Exxon Chemical Patents, Inc.

Other

Exxon Research and Engineering Company

James R Looney

Dennis A Williams

Lee A McDougall

Phyllis K Holifield

Daniel S Sullivan, Iii

John A Haslegrave

Robert A Swenson

Niall Carruthers

Paul J Clewlow

Michael W Conway

Brent I Bourland

Terence M O'Brien

Elemental iodine is used to improve the performance of conventional corrosional inhibitors in oil field acidizing operations. The iodine, because of its solubility, may be used in a formulation which includes a corrosion inhibitor and surfactants dissolved in a suitable organic solvent.

Intensified corrosion inhibitor and method of use

A coalbed formation is stimulated to improve the recovery of methane which involves injecting into the coalbed formation an aqueous acid solution containing an organic amphoteric tertiary ammonium compound having from 1 to 3 tertiary ammonium groups, each N of which contains at least one C.sub.3 to C.sub.4 unsaturated carboxylic acid group, and wherein the compound contains a terminal benzyl or C.sub.5 -C.sub.19 alkyl group.

Stimulation of coalbed methane production

A method of acidizing a subterranean formation with an acqueous acid solution wherein the acid solution contains corrosion inhibiting amounts of an amine derivative prepared by reacting an unsaturated carboxylic acid with (a) fatty amine or polyamine, or (b) a fatty amido amine or polyamine, or (c) a fatty imidazoline amine or polyamine. The derivative is characterized by the absence of primary amino groups, and preferably contains only tertiary amino groups.

Amine derivatives as corrosion inhibitors

An acid system for acidizing wells contains corrosion inhibitor additives which consist essentially of a metal selected from antimony and antimony mixtures, a quaternary compound, and a surfactant. The corrosion inhibitor is free of toxic acetylenic compounds.

Inhibited acid system for acidizing wells

Corrosion inhibitor additives are added directly to an aqueous acid solution used in acidizing subterranean formations. The additives comprise a bismuth compound, a quaternary compound, and a surfactant. The corrosion inhibitor is free of toxic Sb and acetylenic compounds.

Method of inhibiting corrosion in acidizing wells

A corrosion inhibitor for an acid well treating composition includes first metal ions including Sb, Cu, and Bi complexed with a quaternary ammonium compound and second metal ions complexed with a quaternary ammonium compound. The complexed compounds may be prepared and introduced into the acid or the first metal ions may be introduced directly into the acid system.

Corrosion inhibitor and method of use

Corrosion inhibitor additives are added directly to an aqueous acid solution used in acidizing subterranean formations. The additives consist essentially of a metal selected from antimony and antimony mixtures, a quaternary compound, and a surfactant. The corrosion inhibitor is free of toxic acetylenic compounds.

A corrosion inhibitor formulation for use in well treatig acids includes a highly polar aprotic solvent having dissolved therein (a) a complex of a metal compound and a quaternary ammonium compound and (b) a dispersant capable of dispersing the complex in the well treating acid solution.

An anti-sludge agent useful for acid stimulated hydrocarbon containing formations is an ester of sulfonic acid, e.g. monoethoxylated dodecyl benzene sulfonic acid, preferably used in combination with from 0.1 to 2 parts by weight of a surfactant.

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Houston, TX, United States of America

James R Looney