USA As Represented by Secretary of the Navy

James M Hoover

Geoffrey Andrew Lindsay

Robert C Hall

John D Stenger-Smith

Kenneth Joseph Wynne

Andrew P Chafin

Ronald A Henry

Geoffry A Lindsay

Ronald A Henry, Deceased

Second-order nonlinear optical polymeric films, including alternating monlecular layers of two head-to-head, mainchain, amphophilic, chromophoric polymers, one polymer having the electron donating end of the chromophore attached to hydrophilic groups, and the other polymer having the electron donating end of the chromophore attached to hydrophobic groups, and methods of fabricating the films for use in optonics.

Multilayer second-order nonlinear optical films of head-to-head,

Coumarin dyes such as alkylaminocoumarincarboxamides which have functional hydroxyl groups or which are chemically attached to vinyl monomers such as methacrylic acid. The dyes which are chemically attached to vinyl monomers can be copolymerized, e.g. with acrylic monomers to produce a coumarin dye-containing polymer. The dyes which have functional hydroxyl groups can be reacted with an existing polymer or copolymer, e.g. a copolymer of styrene and acrylic acid to esterify the acid groups of the polymer to form a coumarin dye-containing polymer. Such coumarin dye-containing polymers are formed into films and fibers which when poled in an electric field yield a film or fiber with nonlinear optical properties.

Coumarin dyes and side-chain coumarin dye-substituted polymers which

Comb-shaped polymers, comprised of hydrophilic backbones and dye-containi hydrophobic side chains are fabricated into multilayered, polarized, noncentrosymmetric, thin films by means of Langmuir-Blodgett processing techniques. These films exhibit harmonic, generated by shining a laser through the film, increases quadratically with the number of layers of polymeric dye in the film.

Polarized thin films from dye-substituted polymers containing

Comb-shaped polymers, comprised of hydrophilic backbones and dye-containi hydrophobic side chains are synthesized for use in multilayered, noncentrosymmetric, thin films by means of Langmuir-Blodgett processing techniques. The second harmonic signal generation exhibited by these films increases quadratically with the number of layers of polymeric dye in the film.

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Ridgecrest, CA, United States of America

James M Hoover