Korea Research Institute of Chemical Technology

Jang Yong Lee

Tae Ho Kim

Young Taik Hong

Seog Je Kim

Sang Hun Shin

Duk Man Yu

Seokhwan Yang

The present disclosure relates to a carbazole-based anion exchange material, a preparation method therefor and use thereof, and more particularly, to an anion exchange material used in membranes for water electrolysis, redox flow batteries, fuel cells, carbon dioxide reduction, electrochemical ammonia production and decomposition, electrodialysis (ED), reverse electrodialysis (RED) or capacitive deionization (CDI), a separator comprising the same, a preparation method therefor and use thereof. According to the present disclosure, it is possible to prepare a separation membrane with improved mechanical and chemical stability and durability by remarkably improving the molecular weight together with solubility in solvent by providing the anion exchange material in which all bonds between monomers in the main chain are C—C bonds based on the carbazole-based material with high stability.

Carbazole-based anion exchange material, preparation method therefor, and use thereof

The present invention relates to an ion conducting polymer including a partially branched block copolymer; a method of preparing the same; an ion conductor including the ion conducting polymer; an electrolytic membrane including the ion conducting polymer; a membrane-electrode assembly comprising the electrolytic membrane, and a battery comprising the same; and a separation membrane for a redox flow battery including the ion conducting polymer, and a redox flow battery comprising same. Specifically, the partially branched block copolymer includes: a first block including a hydrophilic first polymer; a second block derived from a hydrophobic second polymer having two or more reactive groups respectively on its both ends, in such a way as to form branching points forming side branches on a main chain; and optionally a third block including a hydrophobic third polymer. The ion conducting polymer in the form of a partially branched block copolymer can prepare a polymer membrane having improved conductivity and superior physical properties such as tensile strength elongation at break, etc., while having the same or similar ion-exchange capacity (IEC), percentage water absorption and/or degree of dimensional change compared to conventional ion conducting polymers in the form of linear block copolymers. Because of such outstanding physical properties, the polymer membrane can be used as a membrane-electrode assembly for a fuel cell, and a redox flow battery comprising the same as a separation membrane can exhibit outstanding cell performance and maintain high discharge charge capacity retention rate even when repeatedly charged and discharged several times.

Ion conducting polymer comprising partially branched block copolymer and use thereof

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Daejeon, South Korea

Jang Yong Lee