Arkema Inc.

W. L. Gore & Associates, Inc.

James Theodore Goldbach

David A Mountz

Andrew P Kahn

Scott R Gaboury

Robert J Umpleby

Ramin Amin-Sanayei

Gregory Scott O'Brien

Anthony Bonnet

Saeid Zerafati

Wengsheng He

Julien Parvole

James J Henry

Sean Michael Stabler

Wai Poon

Jérôme Chauveau

Caiping Lin

Wensheng He

James F Coffey

James Carson Meredith, Iii

Daniel B Kent

James E Copenhafer

Pedro Jose Zapata

Xiaobo Wan

Adam W Hauser

Katharine S Pastore

Pa Nhia Xiong

Wai Sing Poon

Gregory Scott Obrien

Sean M Stabler

James Joseph Henry

James Carson Iii Meredith

The invention relates to novel linear, semi-crystalline, functional fluoropolymers that have been obtained by copolymerizing a fluorinated vinylic monomer and a hydrophilic (meth)acrylic comonomer bearing a halogen functionality.

Functional fluoropolymers

The invention relates to a process to produce a stable fluoropolymer latex using non-fluorinated surfactant with greater thermal stability. The polymerization is run at pressures greater than typically used. The resulting polymer exhibit improved melt color stability as compared to those produced under similar conditions at lower pressures.

Process for making a fluoropolymer dispersion

The invention relates to novel linear, semi-crystalline, functional fluoropolymers that have been obtained by copolymerizing a fluorinated vinylic monomer and a hydrophilic monomer chosen from vinyl alkyl acids, vinyl phosphonates, functional acrylamides, carbonates, vinyl ethers, alkoxy compounds, and double hydrophilic group monomers.

The invention relates to sized reinforcing fibers that comprise a reinforcing fiber sized with a fluoropolymer. The fluoropolymer is functionalized and/or the reinforcing fiber is sized with a compatible functional non-fluorinated polymer that is compatible with the fluoropolymer. Functionalization of the fluoropolymer or the compatible non-fluorinated polymer provides enhanced properties, such as increased adhesion to the reinforcing fiber.

High strength polyvinylidene fluoride based sized reinforcing fibers

The present invention pertains to a non-linear, copolymer comprising recurring units derived from vinylidene fluoride (VDF) monomer, at least one functional comonomer and optionally at least one fluorinated ethylenic comonomer. The non-linear fluorinated copolymer comprises from 0.01 to 3.0% by moles of recurring units derived from functional comonomer. The non-linear fluorinated copolymer can be used as electrode binder in batteries.

Non-linear vinylidene fluoride copolymers

The invention relates to fluoropolymer composites having a fluoropolymer matrix containing a functionalized fluoropolymer composition, and reinforced with fibers. The fibers can be chopped fibers, long fibers, or a mixture thereof, and the fluoropolymer matrix preferably is based on polyvinylidene fluoride. Any type of fibers, sized or unsized may be used with the functionalized fluoropolymer matrix composition to form the fluoropolymer composite.

High strength polyvinylidene fluoride composite

The invention relates to very high melt flow fluoropolymer compositions, having low melt viscosities. The fluoropolymers have low molecular weights of from 5 kDa to 200 kDa and melt viscosities of less than 2 kilopoise (kP) at 232&#xb0; C. and 100 s. One use for the high melt flow fluoropolymers is in the formation of very small diameters fibers, useful for melt-blown non-woven materials. Fiber diameters of less than 9 microns, and preferably 500 to 2000 nm can be produced.

High melt flow fluoropolymer composition

The invention relates to a novel synthesis method for forming superacid functional molecules that include monomers, as well as new polymers and copolymers formed from the monomers, and uses for these superacid molecules, polymers, and copolymers. The superacid molecules have an alpha, alpha-difluorosulfonic acid functionality that can be obtained by a reaction between various Grignard reagents and an alkyl(2-fluorosulfonyl)-1,1-difluoroacetate, such as methyl (2-fluorosulfonyl-1,1-difluoroacetate. The molecules, polymers and copolymers would be expected to have enhanced ion conductivity, and would be useful in a variety of applications, including as ion-conductive materials, surfactants, and ion exchange resins.

Superacid functional compounds

Composite filter media which are highly resistant to thermal degradation and retain filter efficiency and extended lifetime in high temperature environments are disclosed. Methods of making the filter media are also disclosed. A composite filter media for removal of particles from a gas stream includes a layer of a porous polymeric membrane, the layer having an upstream side and a downstream side relative to the direction of the gas stream; and at least one layer of an electrostatic microfiber web containing an antioxidant in an amount ranging from about 0.1% to about 10% by weight; the at least one layer of microfiber web disposed on the upstream side of the porous polymeric membrane layer.

Heat stabilized composite filter media and method of making the filter media

The invention relates to composite blend membranes formed from blends of one or more polyelectrolytes, and one or more types of nanoparticles. Preferably the blend also includes one or more fluoropolymers. The addition of the nanoparticles was found to enhance the conductivity and mechanical properties of the membranes.

Organic/inorganic composite blend membrane compositions of polyelectrolye blends with nanoparticles

The invention relates to polyelectrolytes having backbone aromatic groups, and in particular to aromatic backbone group polyelectrolytes having high levels of sulfonation as well as cross-linking functionality. Preferably the polyelectrolyte backbone is free of linear alkyl groups.

High temperature stable polyelectrolytes having backbone aromatic groups

The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.

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Paoli, PA, United States of America

James Theodore Goldbach