Danisco A/s

Synuthane International, Inc.

Dupont Nutrition Biosciences Aps

James O'Connor

Kenneth Knoblock

Charles Nichols

Robin L Grieve

David D Russell

Alexander McLauchlin

Donald L Lickei

The invention relates to a foamed isocyanate-based polymer derived from a reaction mixture comprising an isocyanate, an active hydrogen-containing compound, a blowing agent and a highly branched polysaccharide which is derivatized with at least two esters of different length. Further the invention relates to a mix and a process for the production of isocyanate-based polymer. The mix for the production of a foamed isocyanate-based polymer comprises a mixture of the derivatized polysaccharide of the invention and an active hydrogen-containing compound. The process for producing a foamed isocyanate-based polymer comprises the steps of: contacting an isocyanate, an active hydrogen-containing compound, the derivatized highly branched polysaccharide of the invention and a blowing agent to form a reaction mixture and expanding the reaction mixture to produce the foamed isocyanate-based polymer. The derivatized highly branched polysaccharide of the invention has an active hydrogen functionality of less than 15 and comprises randomly bonded glucopyranose units, having an average number of 10-100 glucose residues.

Foamed isocyanate-based polymer, a mix and process for production thereof

The invention relates to a foamed isocyanate-based polymer derived from a reaction mixture comprising an isocyanate, an active hydrogen-containing compound, a blowing agent and a highly branched polysaccharide which is derivatized to provide a hydrophobicity which renders it compatible with a polyether polyol with which the underivatized polysaccharide is incompatible. Further the invention relates to a mix and a process for the production of isocyanate-based polymer. The mix for the production of a foamed isocyanate-based polymer comprises a mixture of the derivatized polysaccharide of the invention and an active hydrogen-containing compound. The process for producing a foamed isocyanate-based polymer comprises the steps of: contacting an isocyanate, an active hydrogen-containing compound, a derivatized highly branched polysaccharide and a blowing agent to form a reaction mixture and expanding the reaction mixture to produce the foamed isocyanate-based polymer. The derivatized highly branched polysaccharide of the invention has an active hydrogen functionality of at least 15 and comprises randomly bonded glucopyranose units, having an average number of 10-100 glucose residues.

The invention relates to a polyurethane obtainable by reacting a polyisocyanate and a polyol composition comprising a highly branched polysaccharide of randomly bonded glucopyranose units or an alkoxylated derivative of the same. The polysaccharide has an average number of 10&#x2013;100 glucose residues and said polysaccharide and derivative both have an average functionality of 30 or more. The invention also relates to a process for the production of such a polyurethane as well as a mix for the production of a polyurethane comprising a polyol composition, comprising 2&#x2013;100 % of a highly branched polysaccharide, at least one catalyst and at least one surfactant.

Polyurethane containing a polyol composition comprising a highly branched polysaccharide, mix and process for preparation thereof

Double metal cyanide catalysts containing polyglycol ether complexing agents

A process for making polyether polyols employing a double metal cyanide (DMC) catalyst with specific low molecular weight polyether polyols as starters in combination with specific reaction conditions and impurity levels.

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Cheshire, CT, United States of America

James O'Connor