Shell Oil Comapny

Kraton Polymers U.S. LLC

Shell Canada Limited

Jan Korenstra

Willem C Vonk

Jeroen Van Westrenen

Robert Q Kluttz

Keith Edward Stephens

Willem Cornelis Vonk

The present invention is directed to bituminous emulsions comprising bitumen, water, one or more emulsifiers systems and a diblock copolymer including one block of a monovinylaromatic hydrocarbon and one block of a conjugated diene, wherein the conjugated diene has a peak molecular weight from 30,000 to 78,000 and a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block. A block copolymer comprising at least two blocks of monovinylaromatic hydrocarbon and at least one block of conjugated diene, the block copolymer selected from linear triblock copolymers having a peak molecular weight that is 1.5 to 3.0 times the peak molecular weight of the diblock copolymer, multiarm coupled block copolymers having a peak molecular weight that is 1.5 to 9.0 times the peak molecular weight of the diblock copolymer, and mixtures thereof, wherein each block copolymer has a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block, wherein the ratio of (i) to (ii) in the block copolymer composition is greater than 1:1.

Bituminous emulsions

A bituminous composition comprising a bituminous component and a block copolymer composition which comprises at least one of the group consisting of linear triblock copolymers, multi-armed block copolymers, and diblock copolymers, which block copolymers comprise at least one block of a monovinylaromatic hydrocarbon (A) and at least one block of a conjugated diene (B), wherein the block copolymer composition which is present in an amount in the range of from 1 to 10% wt, based on total bituminous composition has a vinyl content of at least 25% by weight, based on the total diene content, and any diblock copolymer (AB) present has an apparent molecular weight in the range of from 60,000 to 100,000.

Bituminous composition

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Amsterdam, Netherlands

Jan Korenstra