University of Toronto

Apollo Environmental Systems Corp.

Thor Technology Corporation

Polyphalt Inc.

Powlesland Engineering Limited

Ahlstrom Recovery Inc.

Lep America, Incorporated

Power and Light Sources, Incorporated

Apollo Evironmental Systems Corp.

780863 Ontario Limited

Appollo Environmental Systems Corp.

Desom Engineered Systems Limited

James W Smith

David T Ellenor

John N Harbinson

Silvano Meffe

Peter S Walton

David T R Ellenor

Bruce McKague

Kaj Henricson

Rolf C Ryham

Raymond T Woodhams

Hoc N Tran

Zhi-zhong Liang

Jian E Jiang

William H Powlesland

John Davis

Robert A Barton

Cyril H Knight, Deceased

Nim Y Lee

A radiation-emitting polymer composition includes a polysiloxane polymer including tritium and a wavelength-shifter chemically bonded as a side chain to the polysiloxane polymer or chemically bonded as a side chain to a siloxane carrier dispersed within the polysiloxane polymer. The wavelength-shifter includes a plurality of cyclic chemical moieties and emits electromagnetic radiation in response to radiation emitted by the tritium.

Light-emitting polymer

A light-emitting polymer composition includes a polysiloxane polymer having tritium that emits radiation and a wavelength-shifter chemically bonded to the polysiloxane polymer or a siloxane carrier dispersed within the polysiloxane polymer. The wavelength-shifter emits light in response to the radiation.

Hydrogen sulfide removal process

Stabilized bitumen compositions

Natural gas treatment process

Hydrogen Sulfide is substantially completely removed from a gas stream in a two-stage operation. Hydrogen Sulfide is first partially oxidized to sulfur dioxide and the sulfur dioxide reacted with part of the remaining hydrogen sulfide while the hydrogen sulfide not so reacted is subsequently oxidized, thereby removing all of the hydrogen sulfide from the gas stream.

Process for the removal of hydrogen sulfide from a gas stream

Sodium hydroxide is formed from sodium sulphate by a three step operation comprising converting the sodium sulphate to sodium sulphide, converting the sodium sulphide to sodium bicarbonate, and converting the sodium bicarbonate to sodium hydroxide. The operations preferably are effected in conjunction with a bleached kraft pulp mill operation, so as to utilize by-product sodium sulphate from chlorine dioxide generation to produce useful sodium hydroxide as sulphur without co-producing chlorine.

Process of producing sodium hydroxide from sodium sulphate in a pulp mill

Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a agitated flotation cell. The same principal may be employed with other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases, for example, to treat or strip or react a component of the liquid phase.

Method for effecting gas-liquid contact

The parameters of a gas-liquid contact apparatus for the removal of a component of a gas stream in which an impeller-apertured shroud combination is immersed in a liquid phase to which the gas stream is fed at a gas flow rate of Q. The structural and operating parameters of the apparatus are quantified to provide a Shear Effectiveness Index (SEI) value of from about 1 to about 10 and an Effective Shear Index (ESI) value of from about 1 to about 2500.

Method for determining the parameters of a gas-liquid contact apparatus

Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principal may be employed in other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell is also described. In order to effect mass transfer and rapid reaction gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear. To assist in the reaction, a surrounding shroud has a plurality of openings, generally of aspect ratio of approximately 1, of equal diameter and arranged in uniform pattern, such as to provide a gas flow therethrough less than about 0.02 lb/min/opening in the shroud. In general, the gas velocity index of gas through the openings in the shroud is at least about 18 per second per opening. Each of the openings has an area corresponding to an equivalent diameter of less than about one inch.

Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principle may be employed with other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell also is described. In order to effect efficient mass transfer and rapid reaction, gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear. To assist in the reaction, a surrounding shroud has a plurality of openings, generally of aspect ratio of approximately 1, of equal diameter and arranged in uniform pattern, such as to provide a gas flow therethrough less than about 0.02 lb/min/opening in the shroud. In general, the gas velocity index of gas through the openings in the shroud is at least about 18 per second per opening, preferably at least about 24 per second per opening. Each of the openings has an area corresponding to an equivalent diameter less than about one inch.

Method and apparatus for effecting gas-liquid contact

Hydrogen sulfide or other gaseous component is removed from a gas stream containing the same by distribution of the gas stream in the form of fine bubbles by a rotary impeller and stationary shroud arrangement at a submerged location in an aqueous iron or other transition metal chelate solution, or other suitable catalyst, contained in an enclosed reaction vessel. Sulfur particles, or other insoluble phase product, of narrow particle size range formed in the reaction are floated off from the iron chelate solution. An oxygen-containing gas stream also is distributed in the form of fine bubbles by a separate rotary impeller and stationary shroud arrangement at a separate submerged location in the iron chelate solution. The second submerged location generally is separated from the first by a baffle extending downwardly in the reaction vessel from a top closure towards a bottom closure.

Dual impeller method and apparatus for effecting chemical conversion

Growing community of inventors

Toronto, Canada

James W Smith