3m Innovative Properties Company

Jean A Tangeman

Kenton D Budd

Taisiya Skorina

Anatoly Z Rosenflanz

Rebecca L A Everman

John Charles Clark

Craig W Lindsay

Noah O Shanti

Fabian Stolzenburg

Rebecca L Everman

Robert P Brown

Jason D Anderson

Christopher Bland Walker, Jr

Alexander J Kugel

Kevin W Gotrik

John J Gagliardi

Vivek Krishnan

Paul C Nordine

Thomas B Galush

Rachael A T Gould

Daniel Scott Hampton

Jk Richard Weber

Zachary M Schaeffer

Kristin M Amsden

Lara K N Ughetta

Eric J Vanbruggen

Jonathan A Hubin

Plurality of granules comprising a ceramic core having an outer surface and a shell on and surrounding the core, wherein the shell comprises ceramic particles bound together with an inorganic binder, the inorganic binder comprising reaction product of at least alkali silicate and hardener, wherein the ceramic particles are present as greater than 50 percent by weight of the shell of the respective granule, based on the total weight of the shell of the respective granule, wherein the shell of each granule has a total porosity in a range from greater than 0 to 60 percent by volume, based on the total volume of the shell of the respective granule, wherein the shell of each granule has a volume of at least 40 volume percent, based on the total volume of the respective granule, and wherein the granules have a minimum Total Solar Reflectance of at least 0.7. The granules are useful, for example, as roofing granules.

Granules

A plurality of non-white roofing granules is provided. The roofing granules include a plurality of particles including mineral fines and a calcia-based cement binder; and a non-white pigment-containing coating disposed on at least a portion of exterior surfaces of the particles. Methods of making the roofing granules are also provided. One method includes: mixing material including mineral fines and a calcia-based cement binder to provide agglomerates; curing the agglomerates to provide particles; and coating at least a portion of exterior surfaces of the particles with a non-white pigment-containing coating. Another method of making the roofing granules includes: providing an aqueous dispersion in a tool having cavities, the aqueous dispersion including mineral fines and a calcia-based cement binder; curing the aqueous dispersion in the tool to provide particles; and coating at least a portion of exterior surfaces of the particles with a non-white pigment-containing coating. The roofing granules exhibit an intrinsic total solar reflectance greater than 0.3. Often, the roofing granules contain by-product mineral fines.

Non-white roofing granules and methods of making same

There is provided an article comprising at least a first surface having: (a) a first binder layer; (b) a plurality of transparent microspheres partially embedded in the first binder layer wherein the transparent microspheres have refractive indices that are less than a refractive index of the first binder layer and wherein the plurality of transparent microspheres consist of microspheres having a refractive index of no more than 1.490. There is also provided a transfer article comprising: (a) a transfer carrier, the transfer carrier comprising: (i) a support layer; and (ii) a thermoplastic release layer bonded to the support layer; (b) a layer of a plurality of transparent microspheres, formed on a side of the thermoplastic transparent microsphere release layer opposite the support layer, wherein the plurality of transparent microspheres consist of microspheres having a refractive index of no more than 1.490.

Microsphere articles and transfer articles

A plurality of granules comprising ceramic particles bound together with an inorganic binder, the inorganic binder comprising reaction product of at least alkali silicate and hardener, wherein the ceramic particles are present as at least 50 percent by weight of each granule, based on the total weight of the respective granule, wherein each granule has a total porosity in a range from greater than 0 to 50 percent by volume, based on the total volume of the respective granule, and wherein the granule has a minimum Total Solar Reflectance of at least 0.7. The granules are useful, for example, as roofing granules.

Methods for making articles comprising crystalline material. Exemplary articles made by a method described herein include electronics enclosure (e.g., a watch case, cellular phone case, or a tablet case).

Articles comprising crystalline materials and method of making the same

A plurality of granules comprising particulate silicate material bonded together with an inorganic binder, the inorganic binder comprising reaction product of at least alkali silicate and hardener, wherein the hardener is at least one of aluminum phosphate, amorphous aluminosilicate, fluorosilicate, Portland cement, or a calcium silicate, wherein the particulate silicate material is present as at least 50 percent by weight of each granule, based on the total weight of the respective granule, wherein each granule has a total porosity in a range from greater than 0 to 50 percent by volume, based on the total volume of the respective granule, and wherein the granules have Tumble Toughness Value of at least 70 before immersion in water and at least 40 after immersion in water at 20&#xb0; C.&#xb1;2&#xb0; C. for two months. The granules are useful, for example, as roofing granules.

A method of coating a roofing material is described. The method comprises providing an aqueous roof coating composition comprising an inorganic binder material, a chemical curing agent, inorganic particulate filler; applying the aqueous roof coating composition to an inorganic roofing material; and allowing the aqueous roof coating composition to dry and chemically curing agent. The roof coating composition has a total solar reflectance of at least 0.7 after allowing the aqueous roof coating composition to dry and chemically cure. Also described are aqueous roof coating compositions and inorganic (e.g. roofing) materials comprising a surface coating having a total solar reflectance of at least 0.7; wherein the surface coating comprises silicate, a chemical curing agent; and inorganic particulate filler.

Roof coating composition, methods of use, and articles

A granule and building material including a granule having an inner zone and an outer zone that at least partially surrounds the inner zone and that comprises greater than 10% of the total volume of the granule is provided.

Glass granule having a zoned structure

Described herein is a construction comprising a microsphere layer comprising a plurality of microspheres, wherein the microspheres comprise glass, ceramic, and combinations thereof; a bead bonding layer, wherein the plurality of microspheres is partially embedded in the bead bonding layer forming a first surface comprising exposed microspheres, wherein the plurality of microspheres on the first surface are truncated. Also disclosed herein are articles comprising the construction and methods of making thereof.

Truncated beadfilm constructions and methods of making the same

A roofing granule includes a glass substrate and a plurality of pores in the glass substrate such that the roofing granule has a minimum total solar reflectance of at least 50%.

Porous glass roofing granules

This invention relates to the use of novel glass materials comprising rare earth aluminate glasses (REA1&#x2122; glasses) in the gain medium of solid state laser devices that produce light at infrared wavelengths, typically in the range 1000 to 3000 nm and for infrared optics with transmission to approximately 5000 nm in thin sections. The novel glass materials provide stable hosts for trivalent ytterbium (Yb) ions and other optically active species or combinations of optically active species that exhibit fluorescence and that can be optically excited by the application of light. The glass gain medium can be configured as a waveguide or placed in an external laser cavity, or otherwise arranged to achieve gain in the laser waveband and so produce laser action.

Growing community of inventors

Minneapolis, MN, United States of America

Jean A Tangeman