Schlumberger Technology Corporation

Jane T Lam

Ronald E G Van Hal

Jimmy Lawrence

Farshid Mostowfi

Shahnawaz Hossain Molla

Neil William Bostrom

Michael Mallari Toribio

Ronald Van Hal

Amy Du

Oliver Clinton Mullins

Christopher Harrison

Douglas W Grant

Michael O'Keefe

Huilin Tu

Andreas Hausot

Roman Kats

James G Haug

Rekha Agarwalla

A technique facilitates detection and analysis of constituents, e.g. chemicals, which may be found in formation fluids and/or other types of fluids. The technique comprises intermittently introducing a first fluid and a second fluid into a channel in a manner which forms slugs of the first fluid separated by the second fluid. The intermittent fluids are flowed through the channel to create a mixing action which mixes the fluid in the slugs. The mixing increases the exchange, e.g. transfer, of the chemical constituent between the second fluid and the first fluid. The exchange aids in sensing an amount of the chemical or chemicals for analysis. In many applications, the intermittent introduction, mixing, and measuring can be performed in a subterranean environment.

System and methodology for chemical constituent sensing and analysis

A method for determining scaling cation concentration may include introducing a first solution that includes a scaling cation, incrementally adding a portion of the first solution to a volume of a second solution comprising a counter scaling anion and a complexing agent, wherein the second solution comprises a fixed concentration of the counter scaling anion and the agent, to form a mixed solution, adding the first solution to the second solution until a precipitate of the scaling cation and the counter scaling anion forms, and determining the scaling cation concentration of the first solution.

Back titration methods for scaling cations and downhole tools for performing such methods

A method for analyzing formation fluid in a subterranean formation is disclosed, wherein the method includes the steps of: adding a scavenger compound to an analytical reagent to form a reagent solution; collecting an amount of formation fluid into a formation tester, wherein the formation tester includes at least one fluids analyzer comprising at least one probe, at least one flow line, at least one reagent container, and at least one spectral analyzer, wherein the fluids analyzer is configured such that the collected formation fluid is fed through the at least one flow line to the at least one spectral analyzer; mixing an amount of the collected formation fluid with an amount of the reagent solution to form a mixture; and analyzing the mixture downhole.

Chemical scavenger for downhole chemical analysis

Methods and related apparatuses and mixtures are described for spectroscopic detection of hydrogen sulfide in a fluid, for example a formation fluid downhole. A reagent mixture is combined with the fluid. The reagent mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and a capping agent that limits growth of the insoluble metal sulfide species by electrosteric or steric stabilization. The particle growth is one of chemical reaction or significant aggregation, and the capping agent further functionalizes the reagent mixture to exhibit properties outside the natural characteristics of the metal sulfide species to allow for spectroscopic detection of the metal sulfide species. The combined mixture and fluid is then spectroscopically interrogated to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.

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Described herein are variable-volume reservoir (e.g., syringe pump) based processes and systems usable to characterize samples of reservoir fluids, without having to first transport the fluids to the surface. Variable-volume reservoirs are used, for example, for one or more of storing reactants, controlling mixing ratios and storing used chemicals. The processes and systems can be used in various modes, such as continuous mixing mode, flow injection analysis, and titrations. A fluid interrogator, such as a spectrometer, can be used to detect a change in a physical property of the mixture, which is indicative of an analyte within the mixture. In at least some embodiments, a concentration of the analyte solution can be determined from the detected physical property.

System and method for fluid processing with variable delivery for downhole fluid analysis

Methods and devices for mixing a first fluid with a second fluid downhole include a chamber having a first end, a second end and an opening for fluid to flow there through. A top surface of a perforated piston is capable of contacting the second end and a top surface of a piston is capable of contacting a bottom surface of the perforated piston. The perforated piston is located at a first position within the chamber based upon characteristics of a first fluid. A first fluid delivery system supplies the first fluid and a second fluid delivery system supplies a second fluid to the chamber, wherein the second fluid is at a pressure that moves the piston approximate to the first end. An actuating device applies a force against the bottom surface of the piston to inject the fluids through channels of the perforated piston to produce spray droplets.

Downhole mixing device for mixing a first fluid with a second fluid

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Randolph, MA, United States of America

Jane T Lam