Bayer Corporation

Mobay Chemical Corporation

Mobay Corporation

James N Rieck

Sivaram Krishnan

James W Rosthauser

Karl W Haider

Robert Allen Pyles

Richard S Pantone

Robert P Yeater

Jeffrey F Dormish

Randall C Rains

Jack C Chan

Susan A Stanton

Pia I Santelices

Joseph M Jupa

William G Curtis

Eric C Ma

A process for making a photochromic optical lens is disclosed. In a first embodiment of the process a multi-plied laminate, containing a ply of photochromic thermoplastic polyurethane (herein &ldquo;TPU&rdquo;) and a ply containing thermoplastic polycarbonate, is first placed in the cavity of a suitable mold. The ply that contains polycarbonate resin is placed facing the cavity. Thermoplastic polycarbonate resin is then injected into the cavity. In a second embodiment, referred to as an over-mold method, polycarbonate is first injection molded into a molding cavity to form a substrate. Photochromic TPU is, in a subsequent step, injected into the cavity to form a superstrate overlay. In both embodiments, the articles thus molded are suitable for the preparation of optical lenses.

Process for preparing a photochromic lens

The present invention relates to a novel photochromic polyurethane consisting essentially of an isocyanate reactive mixture consisting essentially of: i) from about 40 to about 85% by weight of one or more polyols having a nominal functionality of from 2 to 4 and molecular weights of from 500 to 6000 g/mole; ii) from about 15 to about 60% by weight of one or more diols or triols or mixtures thereof having a functionality of from 2 to 3 and molecular weights of from 62 to 499; b) an aliphatic polyisocyanate having a functionality ranging from about 2 to about 3; and c) a photochromic compound selected from a group consisting of spirooxazines, fulgides, fulgimides, and naphthopyrans, wherein the photochromic compound is present in an amount of 0.01 to 5 parts per hundred parts by weight of the isocyanate reactive mixture.

Photochromic polyurethanes

Blooming in certain thermoplastic polyurethane products is substantially or completely eliminated by including a chain terminator. More specifically, at least one hydroxy functional polyester polyol having a molecular weight of at least 500 and a hydroxyl functionality of at least 2, a chain extender and an organic diisocyanate are combined with a chain terminator. The chain terminator which is preferably a monofunctional compound that is reactive with an isocyanate. These reactants are used in amounts such that the of NCO/H index of the formulation is at or near 100.

Bloom-free thermoplastic polyurethane compositions

The present invention is related to a structural member comprising a laminate and an adhesive where said adhesive is the reaction product of (a) 100 parts by weight of at least one hydroxy functional material having a molecular weight of at least 300 and a hydroxy functionality of at least 2 which material is preferably selected from the group consisting of polyether polyols, polyester polyols, polyester amide polyols, and polycarbonate polyols, (b) 0.2 to 20 parts by weight of an aliphatic, aromatic and/or a cycloaliphatic diamine or triamine, and (c) an organic isocyanate in an amount sufficient to render the isocyanate index between about 70 and about 150, wherein said component (c) is not prereacted with any of the components (a) and (b). In a preferred embodiment, there is included up to 50 parts by weight of component (d) which is an aliphatic polyol having a functionality of at least 2 and a molecular weight of below 300. Also in the preferred embodiment, component (c) is not prereacted with any of (a), (b) and (d).

Two component polyurethane adhesive

The present invention is directed to a polyol mixture comprising the reaction product of at least two polyols which normally are incompatible with each other and an organic isocyanate, the isocyanate to hydroxyl equivalent ratio being from 1:4 to 1:35.

Conversion of incompatible mixed polyols to polyol products with

A novel polyether polyurethane polymer comprising the reaction product of an organic diisocyanate and a linear polyhydroxyl polyether having a molecular weight of less than 8000 and from 0.01 to 1%, by weight, of finely-divided inorganic particles is described, together with a process for producing a cast elastomer by reacting this polymer with a cross-linking or chain-extending agent.

Polyether polyurethane prepolymers containing finely divided inorganic

The present invention is directed to a liquid, diphenylmethane diisocyanate composition having an isocyanate functionality of greater than 2.0 and having an isocyanate group content of from about 20 to about 30 percent by weight prepared by reacting:

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Wheeling, WV, United States of America

James N Rieck