Rayovac Corporation

Spectrum Brands, Inc.

Energizer Brands, LLC

Janna L Rose

Ronald J Ekern

M Edgar Armacanqui

John L Hadley

Miguel E Armacanqui

Wen Li

Andrew John Roszkowski

Kenneth H Kenyon

Patricia S Bennett

Patrick J Spellman

Donald Raymond Crowe

Zhihong Jin

Robert J Jacus

Randall L Collien

Gerald F Sanden

Alane M Boutelle

Cecilia T Maske

Josie B Wieser

A gelled anode for an alkaline electrochemical cell contains zinc-based particles, an alkaline electrolyte, a gelling agent, and two or more additives selected from the group consisting of an alkali metal hydroxide, an organic phosphate ester surfactant, a metal oxide, and tin, which as reduced cell gassing properties relative to cells lacking such additives.

Alkaline cell with improved discharge efficiency

The present disclosure relates generally to an alkaline electrochemical cell, such as a battery, and in particular to an improved gelled anode suitable for use therein. More specifically, the present disclosure relates to a gelled anode that improves anode discharge efficiency by adjusting physical properties such as apparent density.

Alkaline cell with improved high rate capacity

Alkaline cell with improved high rate capability

The present disclosure is directed to a primary electrochemical cell having an improved discharge performance, and/or improved reliability under physical abuse and/or partial discharge. More particularly, the present disclosure is directed to such a primary cell that comprises an improved cathode material comprising iron disulfide and a select pH-modifier and an improved non-aqueous electrolyte that comprises a solvent, a salt, pH-modifiers, and selected organic or inorganic additives, which improve cell stability and discharge performance.

Lithium primary cell

An electrochemical cell having a cell can that includes an interior surface, a current collector, a solid cathode contained in the can and in conductive contact therewith, an organic or solid polymer electrolyte comprising lithium salt solutes and aprotic organic solvents has improved storage properties when a coating comprising carbon powder is diposed on the current collector surface and on the adjacent interior surface of the cell can. Further, the cell has advantageous enhanced discharge properties over an expanded temperature range when the cathode additionally comprises a fluoropolymer resin binder.

Extended temperature operating range electrochemical cells

A sodium polyacrylate superabsorbent polymer made by bulk polymerization and characterized as described herein is a superior gelling agent when provided at a suitable concentration in a gelled anode for an alkaline electrochemical cell. Suitable gelled anodes, alkaline electrochemical cells containing such gelled anodes, and methods for making and using same are also described.

Sodium polyacrylate gelling agent for zinc gelled anode

An ionically permeable separator for a LeClanche cell, and methods of making and using same, are provided for in the invention. The separator comprises a Kraft paper separator and a corrosion-inhibiting coating thereupon selected to prevent corrosion of a zinc anode of the LeClanche cell. The separator may be configured for use in round or flat LeClanche cells. The separators of the invention may be used in heavy duty batteries containing an electrolyte comprising zinc chloride as a primary component. Cells made in accordance with the invention exhibit comparable or improved capacity and other performance characteristics in respect of conventional cells.

Method of making an ionically permeable separator for a leclanche cell

Method of making a reduced environmental hazard leclanche cell having

A potassium polyacrylate superabsorbent polymer made by modified bulk polymerization and characterized as described herein is a superior gelling agent when provided at a suitable concentration in a gelled anode for an alkaline electrochemical cell. Suitable gelled anodes, alkaline electrochemical cells containing such gelled anodes, and methods for making and using same are also described.

Gelling agent for alkaline electrochemical cells

This invention pertains to rechargeable zinc alkaline electrochemical cells. In cells of the invention, the anode current collector comprises copper, and from about 0.5% by weight to about 11% silicon. Preferred compositions for the anode current collector comprise from about 1% by weight silicon to about 6% by weight silicon. Cells embodying anode current collectors of the invention exhibit reduced current flow under anode polarization in alkaline conditions, and reduced cell expansion under abusive electrical drain conditions. The cells are less susceptible to oxidation of the anode current collector, which is typically irreversible, than known brass anode current collectors. In general, cells of the invention are less susceptible to, and generally do not exhibit as much, irreversible chemical reaction activity, as conventional current collectors, especially oxidation of copper at the anode current collector.

Rechargeable alkaline electrochemical cell

Ionically permeable separator for leclanche cell

Reduced environmental hazard LeClanche cell having improved performance

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Madison, WI, United States of America

Janna L Rose