydroxyalkylidenediphosphonic acid or morpholinomethanediphosphonic acid (or salt thereof) for stability in the presence of calcium ions. This concentrate is prepared by mixing the components in a unique order for improved safety and manufacturability. It can be used to make a working strength processing solution, or it can be used as a replenishing composition with proper dilution to provide color images in photographic silver halide materials.

Calcium ion stable photographic color developing concentrate and method

Multi-part photographic color developing composition and methods of

An aqueous, homogeneous, single-part color developing concentrate comprises a color developing agent in free base form, an antioxidant for the color developing agent, a buffering agent, and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent present in an a concentration such that the weight ratio of water to the organic solvent is from about 15:85 to about 50:50. This composition is prepared in a unique manner, namely by combining the noted components, and removing the sulfate anions commonly present in color developing agents by precipitation with alkali metal ions, before addition of further components. The concentrate can be used to make a working strength processing solution, or it can be used as a replenishing composition with proper dilution.

Homogeneous single-part photographic color developing concentrate and

Concentrated and working strength photographic fixing compositions include a photographic fixing agent, a triazinylstilbene compound, and a water-soluble stabilizing compound that has a molecular weight of less than 200, from 2 to 10 carbon atoms, and at least two amino or hydroxy functional groups. The triazinylstilbene is provided in a concentrated fixer additive composition in a mixture with the stabilizing compound. The fixing compositions also include predominantly ammonium ions, and can be used to provide images in color photographic materials, and particularly in color reversal films, with reduced residual sensitizing dye stain.

Concentrated photographic fixer additive and fixing compositions

A conditioning or bleach accelerating solution is prepared by diluting a concentrate up to 25 times. The concentrate contains a formaldehyde bisulfite precursor salt at from 200 to 600 g/l, sulfite ions at 0 to 200 g/l, a bleach accelerating agent at from 1.5 to 25 g/l, and a metal ion chelating agent present at up to 60 g/l. The concentrate is free of sodium ions.

Growing community of inventors

Brockport, NY, United States of America

Jean Marie Buongiorne