Eastman-kodak Company

Bruker Biospin Gmbh

Carestream Health, Inc.

James R Bennett

Dennis E Smith

Mridula Nair

Yongcai Wang

Douglas E Bugner

Mary Christine Brick

Charles E Romano, Jr

Louis J Sorriero

Xiqiang K Yang

Jeffrey W Leon

John W Harder

Rajesh Vinodrai Mehta

Robert A Guistina

John F Bishop

David A Stegman

David F Jennings

William J Harrison

David A Czekai

Sharon M Melpolder

Richard C VanHanehem

Ruizheng Wang

Paul E Woodgate

Peter David Rollinson

Hans F Schmitthenner

Brian J Kelley

Patrick M Jeffries

Tao Ji

Yonghong Yang

David Alan Stegman

John William Harder

Brian Joseph Kelley

Jeffrey Wade Leon

William James Harrison

A method of making a high density organic polymeric particle, suitable for use in milling, includes the steps of: providing an oil phase including a high density metal, a metal modifying agent, a cross-linkable organic monomer mixture, and an oil soluble polymerization initiator; admixing the oil phase under high shear conditions in an aqueous medium to produce droplets of the oil phase in the aqueous medium; and adding a hydrocolloid to the aqueous medium containing the droplets of the oil phase. The method further includes polymerizing the droplets of the oil phase to produce high density organic polymeric particles comprising a cross-linked polymer host matrix and a high density metal wherein the high density metal is within the interior of the cross-linked polymer host matrix.

Making high density polymer particles

The present invention relates to a loaded particle comprising at least one fluorescent dye, and in particular, a fluorescent dye with a large Stokes shift. The invention further relates to a method for producing an loaded latex particle, loaded with a fluorescent dye having a large stokes shift. In addition, the present invention relates to latex particles loaded with fluorescent dyes that are organic solvent soluble and insoluble in water. In a preferred embodiment, when the dyes are loaded into the water soluble latex particle, an increase is observed in quantum yield of fluorescence as compared to the quantum yield of the dye in aqueous solvent.

Loaded latex optical molecular imaging probes containing lipophilic large stokes shift dyes

A high density polymer particle includes a cross-linked organic polymer host matrix; and a high density metal provided within the interior of the cross-linked organic polymer host matrix.

High density polymer particles and dispersion of same

A process for forming polymer particles with aligned pores and controlled narrow particle size distribution, including: a) forming an oil phase by dissolving a polymeric binder in a solvent; b) dispersing the oil phase into a water phase containing a controlled amount of particulate stabilizer and forming an oil-in-water emulsion of controlled narrow dispersed oil phase droplet size distribution; c) freezing the emulsion to freeze solvent in the oil droplets to form frozen solvent domains within the polymeric binder, and also the water in the continuous water phase; and d) removing the frozen solvent from the polymeric binder and the frozen water in the continuous water phase, thereby forming porous polymer particles of controlled narrow particle size distribution and containing directional aligned non-spherical pore structures. Optionally, the porous particles may contain encapsulated functional ingredients.

Process for preparing porous polymer particles

The present invention is a method of manufacturing porous polymer particles comprising: forming a dispersion of porous polymer particles in an external aqueous phase, wherein individual porous particles each comprise a continuous polymer phase and internal pores containing an internal aqueous phase; and filtering the dispersion of porous polymer particles with a filter to remove the external aqueous phase, wherein the filtering is done while agitating the porous particles.

Method of filtering porous particles

Thermally processable imaging element

Process for preparing an ink jet ink

The present invention provides a photographic element comprises a support, at least one hydrophilic light-sensitive layer, and a light-insensitive layer containing a binder and polymer matte particles having the formula:

Photographic elements containing elastomeric matting agent

A process of forming milled solid particles of a compound comprising milling solid particles of the compound in a liquid organic medium continuous phase in the presence of polymeric milling media to reduce the average size of the compound particles, wherein the liquid continuous phase comprises a solvent for the milling media polymer in the uncrosslinked form and the milling media is crosslinked sufficiently to prevent 50 vol. % swelling of the polymeric milling media in the liquid continuous phase within four hours at 25.degree. C. In various preferred embodiments of the invention, polymeric milling media having a mean particle size of less than about 100 .mu.m in the unswelled state (i.e., prior to addition to the liquid organic continuous phase) is used; the compound particles are milled to an average particle size of less than 100 nm; the compound comprises electrophotographic toner pigment; the liquid continuous phase comprises an ethylenically unsaturated polymerizable monomer; and the milling media polymer comprises polymerized styrene and divinylbenzene monomers. In an additional preferred embodiment of the invention wherein the compound comprises electrophotographic toner pigment and the liquid organic medium continuous phase comprises an ethylenically unsaturated polymerizable monomer, electrophotographic toner particles are formed by polymerizing the ethylenically unsaturated polymerizable monomer after the toner pigment compound is milled. It is a particularly advantageous feature of this invention that there is provided a method of preparing extremely fine solid particles of a compound free of unacceptable contamination and/or discoloration using polymeric milling media in a liquid continuous phase which is an effective solvent for the milling media polymer in uncrosslinked form. It is a further advantage of the invention to allow for preparing electrophotographic toner particles directly from a milled toner pigment particle dispersion without first needing to separate the milled particles from the liquid milling medium continuous phase. The ability to form extremely fine, e.g., less than 100 nm, size pigment particles in accordance with the invention is especially advantageous where toner particles are subsequently formed by suspension polymerization of ethylenically unsaturated monomers after milling of the pigment particles.

Method to media mill particles using crosslinked polymer media and

Particles of compound useful in imaging elements are milled using a milling media comprising a polymeric resin. The use of polymeric milling media permits the production of particles having an average particle size less than 1 micron. Further, the resulting particles are free from the contamination resulting from conventional milling media of, for example, glass, ceramic or steel.

Milling a compound useful in imaging elements using polymeric milling

A limited coalescence method of making polymer particles having an average particle size of 3 .mu.m or less comprising dispersing the polymer particles in an organic liquid diluent after they are separated from the aqueous suspension medium in which they are prepared, to thereby eliminate or substantially avoid agglomeration between the polymer particles upon drying.

Limited coalescence process

Growing community of inventors

Rochester, NY, United States of America

James R Bennett