Agfa Gevaert Nv

Jan J Priem

Walter F De Winter

August Jean Van Paesschen

Daniel M Timmerman

Yvan K Gilliams

Lucien J Van Gossum

Wilhelmus Janssens

Etienne A Van Thillo

Noel J De Volder

Pierre R De Roo

Jan H Janssens

The present invention provides a photographic element comprising a dimensionally stable hydrophobic transparent polyester film support, at least one light-sensitive silver halide emulsion layer, and at the side of said support opposite to that of said emulsion layer(s), a subbing layer essentially consisting of poly-N-vinyl pyrrolidone, and an antihalation layer comprising carbon black dispersed in a water-insoluble alkali-soluble copolymer of 1 to 65% by weight of a C.sub.1 -C.sub.4 alkyl methacrylate, 10 to 79% by weight of a C.sub.1 -C.sub.8 alkyl acrylate, and 10 to 50% by weight of acrylic acid or methacrylic acid. The present invention also provides a process of manufacturing a dimensionally stable hydrophobic transparent polyester film support carrying a subbing layer and an alkali-soluble carbon black antihalation layer, said process comprising monoaxially stretching an extruded amorphous polyester film, coating it with an aqueous solution of poly-N-vinyl pyrrolidone to form said subbing layer, drying it, stretching it together with said film in a direction perpendicular to that of the first stretching, heat-setting, coating the film support with an aqueous dispersion of carbon black in said above-mentioned water-insoluble alkali-soluble copolymer to form said alkali-soluble antihalation layer.

Subbed polyester film support carrying carbon black antihalation layer

Method for the preparation of stable aqueous dispersions of finely divided solid spherical polymer beads having an average particle size between about 0.5 and about 5 .mu.m and having a glass transition temperature of at least 40.degree. C. by dissolving in an aqueous solvent mixture at least one .alpha.,.beta.-ethylenically unsaturated monomer capable of forming a polymer that is soluble in the monomer(s) present in said aqueous solvent mixture but which is insoluble in said aqueous solvent mixture, a free radical-forming polymerization initiator, and a graft-polymerizable polymer containing hydrophilic groups, heating the solution to a temperature from 50.degree. C. to the reflux temperature thereof with stirring so as to form said polymer beads. The polymer beads can be used in an antifriction surface layer, an antihalation surface layer, an antistatic surface layer, or in a protective surface layer of a photographic element or in a top layer of a drafting film containing a photosensitive layer.

Method for the preparation of stable aqueous dispersions of polymer

An electrostatic liquid developer for the development of electrostatic charge patterns comprises an electrically insulating carrier liquid having a dielectric constant of less than 3 and a volume resistivity in excess of 10.sup.9 Ohm.cm. In this electrically insulating carrier liquid are dispersed resin-precoated toner particles formed of a pigment or coloring agent precoated with a polymer of an acrylic or methacrylic acid ester of hydrogenated abietyl alcohol.

Electrophotographic liquid developer comprising acrylic or methacrylic

A process is described for the manufacture of a dimensionally stable polyester film support carrying a primer coating for improving the adhesion thereto of subsequently applied coatings, which process comprises applying to an unstretched or only monoaxially stretched polyester film support a layer of a coating composition from an aqueous dispersion, drying said layer, stretching it biaxially or in a direction perpendicular to the said first stretching operation together with the polyester film support and heat-setting the polyester film, wherein said coating composition, before drying and heat-setting, comprises a mixture of:

Dimensionally stable polyester film supports with subbing layer thereon

A process of making a color photographic material comprising a support and a layer comprising gelatin and as a color-coupling agent a water-insoluble homopolymer of a solid water-insoluble ethylenically unsaturated color coupling monomer or a water-insoluble copolymer of said monomer with a water-insoluble ethylenically unsaturated monomer, wherein the color-coupling agent is made by:

Polymerization of monomeric color couplets

Oxazolidines and tetrahydro-1,3-oxazines which are substituted with 3-acryloyl or 3-methacryloyl groups are prepared by adding to an excess of a ketone and in the presence of a hydrogen chloride acceptor, about equimolecular amounts of a 2- or 3-amino lower alkanol and of acryloyl chloride or methacryloyl chloride, heating the mixture, and eliminating the unreacted ketone by destillation. The ketone corresponds to the formula: ##STR1## wherein R.sub.1 = alkyl (1-4 C),

Polymerizable unsaturated oxazolidines and tetrahydro-1,3-oxazines and

Carrier beads for use in an electrostatographic developer mixture comprise a glass core or iron-containing metal core enveloped with a coating of a copolymer of N-vinylcarbazole, trialkoxyvinylsilane and/or triacetoxyvinylsilane and optionally one or both of the monomers of the group consisting of C.sub.1 -C.sub.4 alkyl (meth)acrylate and styrene.

Electrostatographic developers comprising a carrier bead coated with a

The adhesion of hydrophilic layers on a dimensionally stable polyester film support is improved by applying after longitudinal stretching of the polyester film a single adhesive layer thereon. The thus covered polyester film is stretched in transverse direction and heat-setted at 180.degree.-220.degree. C. The adhesive layer comprises 30 to 80 % by weight of a chlorine-containing copolymer, 5 to 30 % by weight of gelatin, 5 to 40 % by weight of a plasticizer for the gelatin and 0 to 30 % by weight of a metal-complexing antistatic agent. The polyester film may be a film of polyethylene terephthalate and the hydrophilic layer applied to the single adhesive layer may be a light-sensitive gelatin silver halide emulsion layer.

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Mortsel, Belgium

Jan J Priem