The Dow Chemical Company

James R Gross

Russell T McFadden

George E Ham

James L Potter

Kevin F Dick

Bobby Leroy Atkins

Robert Niles Bashaw

Frederick Bernhard Kassell

Phosgene is removed from an off gas containing phosgene by contacting the off gas with an aqueous solution containing alkali metal hydroxide and a tertiary amine compound having 3 to 20 carbon atoms. The concentration of the alkali metal hydroxide can vary from 1 to 25 weight percent and the concentration of the tertiary amine can be any amount which is effective in the contact apparatus chosen. The amines found to be useful are trialkyl amines having 1 to 4 carbon atoms and pyridines having 0 to 3 alkyl groups of 1 to 5 carbon atoms and diamines such as 4-dimethylaminepyridine.

Phosgene removal process

Absorbent articles are rendered more blood absorptive by incorporating water soluble amido compounds having the formula

Absorbent article having enhanced blood absorption

Polycarbonates are prepared in homogeneous solutions from dihydric phenols and phosgene wherein the stoichiometric end point for the addition of phosgene is accurately controlled by using 4-(p-nitrobenzyl) pyridine as a colorometric indicator for the end point in a series of samples of the reaction solution.

Preparation of polycarbonates in a homogeneous solution

Water absorbent articles, made from solutions of carboxylic polyelectrolytes, together with methods for their preparation, and a composition useful to make said articles are disclosed. The articles are cured and/or crosslinked with monomeric amine-epihalohydrin adducts by heating and/or removing substantially all of the solvent from the precursor composition. The absorbent articles are useful as surgical sponges, diapers, tampons, meat trays, bath mats and the like.

Absorbent articles cured with amine-epihalohydrin adducts

Water swellable absorbent articles, made from latexes having a copolymerized crosslinker, together with methods for their preparation, and a composition containing a copolymerized crosslinker useful to make said articles are disclosed. The articles are crosslinked by heating and/or removing substantially all of the water from the precursor composition. The absorbent articles are useful as surgical sponges, diapers, tampons, meat trays, bath mats and the like.

Absorbent articles made from latexes of carboxylic synthetic

Water swellable absorbent articles, made from copolymers having a copolymerized crosslinker, together with methods for their preparation, and a composition containing a copolymerized crosslinker useful to make said articles are disclosed. The copolymers comprise 25-98% by weight of an alkali metal salt of an olefinically unsaturated monosulfonic or monocarboxylic acid, about 2-50% by weight of an olefinically unsaturated monocarboxylic acid and about 0.1-5.0% by weight of an N-substituted acrylamide or methacrylamide. The articles are crosslinked by heating and/or removing substantially all of the water from the precursor composition. The crosslinked compositions, in the form of a film, can be disintegrated to form flakes, strips or powders. The absorbent articles are useful as surgical sponges, diapers, tampons, meat trays, bath mats and the like.

Substantially dry water swellable particulate polyelectrolyte

Water swellable absorbent articles, made from copolymers having a copolymerized crosslinker, together with methods for their preparation, and a composition containing a copolymerized crosslinker useful to make said articles are disclosed. The copolymers comprise 25-98% by weight of an alkali metal salt of an olefinically unsaturated monosulfonic or monocarboxylic acid, about 2-50% by weight of an olefinically unsaturated monocarboxylic acid and about 0.1-5.0% by weight of an N-substituted acrylamide or methacrylamide. The articles are crosslinked by heating and/or removing substantialy all of the water from the precursor composition. The absorbent articles are useful as surgical sponges, diapers, tampons, meat trays, bath mats and the like.

Films and absorbent articles made from copolymers having a copolymerized

Water swellable polyacrylate articles are made from a solution of the polyacrylate having an effective amount of a soluble crosslinking agent therein by heating and/or drying the solution. The polyacrylate solution is made from a polyacrylate by saponification and the crosslinking agent is then added.

Flexible water swellable crosslinked polyacrylate film

Water swellable absorbent articles, made from copolymers having a copolymerized crosslinker, together with methods for their preparation, and a composition containing a copolymerized crosslinker useful to make said articles are disclosed. The articles are crosslinked by heating and/or removing substantially all of the water from the precursor composition. The absorbent articles are useful as surgical sponges, diapers, tampons, meat trays, bath mats and the like.

Absorbent articles made from carboxylic synthetic polyelectrolytes

Water swellable absorbent articles, made from polyelectrolytes, containing free carboxylic groups, together with methods for their preparation, and a composition useful to make said articles are disclosed. The composition contains bis-oxazolines or bis imino oxazolidines. The articles are crosslinked by heating and/or removing substantially all of the water from the precursor composition. The absorbent articles are useful as surgical sponges, diapers, tampons, meat trays, bath mats and the like.

Absorbent articles made from carboxylic polyelectrolyte solutions

Water swellable absorbent articles, made from carboxylic polyelectrolytes, together with methods for their preparation, and a composition useful to make said articles are disclosed. The articles are crosslinked by heating and/or removing substantially all of the water from the precursor composition. The absorbent articles are useful as surgical sponges, diapers, tampons, meat trays, bath mats and the like.

Absorbent articles and methods for their preparation

Process for spinning absorbent articles from copolymers having a

Water swellable articles

A method for the preparation of aqueous solutions of anionic polyelectrolytes by combining a stream of a high solid content alkenoic acid-alkyl acrylate latex with a stream of aqueous alkali metal hydroxide, mixing the combined streams under low shear conditions and heating the mixture to produce a polyelectrolyte solution. The use of these steps avoids the formation of high viscosity mixtures or rubber masses which are difficult, if not impossible, to further process into the desired polyelectrolyte solution.

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Lake Jackson, TX, United States of America

James R Gross