Institut Francais Du Pe'trole

Institute Francais Du Petrole

Jean-Herve Le Gal

Patrick Euzen

Gerard Martin

Pierre Boucot

Michel Maute

A catalytic combustion process for at least one fuel comprises the use of a plurality of successive catalytic zones, the process being characterized in that at least one of the first catalytic zones includes a catalyst comprising a monolithic substrate, a porous support based on a refractory inorganic oxide and an active phase constituted by cerium, iron and optionally zirconium, also at least one metal selected from the group formed by palladium and platinum; and in that at least one of the subsequent catalytic zones includes an active phase comprising: an oxide of at least one element A with valency X selected from the group formed by barium, strontium and rare-earths; at least one element B with valency Y selected from the group formed by Mn, Co and Fe; and at least one element C selected from the group formed by Mg and Zn, and aluminium; the oxide may have formula A.sub.1-x B.sub.y C.sub.z Al.sub.12-y-z O.sub.19-.delta., x being 0 to 0.25, y being 0.5 to 3; and z being 0.01 to 3; the sum y+z having a maximum value of 4 and .delta. having a value which is a function of the respective valencies X and Y of elements A and B and the values of x, y and z, and is equal to 1-1/2{(1-x)X+yY-3y-z}.

Catalytic combustion process using a plurality of successive catalytic

Described is a process of catalytic combustion with staged fuel injection that comprises: a first injection of fuel and air, the passage of the air-fuel mixture that is formed into a catalytic zone, and a second fuel injection into the flow of output from said catalytic zone; with said process being characterized in that said catalytic zone comprises at least one catalyst that comprises a monolithic substrate, a porous support based on a refractory inorganic oxide, and an active phase that comprises cerium, iron, and optionally zirconium, as well as at least one metal that is selected from the group that is formed by palladium and platinum; the content of porous support is between 100 and 400 g per liter of catalyst; the cerium content is between 0.3 and 20% by weight relative to the porous support; the zirconium content is between 0 and 20% by weight relative to the porous support; with the iron content being between 0.01 and 3.5% by weight of iron relative to the porous support; and the palladium and/or platinum content is greater than 3 g per liter of catalyst. The process that uses such a catalyst produces improved performance levels by avoiding the fluctuating nature of combustion and the deactivation of the catalyst.

Process for catalytic combustion with staged fuel injection

The present invention relates to a catalytic combustion system comprising a casing (1) having an inlet (2) for an oxidizer such as air, several fuel injection means (3, 5; 7) intended for a multistage fuel injection, and at least a first monolithic element (4) that may be covered with a combustion catalyst and situated downstream from a first fuel injection means (3) in relation to the direction of progress of an air-fuel mixture in the system, said first injection means performing a partial fuel injection, and comprising at least a second monolithic element (6) situated downstream from a second injection means (5), said second monolithic element (6) being intended to stabilize the combustion. The second monolithic element (6) can be covered with a combustion catalyst.

Catalytic combustion system with multistage fuel injection

The invention relates to the manufacturing of synthetic gas according to which the following stages are performed within a single housing:

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Paris, France

Jean-Herve Le Gal