Robert Boschgmbh

Seeo, Inc.

Jean Fanous

Martin Tenzer

Bernd Schumann

Jens Grimminger

Marcus Wegner

Joerg Thielen

Hany Basam Eitouni

Kulandaivelu Sivanandan

Russell Clayton Pratt

Scott Allen Mullin

Christine Engel

Malte Rolff

Xiao-Liang Wang

Joerg Poehler

Michael Butzin

A separator having a first polymer diaphragm and a second polymer diaphragm and a layer between the first polymer diaphragm and the second polymer diaphragm including particles featuring low elasticity, the first polymer diaphragm and the second polymer diaphragm being interconnected, which may be periodically, by first support elements. In addition, a galvanic cell and a battery having such a separator are provided.

Separator and galvanic cell providing robust separation of anode and cathode

A lithium-sulfur cell includes a lithium-containing anode, a sulfur-containing cathode and a separator arranged between the lithium-containing anode and the sulfur-containing cathode. To suppress a shuttle mechanism and to prevent a loss of active material, the separator includes a base layer and a polysulfide barrier layer. The polysulfide barrier layer is formed on the cathode side of the separator.

Separator having a polysulfide barrier layer for lithium-sulfur cells

A separator for an energy store. The separator may be used in a lithium-sulfur battery in particular. To achieve improved cycle stability, the separator has at least one first layer and at least one second layer, the at least one first layer containing a material having an affine property with respect to at least one active electrode material, and the at least one second layer containing a material having a repellent property with respect to at least one active electrode material. The at least one first layer and the at least one second layer may be situated directly adjacent to one another. Also described is an energy store including the separator.

Separator for an energy store and an energy store

A cathode material for an electrochemical cell, in particular a lithium-sulfur cell, including at least one cathode active material and at least one in particular lithium ion-conducting or lithium ion-conductive polymer electrolyte and/or at least one inorganic ion conductor, in particular a lithium ion conductor. The at least one cathode active material includes a polymer containing in particular covalently bound sulfur. Moreover, also described is a cell and a battery equipped with same.

Cathode material for a lithium-sulphur cell

A polymer or a polymer electrolyte and cathode material for an alkali metal cell, in particular for a lithium-sulfur cell. To improve the performance and reliability of alkali metal cells, for example lithium-sulfur cells, a polymer based on the general chemical formula (I) is provided, where -[A]- stands for a unit which forms a polymer backbone, X stands for a spacer, x stands for the number of spacers X and is 1 or 0, Q stands for a positively charged group Qand a counterion Z, or Q stands for a negatively charged group Qand a counterion Z, or Q stands for an uncharged group. Moreover, the invention relates to the use thereof, and a cathode, a separator, a protective layer, and a cell.

Polymer electrolyte for a lithium sulfur cell

A lithium electrode includes a first lithium layer made of lithium or a lithium alloy, a current collector situated on a first side of the lithium layer, and a lithium-ion-conducting protective layer situated on a second side of the lithium layer opposite the first side. An intermediate layer completely covers the second side of the lithium layer and is situated between the lithium layer and the protective layer. The protective and intermediate layers have an electrical conductivity of less than 10S/cm. The lithium electrode may be used as the anode of a rechargeable lithium-ion battery. A lithium layer is applied to a current collector, an intermediate layer is applied to the lithium layer so that the intermediate layer completely covers the lithium layer, and a lithium-ion-conducting protective layer is applied to the intermediate layer.

Lithium electrode for a rechargeable lithium-ion battery and method for the manufacture thereof

A vehicle traction battery includes a battery cell, the battery cell including a cathode, and anode, and a separator the anode and cathode. The separator includes at least one protective layer that is impermeable to polysulfides and at least one ion-conducting conductive layer whose composition is different than that of the protective layer and that is designed as a copolymer which includes a stabilizing phase and an ionically conductive phase, the protective layer including an inorganic substance.

Separator including a polysulfide barrier layer for a battery cell, and battery cell

A battery housing including at least one interior space for accommodating at least one battery, and including at least one contact element which, in a connection position, establishes a connection to a counter-contact element, the connection passing through the battery housing out of the interior space and/or into the interior space, the connection being cut off in an out-of-contact position with the counter-contact element, the counter-contact element being situated on an insulation component movable relative to the battery housing, which is movable from a first position, in which the counter-contact element and the contact element are in the connection position, into a second position, in which the counter-contact element and the contact element are in the out-of-contact position, the contact element being thermally insulated in the out-of-contact position by the insulation component.

Thermal insulation of a battery having an elevated operating temperature

A cathode material for an alkali metal/sulfur cell, which encompasses at least one sulfur-containing cathode active material and at least one transition metal sulfide and/or at least one metal sulfide of at least one metal of the third, fourth, and/or fifth main group. Also described is a cell and a battery equipped therewith.

Cathode material for a lithium/sulfur cell

A protective layer system for a metallic lithium-containing anode of a lithium cell, for example a lithium-sulfur cell and/or lithium-oxygen cell. To increase the service life and reliability of the cell, the protective layer system includes a lithium ion-conducting layer, in particular an inorganic layer, on the anode side. The anode-side layer has an anode contact side which rests against or which may be placed against the anode. At least one lithium ion-conducting layer, in particular a polymer layer, which contains at least one agent which is reactable with metallic lithium to form an electrically insulating solid is situated on a side of the anode-side layer opposite from the anode contact side. Moreover, the invention relates to an anode which is equipped with such a protective layer system, a lithium cell, and a lithium battery.

Protective layer system for a metallic lithium anode

A method is provided for manufacturing a polyacrylonitrile-sulfur composite material, the polyacrylonitrile-sulfur composite material having an sphybrid proportion, with respect to the total carbon atoms included in the composite material, of greater than or equal to 85% including the method steps: a) reaction of polyacrylonitrile with sulfur at a temperature of greater than or equal to 450&#xb0; C., in particular greater than or equal to 550&#xb0; C.; b) immediate purification of the product obtained in method step a); and c) drying the purified product, if necessary. A composite material manufactured in this way may be used in particular in an active material of a cathode of a lithium-ion battery and offers a particularly high rate capacity. In addition, methods are provided for manufacturing an active material for an electrode, a polyacrylonitrile-sulfur composite material and an energy store.

Method for manufacturing a polyacrylonitrile-sulfur composite material

In a solid-state lithium-metal/sulfur-based battery cell, barriers to sulfur and polysulfide diffusion are included in or used as an ionically conductive electrolyte in the cathode or separator layers. During operation of the battery, the barrier materials are positioned to either 1) rapidly react with any free sulfur or lithium polysulfide species that are generated, forming stable carbon-sulfur bond(s) and preventing further migration of the sulfur or polysulfide species or 2) prevent the formation and diffusion of elemental sulfur or free lithium polysulfide species. Regardless of the identity of the sulfur/polysulfide species, the sulfur-containing species is prevented from diffusing to the anode and causing capacity fade and higher internal resistance to ion flow.

Long cycle-life lithium sulfur solid state electrochemical cell

An energy store system, including at least one cell element situated in a cell region having an anode, a cathode and an electrolyte system that is situated between the anode and the cathode and that is particularly at least partially liquid, the anode, the cathode and/or the electrolyte system being configured so that, as a function of a charging or discharging process of the cell element, functioning material is situated in the electrolyte system, and the functional material situated in the electrolyte system being ascertainable qualitatively and/or quantitatively. Because of such an energy store system, operating states of an energy store or a cell may be ascertained particularly simply and accurately. Also described is a related state detection system.

Energy store system and state detection system including the energy store system

A battery, particularly a lithium-metal battery or a lithium-ion battery, having at least one galvanic cell surrounded by a cell housing. To increase the safety of the battery and to close up again a cell opened by a safety device or by a leakage, the inner chamber of the cell housing of the at least one cell includes a first chemical component, a chamber bordering on at least one section of the outer side of the housing including a second chemical component; a solid reaction product being developable by the chemical reaction of the first and second chemical components. The first component is containable in the electrolyte of the cell and the second component in a cooling and/or tempering arrangement. Also described is a cooling and/or tempering arrangement based on it, and an electrolyte, an electrolytic liquid, a safety system, a method and a mobile or stationary system.

Safety system for batteries

A cathodic electrode of a lithium-based accumulator includes a basic structure, which is formed from fibers, flakes or grains. For this purpose, the fibers, flakes or grains are interspersed with channels, cavities or open pores.

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Stuttgart, Germany

Jean Fanous