Compagnie De Raffinage Et De Distribution Total France

Total Raffinage Distribution S.a.

C. Compagnie De Raffinage Et De Distribution

Compagnie De Raffinage Et De Distribution France

Jean-Bernard Sigaud

Jean-Louis Mauleon

Jean-Claude Courcelle

Roben Loutaty

Thierry Patureaux

Leonard Seglin

Francois Ville

Christophe Williatte

Bernard Chapotel

The present invention relates to a steam cracking process and apparatus which permits the conversion of fractions of petroleum hydrocarbons. The claimed invention provides for the conversion of at least one light hydrocarbon fraction, as well as a heavier hydrocarbon feedstock. The inventive process takes place at a high temperature and in the presence of a dilute fluidized phase of heat-transfer particles. The process comprises contacting the light-hydrocarbon feedstock and then the heavier feedstock, in a sequential manner with catalytic or noncatalytic heat-transfer particles in a continuous flow reactor. The process further provides for separating and stripping, to separate at least 90 percent of the particles which are regenerated before recycling. The process also provides for the separation of the effluent hydrocarbons which are quenched by cold feedstock and/or recycled residue (optionally supplemented by fresh particles) and thereafter recovered by fractionation distillation with at least a portion of the residue fraction being recycled to the downstream portion of the reactor.

Process and apparatus for the steam cracking of hydrocarbons in the

The invention relates to a process for the conversion of petroleum hydrocarbons in the presence of catalyst particles in a fluidized phase in an essentially upflow or downflow tubular reaction zone. The process includes at least one stage of steam cracking of at least one light hydrocarbon fraction and a stage of catalytic cracking of at least one heavy hydrocarbon fraction. The steam cracking is carried out by contacting the light hydrocarbons and a quantity of steam equal to at least 20 percent by weight in a fluidized bed of the catalyst particles, the resulting temperature ranging from 650.degree. to 850.degree. C. The catalytic cracking of the heavy hydrocarbons is carried out by injection of the effluents from the upstream section of the reaction zone into the catalyst suspension in such a way that the temperature of the mixture ranges from 500.degree. to 650.degree. C. and is then reduced to a temperature ranging 475.degree. to 550.degree. C.

Process and apparatus for fluidized-bed hydrocarbon conversion

The invention relates to a process for the conversion of petroleum hydrocarbons in the presence of catalyst particles in a fluidized phase in an essentially upflow or downflow tubular reaction zone, said process comprising at least one stage of steam cracking of at least one light hydrocarbon fraction and a stage of catalytic cracking of at least one heavy hydrocarbon fraction. The steam cracking is carried out by contacting the light hydrocarbons and a quantity of steam equal to at least 20 percent by weight in a fluidized bed of the catalyst particles, the resulting temperature ranging from 650.degree. to 850.degree. C. The catalytic cracking of the heavy hydrocarbons is carried out by contacting them with the effluents from the upstream section of the reaction zone and the catalyst suspension in such a way that the temperature of the mixture ranges from 500.degree. to 650.degree. C. and is then reduced to a temperature ranging from 475.degree. to 550.degree. C.

Process and apparatus for fluidized bed hydrocarbon conversion

The invention relates to an installation for the fluidized-bed cracking of a hydrocarbon feedstock. In accordance with the invention recycling of the regenerated catalyst particles to the intake of the reactor comprise, from upstream to downstream, a preferably substantially vertical pipe (1) for the discharge of the regenerated particles from the regenerator, and a substantially straight pipe (2) connected to the vertical pipe (1) and sloping downward therefrom to the base (3) of the reactor to which it is connected, the downward-sloping pipe (2) being connected to the vertical pipe (1) and to the base (3) of the reactor through inward-curved portions or elbows which impose neither a sharp change in direction on the course of the particles nor sudden changes in the diameter of the pipes.

Installation for the fluidized-bed catalytic cracking of a hydrocarbon

A device for injection of a hydrocarbon feedstock into a catalytic cracking reactor comprising, from upstream to downstream in the direction of flow of the feedstock, an intake and mixing system (5) for the liquid hydrocarbon feedstock and steam, a venturi tube (6) whose entrance cone (10) is joined to said intake and mixing system (5), and a protective cap (7) that is integral with the discharge cone (14) of the venturi tube and is provided with an orifice (16) for injection of the feedstock into the reactor. The dimensions of the venturi tube (6) are such that the velocity of the mixture of liquid feedstock and steam attains therein sonic conditions at the level of the throat (13), and the rectilinear throat located between the discharge cone (14) and the entrance cone (10) is connected to such cones continuously by a curved section without making an angle exceeding about 5 degrees and about 15 degrees, respectively, with the axis of the venturi tube.

Device for injection of a hydrocarbon feedstock into a catalytic

A process for the regeneration of a catalyst by combustion of the coke deposited thereon during a hydrocarbon conversion reaction in which process more than 50 percent of the coke is burned in at least one regeneration chamber operating with a fluidized bed, wherein the upper portion of the fluidized bed the suspension of catalyst particles in said chamber is slowed down due to a substantial increase in the diameter of the regeneration chamber so that the superficial velocity of the rising fluids which no longer contain any oxygen is reduced to a value ranging from 0.5 to 1.5 meters/second, that is, to a value corresponding to the fluidization conditions in a dense fluidized bed.

Fluidized-bed catalyst regeneration

A process is disclosed for the catalytic cracking of hydrocarbons in a fluidized bed wherein the catalyst particles are injected in a fully fluidized suspension into an elongate reaction zone. In accordance with the process, the feedstock to be cracked is injected in a state of small droplets less than 200 microns in diameter countercurrently to the flow of the fully fluidized suspension of catalyst particles.

Process for the catalytic cracking of hydrocarbons in a fluidized bed

The invention relates to a process and apparatus for catalytic cracking in a fluid phase of a hydrocarbon charge. The process comprises contacting, in ascending or descending flow, the charge and grains of a cracking catalyst in a tubular reactor, ballistically separating the spent catalyst and the cracked charge downstream of the end of said reactor, mixing spent catalyst with grains of at least partially regenerated catalyst having a temperature exceeding that of the grains of spent catalyst, stripping spent catalyst in a dense fluidized phase by means of a fluid injected counter-current into this catalyst regenerating the catalyst under conditions to effect combustion of coke deposited thereon, and recycling regenerated catalyst to feed the reactor.

Process and apparatus for the catalytic cracking of hydrocarbon charges

An apparatus for the catalytic cracking of hydrocarbon feedstocks with reaction temperature control is provided which includes an upward-flow or downward-flow cracking column, means for feeding said column under pressure with a hydrocarbon feedstock and with particles of a regenerated cracking catalyst, at least one means for injection of an auxiliary fluid downstream of the zone in said column where the hydrocarbon feedstock and the regenerated catalyst particles are contacted with each other, to reduce the temperature of the reaction zone situated directly downstream thereof, means for separating the products of the cracked feedstock and the spent catalyst particles, at least one stripping means, at least one unit for regeneration of the catalyst by combustion of the coke deposited thereon and means for recycling the regenerated catalyst to said feeding means.

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Vaucresson, France

Jean-Bernard Sigaud