Exxonmobil Research and Engineering Company

Exxonmobil Technology and Engineering Company

Jasmina Poturovic

Mohsen N Harandi

Ian A Cody

Mark Alan Greaney

Limin Song

Shifang Luke Luo

Bal K Kaul

Amar S Wanni

Scott K Berkhous

James Edward Feather

Ian J Laurenzi

Mike T Noorman

Robert Charles Welch

Gregory K Lilik

Matthew H Lindner

Stuart S Goldstein

Abhash Nigam

Naphtha boiling range compositions are provided that are formed from crude oils with unexpected combinations of high naphthenes to aromatics weight and/or volume ratio and a low sulfur content. The resulting naphtha boiling range fractions can have a high naphthenes to aromatics weight ratio, a low but substantial content of aromatics, and a low sulfur content. In some aspects, the fractions can be used as fuels and/or fuel blending products after fractionation with minimal further refinery processing. In other aspects, the amount of additional refinery processing, such as hydrotreatment, catalytic reforming and/or isomerization, can be reduced or minimized. By reducing, minimizing, or avoiding the amount of hydroprocessing needed to meet fuel and/or fuel blending product specifications, the fractions derived from the high naphthenes to aromatics ratio and low sulfur crudes can provide fuels and/or fuel blending products having a reduced or minimized carbon intensity.

High naphthenic content naphtha fuel compositions

This invention relates to process for producing a reformate or gasoline product. The process involves a rapid cycle of reacting hydrocarbon feedstock to form the product and then regenerating the catalyst used in the reaction. The process can be carried out at relatively high liquid hourly space velocities and preferably at relatively low hydrogen to hydrocarbon ratios to produce a reformed product having relatively high liquid yield and hydrogen content.

Rapid cycle reforming process

Targeted application of anti-fouling mechanisms in a heat exchange system produces higher rates of energy recovery. The anti-fouling mechanisms with high mitigation rates can be deployed at only the hottest portions of a pre-heat train that experience the highest rates of fouling and heat loss. In application, bundles of corrosion resistant smoothed tubes are deployed in the late pre-heat train to significantly reduce the formation of harder deposits. Vibration can be used as an adjunct approach in conjunction with the corrosion resistant, smooth tubes, or deployed alone on existing bundles. The use of high performing, more durable exchangers in select locations justifies the increased cost of these components.

Crude oil pre-heat train with improved heat transfer

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Vienna, VA, United States of America

Jasmina Poturovic