Novvi LLC

Chevron U.s.a. Inc.

Skyline Solar, Inc.

Other

Intermolecular, Inc.

Symyx Technologies, Inc.

Jason Wells

Eduardo J Baralt

Liwenny Ho

Benton Thomas

Jason Charles Rosalli

Marc A Finot

Ajit Ramachandra Pradhan

Yalin Hao

Willbe Ho

Wui Sum Willbe Ho

Cong-Yan Chen

H Sam Bergh

Lynn Van Erden

John Lawrence Nightingale

Anthony F Volpe

Shenheng Guan

Peijun Cong

Eric C Johnson

Victor Wong

Hyeok Hahn

Jeffrey A Brown

John Gallipeo

Stephen Cypes

Jeffrey Maag

Joseph A Duimstra

James L Bilodeau

Paula Vettel

Cong Yan Chen

Jeffrey Brown

Aspects of the present disclosure relate to a process for producing synthetic hydrocarbon base oils having advantageous properties for formulation of engine oils, and the base oils obtained by such processes, involving the production of branched alkenes from the oligomerization of C14-C18 olefins. According to one embodiment, the base oils are obtained by first forming a mixture of two or more olefins ranging from C14-C18, where one of the olefins is an alpha olefin and the other has an average double bond position between 1.5-5.0, and oligomerizing this mixture in the presence of a catalyst to form one or more branched alkenes, hydrogenating the branched alkenes, and fractionating to form base oils. According to one aspect, advantageous properties can be obtained by controlling one or more of the degree of branching, branch length, branching positions, selection of the C14-C18 olefins, and catalytic isomerization, during or after the oligomerization process.

Base oils and methods of making the same

A process for the preparation of saturated hydrocarbon base oils is provided, comprising oligomerization of a feed mixture that has an average carbon number in the range of 14 to 18 to produce an oligomer product comprising dimers, trimers, and higher oligomers, where the dimer has a branching proximity (BP) of 20 or greater, isomerization of at least the dimer portion, and hydrogenation of the isomerized product. The dimer portion is separated from the oligomer product, and a saturated hydrocarbon base oil is obtained comprising greater than 90% dimers having an average carbon number in the range of from 29 to 36, and the dimer portion having a weight average molecular weight in the range of 422 to 510, where the dimers have an average Branching Index (BI) in a range of 22 to 26 and an average paraffin branching proximity (BP) in a range of from 18 to 26.

Provided herein is a unique process that prepares a saturated hydrocarbon mixture with well-controlled structural characteristics that address the performance requirements driven by the stricter environmental and fuel economy regulations for automotive engine oils. The process allows for the branching characteristics of the hydrocarbon molecules to be controlled so as to consistently provide a composition that has a surprising CCS viscosity at &#x2212;35&#xb0; C. (ASTM D5329) and Noack volatility (ASTM D5800) relationship. The process comprises providing a specific olefinic feedstock, oligomerizing in the presence of a BFcatalyst, and hydroisomerizing in the presence of a noble-metal impregnated, 10-member ring zeolite catalyst.

Process for preparing hydrocarbon mixture exhibiting unique branching structure

A polyalphaolefin composition is provided comprising trimers of C12 alpha-olefins and dimers of C14 alpha-olefins, where the ratio by weight of C12 trimer to C14 dimer is within a range of 4:1 by weight to 1:4 by weight, where the C12 trimer enriched polyalphaolefin has an average branching ratio &#x3c;0.2 and the C14 dimer has an average branching ratio of &#x3e;0.20, and where the average branching ratio for all C12 trimers and C14 dimers is between 0.19 and 0.26. The composition has a boiling point distribution where less than 30% by weight of the composition has a boiling point between 420&#xb0; C. and 455&#xb0; C., and the resulting base oil has a kinematic viscosity of about 3.3 to 4.7 cSt at 100&#xb0; C.

Synthetic oligomer compositions and methods of manufacture

Provided herein are hydrocarbon mixtures with controlled structure characteristics that address the performance requirements for finished lubricants driven by the stricter environmental and fuel economy regulations. The branching characteristics of the hydrocarbon molecules are controlled to provide a composition that has a unique and superior viscosity-temperature relationship and Noack volatility. An important aspect of the present invention relates to a saturated hydrocarbon mixture with at least 80% of the molecules having an even carbon number, with the branching characteristic of BP/BI in the range&#x2265;&#x2212;0.6037 (Internal alkyl branching)+2.0, where on average at least 0.3 to 1.5 of the internal methyl branches are located more than 4 carbons away from the terminal carbon when analyzed by carbon NMR. The saturated hydrocarbon mixture with such unique branching structure consistently exhibits a stand out performance in the cold crank simulated viscosity (CCS) vs Noack volatility relationship, which allows for the formulation of lower viscosity engine oils with improved fuel economies.

Hydrocarbon mixture exhibiting unique branching structure

A dielectric fluid and coolant for electrical apparatuses such as transformers. In one embodiment, the fluid contains more than 25% biobased base oil, such as a biobased hydrocarbon oil, which has a molecular weight greater than 300 g/mol and less than 595 g/mol. The biobased base oil may optionally be blended with other oils, such as mineral oils and vegetable oils.

Dielectric fluid and coolant made with biobased base oil

The present invention discloses an apparatus and method for rapid analysis of members of a combinatorial library. The apparatus includes a plurality of reactor vessels for containing individual library members, a fluid handling system that apportions a test fluid about equally between each of the vessels and a housing for enclosing the reactor vessels, the housing defining a pressure chamber, wherein the housing is configured to sustain a pressure substantially above atmospheric pressure. This allows for simultaneous screening of library members at high pressure by providing a small pressure differential on reactor components. The disclosed apparatus is especially useful for screening library members based on their ability to catalyze the conversion of fluid reactants.

High pressure parallel fixed bed reactor and method

The application provides a base stock or a lubricant composition comprising the substances derived from algae by chemical modification of algal oil, including compositions comprising estomers. Methods for obtaining the same are also provided, including chemically modifying the algal oil with a saturated fatty acid under conditions favorable to the formation of a poly-estomer.

Synthetic compositions obtained from algae

Concentrating solar collector systems that utilize a concentrating reflector to direct incident solar radiation to a solar receiver are described. In one aspect, the reflective surface is arranged to direct light to the receiver in a non-imaging manner in which the solar rays reflected from the opposing edges of the reflective surface are generally directed towards a central portion of the solar receiver. Rays reflected from selected central portions of the reflective surface are directed closer to the edges of the receiver than the solar rays reflected from the edges of the reflective surface. The described reflectors are generally intended for use in solar collector systems that track movements of the sun along at least one axis.

Reflective surface for solar energy collector

In one embodiment, a concentrating solar energy collector, which tracks movements of the sun along one axis has a reflective trough, at least one solar receiver mounted above the reflective trough and configured so that incident sunlight striking the reflective trough is directed toward the at least one solar receiver, and a reflector extender coupled to a first end of the reflective trough and configured to capture and direct incident sunlight towards the at least one solar receiver. In another embodiment, one or more extended end reflectors is attached with a reflective trough of a solar energy collector.

Solar collector with end modifications

A library of material samples is provided in a condition suitable for imaging using infrared (IR) spectroscopy. The samples are provided to one or more detection cells, each of the cells including or containing a reflective surface. Preferably, for imaging, an energy source (e.g. a source of infrared radiation) provides energy to the detection cells to interact with the samples. Thereafter, images (e.g., spectra) related to the samples are created based upon the interaction.

Parallel infrared spectroscopy apparatus and method

Growing community of inventors

San Francisco, CA, United States of America

Jason Wells