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The United States of America As Represented by the Administrator of the

James M Beggs

Robert J Mattauch

Michael Philip Goldowsky

Taylor G Wang

Alan C Seabaugh

Philip A Studer

Demetrius A Kourtides

Daniel D Elleman

Daniel B Leiser

David A Stewart

Daniel D Lawson

John A Mikroyannidis

Kenji Nishioka

John W Redmon, Jr

Howard E Goldstein

Eldon L Jeffers

Donald B Bickler

William H Corcoran

Richard L Brooks

Alexander Daniels

Allan Sherman

Max G Gasser

William S Fong

Puvin Pichaichanarong

Paul C Chan

David A Nibley

Gordon Green

Jerry M Saunders

Archie D Coleman

Garland D Johnston

Joseph N Portwood

Allen C Porter

The subject invention pertains to a novel class of fire- and heat-resistant bisimide resins prepared by thermal polymerization of maleimido or citraconimido substituded 1-[(dialkoxyphosphonyl)-methyl]-2-4 and -2,6-diaminobenzenes. Typical polymer presursors have the chemical structure: ##STR1## wherein R is alkyl, substituted alkyl or aryl, and R.sup.1 is hydrogen or lower alkyl. The polymer precursors are prepared by reacting 1-[(diorganooxyphosphonyl)methyl]-2-4 and -2,6-diaminobenzenes with maleic anhydride or citraconic anhydride in a mole ratio 1:2. Chains extension of the monomers is achieved by reacting the mono-N-maleimido derivatives of 1-[(diorganooxyphosphonyl)methyl]-2,4 and -2,6-diaminobenzenes with aryl tetracarboxylic dianhydrides, such as benzophenone tetracarboxylic diandydride, or aryl diisocyanates, such as methylenebis(4-phenylisocyanate), in a mole ratio 2:1. The polymerization of the monomers is studied by differential scanning calorimetry (DSC) and the thermal stability of the polymers is ascertained by thermogravimetric analysis (TGA).

Fire and heat resistant laminating resin based on maleimido and

A method and a system for testing the bonding of foam insulation (22) attached to metal. The system involves the use of an impacter (10) which has a calibrated load cell (12) mounted on a plunger (14) and a hammer head (16) mounted on the end of the plunger (14). When the impacter (10) strikes the insulation (22) at a point to be tested, the load cell (12) measures the force of the impact and the precise time interval during which the hammer head (16) is in contact with the insulation (22). This information is transmitted as an electrical signal (20) to a load cell amplifier (28) where the signal (20) is conditioned and then transmitted to a Fast Fourier Transform (FFT) analyzer (34). The FFT analyzer (34) produces energy spectral density curves (power plotted against frequency in Hertz) which are displayed on a video screen (39). An operator, by observing the frequency point at which the curve terminates, may determine the quality of the bond. Specifically, the termination frequency of the energy spectral density curve may be compared with a predetermined empirical scale to determine whether a high quality bond, good bond, or debond is present at the point of impact. For future reference and use, data from the FFT analyzer (34) are recorded on a magnetic disk (41) and/or a hard copy is produced by a printer (43).

Insulation bonding test system

A long lifetime Stirling cycle cryogenic cooler particularly adapted for space applications comprised of a compressor section (10) centrally aligned end to end with an expansion section (12) and respectively including a reciprocating compressor piston (14) and displacer (16) radially suspended in interconnecting cylindrical housings (18, 20) by active magnetic bearings (26, 28, 30, 32) and having adjacent reduced clearance regions (82, 84, 108) so as to be in non-contacting relationship therewith and wherein one or more of these regions operate as clearance seals. The piston (14) and displacer (16) are reciprocated in their housings (18, 20) by linear drive motors (48, 52) to vary the volume of respectively adjacent compression and expansion spaces (44, 46) which contain a gaseous working fluid and a thermal regenerator (95) to effect Stirling cycle cryogenic cooling. Electrical circuit means (140, 142) are additionally included for energizing the magnetic bearings (26, 28, 30, 32) and for controlling the stroke amplitudes and relative phase angle between the compressor piston (14) and displacer (16) during the cooling cycle.

Stirling cycle cryogenic cooler

Contact electrodes on a semiconductor device (50) such as a photovoltaic solar cell is formed by screening through a mask (38) onto a surface (40) a pattern of ink containing a dispersion of lower melting, sinterable metal (tin) coated base metal (copper) particles dispersed in a liquid vehicle including a vaporizable binder polymer and a fluorocarbon polymer. On firing the screen coated device (46) in an oven (48) the binder polymer is vaporized, the fluorocarbon vapors etch the surface and the coated metal particles sinter without being oxidized to form an adherent, coherent, contact electrode (53).

Electrodes for solid state devices

The yield of organic extract from the supercritical extraction of coal with larger diameter organic solvents such as toluene is increased by use of a minor amount of from 0.1 to 10% by weight of a second solvent such as methanol having a molecular diameter significantly smaller than the average pore diameter of the coal.

Supercritical multicomponent solvent coal extraction

A method and apparatus are disclosed for determining the concentration of coliform bacteria in a sample. The sample containing the coliform bacteria is cultured in a liquid growth medium. The cultured bacteria produce hydrogen and the hydrogen is vented to a second cell containing a buffer solution in which the hydrogen dissolves. By measuring the potential change in the buffer solution caused by the hydrogen, as a function of time, the initial concentration of bacteria in the sample is determined. Alternatively, the potential change in the buffer solution can be compared with the potential change in the liquid growth medium to verify that the potential change in the liquid growth medium is produced primarily by the hydrogen gas produced by the coliform bacteria.

Method for detecting coliform organisms

A high temperature stable and solar radiation stable thermal control coating either useful as such, applied directly to a member to be protected, or applied as a coating on a re-usable surface insulation (RSI) has a base coat layer and an overlay glass layer. The base coat layer has a high emittance, and the overlay layer is formed from discrete, but sintered together glass particles to give the overlay layer a high scattering coefficient. The resulting two-layer space and thermal control coating has an absorptivity-to-emissivity ratio of less than or equal to 0.4 at room temperature, with an emittance of 0.8 at 1200.degree. F. It is capable of exposure to either solar radiation or temperatures as high as 2000.degree. F. without significant degradation. When used as a coating on a silica substrate to give an RSI structure, the coatings of this invention show significantly less reduction in emittance after long term convective heating and less residual strain than prior art coatings for RSI structures.

High temperature glass thermal control structure and coating

A method is described for forming sharp tips on thin wires, in particular phosphor bronze wires of diameters such as one-thousandth inch used to contact micron size Schottky barrier diodes, which enables close control of tip shape and which avoids the use of highly toxic solutions. The method includes dipping and end (12) of a phosphor bronze wire (14) into a dilute solution (16) of sulfamic acid and applying a current through the wire to electrochemically etch it. The humidity in the room is controlled to a level of less than 50%, and the voltage applied between the wire (14) and another electrode (18) in the solution is a half wave rectified voltage. The current through the wire is monitored, and the process is stopped when the current falls to a predetermined low level.

Thin wire pointing method

A controlled in situ etch-back technique is disclosed in which an etch melt 17 and a growth melt 18 are first saturated by a source-seed crystal 15 and thereafter etch-back of a substrate 14 takes place by the slightly undersaturated etch melt, followed by LPE growth of a layer by the growth melt, which is slightly supersaturated.

Controlled in situ etch-back

A system is described for forming hollow spheres containing pressured gas, which includes a cylinder device (14) containing a molten solid material (20) and having a first nozzle (18) at its end, and a second gas nozzle (24) lying slightly upstream from the tip of the first nozzle and connected to a source (26) that applies pressured filler gas that is to fill the hollow spheres. High pressure is applied to the molten metal, as by moving a piston (22) within the cylinder device, to force the molten material out of the first nozzle and the same time pressured gas fills the center of the extruded hollow liquid pipe that breaks into hollow spheres (12a). The environment (54) outside the nozzles contains gas at a high pressure such as 100 atmospheres, the gas is supplied to the gas nozzle (24) at a slightly higher pressure such as 101 atmospheres, and the pressure applied to the molten material (20) is at a still higher pressure such as 110 atmospheres.

Method and apparatus for producing gas-filled hollow spheres

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James M Beggs