Bayer Aktiengesellschaft

James M Barnes

Wilhelm Goyert

Hanns P Muller

Gerhard Grogler

Peter Haas

Richard Kopp

Gert Jabs

Heinrich Hess

Manfred Dahm

Holger Meyborg

Herbert Salzburg

Norbert Weimann

Ulrich Nehen

Albert Awater

Klaus Konig

Kuno Wagner

Otto Ganster

Andreas Ruckes

Robert Eiben

Wolfgang Grimm

Werner Betz

The present invention relates to a process for the preparation of a modified 1,5-naphthylene diisocyanate containing urea and biuret groups comprising reacting

Process for the preparation of highly elastic plastics

Polyether polycarbonate diols based on 1,6-hexanediol and having a molecular weight of from 500 to 12,000 are made by etherifying 50-100 mole % 1,6-hexane-diol in the presence of 0-50 mole % of specified diols and reacting the resultant polyether with a compound selected from diarylcarbonates, dialkyl carbonates, dioxolanones, hexanediol bischlorocarbonic acid esters, phosgene and urea. These diols are particularly useful in the production of polyurethanes having improved physical properties.

Polyether-polycarbonate diols and processes for their production and use

The present invention is directed to a process for the continuous production of articles or coatings with contours wherein a liquid material is introduced at one end into the mold cavity formed between at least two travelling continous shaping faces, said material being cured in the mold cavity and subsequently removed from the mold, characterized in that (i) the travelling faces are moved downwards at least in the region of the material feed, (ii) the stream of material supplied is moved to and fro transversely to the direction of advance of the faces, and (iii) the quantity of material supplied is controlled so as to fill the mold cavity with a uniform coating and an apparatus for use therein.

Process for the continuous production of articles or coatings with

The present invention relates to 2,3,2',3'-bis-morpholine derivatives corresponding to the formula ##STR1## The present invention also relates to a process for the preparation of these derivatives and to their use as hydrolysis protective agents for synthetic polymers containing ester groups and/or carbonate groups. Preferred synthetic polymers are polyurethanes.

Bismorpholines, a process for their preparation and their use for

The present invention is directed to a process for the production of suspensions of finely-divided polyisocyanates which are obtainable by the surface reaction with from 0.1 to 25 equivalent percent of reactive group per NCO of stabilizers in relatively high molecular weight polyols and/or relatively high molecular weight polyamines having molecular weights from 400 to 6,000 optionally with addition of lower molecular weight polyols and/or aromatic amines having molecular weights of from 60 to 399, which are characterized in that unreacted quantities of stabilizers in the suspension are subsequently partially or completely deactivated by addition of substances having an acylating and/or neutralizing and/or alkylating effect and/or adsorbing effect as 'deactivators'. In particular, mono- and/or polyisocyanates are used as 'deactivators'. Deactivated suspensions obtainable in this way do not exhibit rising thickening temperatures during the production of polyurethanes, in particular in large-volume shaped articles. The present invention also relates to deactivated suspensions obtainable by the present process and to the use thereof for polyurethane production.

Process for the production of deactivated suspensions of finely-divided

Bismorpholines and a process for their preparation

The invention provides a process for the production of polyetherester polyols which have hydroxyester groups terminally bound via ester groups to high molecular weight polyether polyol segments. These are produced by first reacting high molecular weight polyoxyalkylene ether polyols with molecular weights of from about 400 to 10,000 with an excess of dicarboxylic acids, dicarboxylic acid anhydrides or dicarboxylic acid esters, and then reacting the intermediate product in a further stage with an excess of diols, based on carboxyl groups. The new, high molecular weight polyetherester polyols thus consist of polyoxyalkylene ether segments, which have terminal ester segments in each case with terminal hydroxyl groups per end group. Moreover, the use is claimed of the high molecular weight polyetherester polyols as polyhydroxyl compounds for forming polyurethanes.

Process for the production of polyetherester polyols and the products

Microcapsules having a hydrophobic core material and capsule walls formed by the reaction of water-insoluble polyamines with water-soluble bisulphite adducts of polyisocyanates, a process for the production thereof which is characterized in that a mixture of a hydrophobic core material and water-insoluble polyamines is emulsified in water or in an aqueous protective colloid solution to the required particle size, water-soluble bisulphite adducts of polyisocyanates in the form of powders or aqueous solutions are added and the mixture is left to react to completion at temperatures of from 1.degree. to 140.degree. C., and applications thereof.

Microcapsules having walls of polyaddition products of water-insoluble

Production of microcapsules having walls of polyaddition products of

Polyurethane elastomers are made by reacting organic polyisocyanates with compounds having at least two groups containing isocyanate-reactive hydrogen atoms and a molecular weight of from 400 to 10,000 and a 1,4-monoanhydro-tetritol in accordance with techniques known to those in the art. Known chain-lengthening agents, auxiliaries and additives may be included in the reaction mixture. The reaction mixtures employed in the process of the present invention have a longer pot life than prior art reaction mixtures. The elastomers produced by this process are shrink stable.

Process for the preparation of polyurethane elastomers using diols of

This invention relates to a process for the production of polyurethane urea products from isocyanate product blends and preferably less reactive, aromatic diamines, or solutions of aromatic diamines in relatively high molecular weight polyhydroxyl compounds, the reaction components being reacted in a casting process with commercially-reasonable casting times and comparatively short demolding times. For this purpose, relatively high-molecular weight polyhydroxyl compounds, optionally in the presence of low molecular weight diols are reacted with excess quantities of toluene, phenylene or hexamethylene diisocyanate to produce a substantially diisocyanate-free NCO-prepolymer. This NCO-prepolymer is mixed with from 0.1 to 25%, by weight, of less reactive, monomeric tetra-alkyl-diphenylmethane diisocyanates corresponding to the general formula: ##STR1## wherein R.sub.1 to R.sub.4, which may be the same or different, represent C.sub.1 -C.sub.4 alkyl radicals. These isocyanate blends may be easily processed into elastomer moldings having favorable properties in the casting process using moderately-reactive aromatic diamines from the series of di- to tetra-alkyl-diphenylmethane diamines and/or dialkyl-toluene diamines and/or using substituted 3,5-diamino-4-alkyl-benzoic acid alkyl esters, optionally dissolved in the relatively high molecular weight polyhydroxyl compounds.

Process for the production of polyurethane urea products

A process for the preparation of homogeneous and cellular polyurethane plastics by the reaction of

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Wermelskirchen, Germany

James M Barnes