L'oreal

Loreal Sa

L'or&eacute;al

Jean J Vandenbossche

Alex M Junino

Gerard Lang

Herve Borowiak

Alain Lagrange

Jean Cotteret

Herve Richard

Serge Forestier

Compositions for dyeing keratin fibers containing para-aminophenols, dyeing process, novel para-aminophenols and process for their preparation

The invention relates to the use of fused polycyclic compounds having at least one cationic group Z, Z being chosen from quaternized aliphatic chains, aliphatic chains having at least one quaternized saturated ring and aliphatic chains having at least one quaternized unsaturated ring, as direct dyes in compositions intended for dyeing keratin substances and, in particular, compositions intended for dyeing human keratin fibers, especially the hair, and cosmetic compositions intended for making up the skin, the nails and the lips, to the dye compositions or make-up compositions containing them and to the direct dyeing process using them.

Use of cationic fused polycyclic compounds for dyeing keratin substances, dye compositions and dyeing processes

Compositions for the oxidation dyeing of keratin fibers, comprising, as oxidation base, at least one para-aminophenol, of formula (I) and/or at least one acid-addition salt thereof:

Compositions for dyeing keratin fibers containing para-aminophenols, dyeing process, and para -aminophenols

Hydraulic coupler compounds corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl radical; R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical or an alkoxycarbonyl radical; X denotes a C.sub.1 -C.sub.4 lower alkyl radical, a C.sub.1 -C.sub.18 alkoxy radical, a halogen atom, a C.sub.1 -C.sub.20 acyloxy radical, an acetylamino group, a trimethylsilyloxy group or a dialkyl(C.sub.1 -C.sub.4)aminomethyl group, the OH group occupying the 6- or 7-positions, as well as their salts, are combined with oxidation dye precursors for dyeing keratinous fibers.

Method for dyeing keratin fibers with compositions which contain 6- or

A composition for the oxidation dyeing of keratinous fibers containing at least one coupler selected from indazoleamine derivatives and acid addition salts thereof and at least one oxidation base. Another aspect of the invention is the use of indazoleamine derivatives as coupler for the oxidation dyeing of keratinous fibers, in combination with at least one oxidation base, and the dyeing processes employing them.

Compositions for dyeing keratinous fibers comprising indazoleamine

Tinctorial composition for keratinous fibers, in particular for human hair, characterized in that it contains, in a medium appropriate for dyeing these fibers, at least one para oxidation dye precursor or at least one ortho oxidation dye precursor in combination with at least one heterocyclic coupler, corresponding to the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl radical; R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical or an alkoxycarbonyl radical; R.sub.3 denotes a hydrogen or halogen atom, a C.sub.1 -C.sub.4 lower alkyl radical, a carboxyl radical, an alkoxycarbonyl radical or a formyl radical; X denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical, a halogen atom, a C.sub.1 -C.sub.4 alkoxy radical, an acetylamino group or a dialkyl(C.sub.1 -C.sub.4)aminomethyl group; at least one of the groups X, R.sub.1, R.sub.2 and R.sub.3 differing from hydrogen; as well as their salts.

Tinctorial composition for keratinous fibers containing oxidation dye

The present invention relates to a novel process for the preparation of indole compounds of the formula II: ##STR1## from N-protected indolines of the formula I. ##STR2##

Process for the preparation of indole compounds from N-protected

Process for the preparation of 5,6-dihydroxyindole, wherein the compound of formula: ##STR1## in which R' denotes a hydrogen atom or an optionally substituted benzyl radical, is subjected either to the action of hydrogen under pressure or to a hydrogen transfer operation, in a solvent medium and in the presence of a hydrogenation catalyst.

Process for the preparation of 5,6-dihydroxyindole and intermediate

Oxidation tinctorial composition intended to be used for dyeing keratinous fibres, in particular human keratinous fibres and especially hair, characterized in that it contains, in a solvent medium appropriate for dyeing these fibres, at least one para oxidation dye precursor or at least one ortho oxidation dye precursor and at least one heterocyclic coupler corresponding to the formula (I): ##STR1## in which: R.sub.1 and R.sub.3, which may be identical or different, denote a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group;

Tinctorial composition for keratinous fibres containing oxidation dye

The invention concerns 4-hydroxy-5-methoxyindole and 5-ethoxy-4-hydroxy-2-methylindole which are useful as dyes for dyeing keratin materials.

Indole derivatives for dyeing keratin materials

Process for dyeing keratin fibres consisting in applying on these fibres a composition (A) containing at least one indole colorant of formula: ##STR1## where R.sub.1 =H or C.sub.1 -C.sub.4 alkyl;

Process for dyeing keratin fibres with a monohydroxyindole associated

The invention relates to the compounds of the formula: ##STR1## in which R.sub.1 and R.sub.2 denote, independently of one another, a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical or a C.sub.2 -C.sub.3 mono- or polyhydroxyalkyl radical, Z and Z' denote, independently of one another, a C.sub.1 -C.sub.4 alkyl or C.sub.2 -C.sub.4 hydroxyalkyl radical, with the proviso that, when R.sub.1 and R.sub.2 simultaneously denote a hydrogen atom, Z and Z' do not simultaneously denote a methyl radical, and to their addition salts with an acid, to a process for preparation thereof and also to their use, by way of couplers, in an aqueous vehicle, in combination with at least one oxidation dye percursor of the para type, for the dyeing of human hair. The invention also relates to the intermediate compounds of the formula: ##STR2## in which R' denotes a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical, a C.sub.2 or C.sub.3 mono- or polyhydroxyalkyl radical, or an acetyl or .beta.-chloethoxycarbonyl radical, and z and z' denote, independently of one another, a C.sub.1 -C.sub.4 alkyl radical.

Growing community of inventors

Aulnay-sous-Bois, France

Jean J Vandenbossche