The Dow Chemical Company

Jean-Luc Guillaume

Stephen M Oliver

Chiu-Kwan Lam

Veli J Koskelainen

It has been found that monovinylidene aromatic/conjugated diene/ethylenically unsaturated acid copolymer compositions are provided with good combinations of physical properties when a sulfoalkyl monomer is employed in minor amounts in such polymer in place of emulsifying additive(s). In particular, the combinations of wet and dry pick resistance have been shown to be maintained or improved when paper coating formulations are prepared from latex polymer compositions according to this invention. Sulfoalkyl (meth)acrylate salts and 2-acrylamido-2-methylpropane sulfonic acid salts are shown to be suitable sulfoalkyl monomers for this purpose.

Monovinylidene aromatic and conjugated diene copolymer coating

The use of a sulfoalkyl monomer in monovinylidene aromatic/(meth)acrylate/(meth)acrylic acid monomer latexes has been found to provide surprisingly good combinations of ion stability and moisture resistance. This is shown to be especially beneficial in paper coating and paint formulations. In examples, sulfopropyl methacrylate has proven especially beneficial in a styrene/n-butylacrylate/methacrylic acid latex for use in industrial-type, high strength coatings and formulations for coating offset printing paper.

Growing community of inventors

La Wantzenau, France

Jean-Luc Guillaume