Johnson Matthey Public Limited Company

Econic Technologies Limited

James Leeland

Andrew Francis Chiffey

Francois Moreau

John Benjamin Goodwin

Michael Kember

Rakibul Kabir

Paul Richard Phillips

Stuart David Reid

Daniel Swallow

Daniel Hatcher

Anthony Chartoire

Kerry Riley

David Bergeal

Christopher Daly

Andrew Armitage

Emmalina Hollis

Andy Chapman

Nuria Lastra-Calvo

Louis Adriaenssens

David Xuereb

Andrew Carruthers

Fernando Valera

David Muir

Louis Adriaennsens

A process for producing a polyol block copolymer in a multiple reactor system including a first and second reactor in which a first reaction takes place in the first reactor and a second reaction takes place in the second reactor. The first reaction is the reaction of a carbonate catalyst with COand epoxide, in the presence of starter and/or solvent to produce polycarbonate polyol copolymer and the second reaction is the reaction of DMC catalyst with the polycarbonate polyol compound of the first reaction and epoxide to produce polyol block copolymer. The product of the first reaction is fed into the second as crude reaction mixture, the epoxide and the polycarbonate polyol compound of the first reaction are fed in a continuous or semi-batch manner, and/or the product of the first reaction has neutral or alkaline pH on addition to the second. The invention further relates to the copolymers and products incorporating such copolymers.

Polyol block copolymer, compositions and processes therefor

A polyol block copolymer comprising a polycarbonate block, A (-A'-Z′—Z—(Z′-A′)-), and polyethercarbonate blocks, B. The polyol block copolymer has the polyblock structure:B-A′-Z′—Z—(Z′-A′-B)wherein n=t−1 and wherein t=the number of terminal OH group residues on the block A; and wherein each A′ is independently a polycarbonate chain having at least 70% carbonate linkages, and wherein each B is independently a polyethercarbonate chain having 50-99% ether linkages and at least 1% carbonate linkages; and wherein Z′—Z—(Z′)is a starter residue. A process of producing a polyol block copolymer from a two step process carried out in two reactors, and products and compositions incorporating such copolymers.

The method of preparing the polycarbonate ether polyol or high molecular weight polyether carbonate using controlled addition of materials during polymerisation includes the steps of: mixing catalyst of formula(I), double metal cyanide (DMC) catalyst and optionally carbon dioxide and/or solvent with epoxide and optionally starter compound and/or carbon dioxide; or mixing DMC catalyst and optionally starter compound, carbon dioxide and/or solvent with epoxide and optionally carbon dioxide and/or solvent; or mixing epoxide, catalyst of formula(I), starter compound and carbon dioxide and optionally solvent; or mixing catalyst of formula (I), DMC catalyst and optionally starter compound, epoxide, carbon dioxide and/or solvent to form in each case a mixture (α); and adding one or more of starter compound, epoxide, carbon dioxide, catalyst of formula(I), DMC catalyst and/or solvent to mixture (α) to form mixture (β) comprising starter compound, epoxide, carbon dioxide, catalyst of formula(I), DMC catalyst and optionally solvent,

Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates

A method for quenching a polymerisation process is described. The reaction of carbon dioxide with an epoxide in the presence of a bimetallic metal complex catalyst to produce a polymer comprises the quenching step of deactivation of the catalyst by contacting the catalyst with an acid effective to deactivate the catalyst. The deactivated catalyst may be removed from the polymer product by contacting the catalyst and polymer product with a solid phase and/or by precipitation; and the catalyst may also be optionally reactivated by contacting the deactivated catalyst with an anion. The acid may contain an anion effective to initiate the polymerisation process and effective to deactivate the catalyst and the molar ratio of acid to catalyst in the deactivation step may be less than or equal to 20:1 of the acid to catalyst mole ratio for the reaction.

Method for quenching a polymerisation process

An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt), manganese (Mn) and a first support material; a second washcoat region comprising a platinum group metal (PGM) and a second support material; and a substrate having an inlet end and an outlet end; wherein the second washcoat region is arranged to contact the exhaust gas at the outlet end of the substrate and after contact of the exhaust gas with the first washcoat region.

Diesel oxidation catalyst and exhaust system

An oxidation catalyst for treating an exhaust gas from a diesel engine comprises: a first washcoat region for oxidising carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat region comprises a first platinum group metal (PGM) and a first support material, and wherein the first washcoat region does not comprise manganese or an oxide thereof; a second washcoat region for oxidising nitric oxide (NO), wherein the second washcoat region comprises platinum (Pt), manganese (Mn) and a second support material comprising a refractory metal oxide, which is silica-alumina or alumina doped with silica in a total amount of 0.5 to 45% by weight of the alumina, wherein the platinum (Pt) is disposed or supported on the second support material and the manganese (Mn) is disposed or supported on the second support material; and a substrate having an inlet end and an outlet end, and wherein the first washcoat region is a first washcoat layer and the second washcoat region is a second washcoat layer, and the second washcoat layer is disposed on the first washcoat layer; and wherein when the oxidation catalyst comprises a hydrocarbon adsorbent, which is a zeolite, then the first washcoat region further comprises the hydrocarbon adsorbent.

An exhaust system for a diesel engine comprises an oxidation catalyst for treating an exhaust gas from the diesel engine and an emissions control device, wherein the oxidation catalyst comprises: a first washcoat zone for oxidizing carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat zone comprises a first platinum group metal (PGM), which is a combination of platinum and palladium, a first support material and a hydrocarbon adsorbent material, which is a zeolite, and wherein the first washcoat zone does not comprise rhodium and is substantially free of manganese or an oxide thereof; a second washcoat zone for oxidizing nitric oxide (NO), wherein the second washcoat zone comprises platinum (Pt) and manganese (Mn) disposed or supported on a second support material, wherein the second support material comprises a refractory metal oxide, wherein the refractory metal oxide is silica-alumina or an alumina doped with silica in a total amount of 0.5 to 45% by weight of the alumina, and wherein the second washcoat zone does not comprise a hydrocarbon adsorbent material, which is a zeolite; and a substrate having and inlet end and an outlet end, and wherein the second washcoat zone is disposed at an outlet end of the substrate, and the first washcoat zone disposed at an inlet end of the substrate; and wherein the emissions control device is a selective catalytic reduction (SCR) catalyst, a selective catalytic reduction filter catalyst, a diesel particulate filter (DPF), or a catalyzed soot filter (CSF).

The present invention relates to the field of polymerisation catalysts, and systems comprising said catalysts for polymerising carbon dioxide and an epoxide, a lactide and/or lactone, and/or an epoxide and an anhydride. The catalyst is of formula (I):  Wherein Mand Mare independently selected from Zn(II), Cr(II), Co(II), Cu(II), Mn(II), Ni(II), Mg(II), Fe(II), Ti(II), V(II), Cr(III)-X, Co(III)-X, Ni(III)-X, Mn(III)-X, Fe(III)-X, Ca(II), Ge(II), Al(III)-X, Ti(III)-X, V(III)-X, Ge(IV)-(X)or Ti(IV)-(X). Ris different from R; and/or at least one occurrence of E, E, Eand Eis different to a remaining occurrence of E, E, Eand E. A ligand, a process of asymmetric N-substitution of a symmetrical ligand and a process for the reaction of: (i) carbon dioxide with an epoxide; (ii) an epoxide and an anhydride; and/or (iii) a lactide and/or a lactone, in the presence of a catalyst is also described.

Catalysts

An oxidation catalyst for treating an exhaust gas produced by a compression ignition engine comprising: a substrate; a catalytic material disposed on the substrate, wherein the catalytic material comprises platinum (Pt); and a region comprising a capture material, wherein the region is arranged to contact the exhaust gas after the exhaust gas has contacted and/or passed through the catalytic material.

Exhaust system for a compression ignition engine having a capture region for volatilised platinum

A catalyst for storing nitrogen oxides (NO) in an exhaust gas from a lean burn engine comprising a NOstorage material and a substrate, wherein the NOstorage material comprises a NOstorage component and an NO oxidation promoter on a support material, wherein the NO oxidation promoter is manganese or an oxide, hydroxide or carbonate thereof.

Nitrogen oxides (NOx) storage catalyst

An oxidation catalyst for treating an exhaust gas from a diesel engine and an exhaust system comprising the oxidation catalyst are described. The oxidation catalyst comprises: a first washcoat region for oxidizing carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat region comprises a first platinum group metal (PGM) and a first support material; a second washcoat region for oxidizing nitric oxide (NO), wherein the second washcoat region comprises platinum (Pt), manganese (Mn) and a second support material; and a substrate having an inlet end and an outlet end; wherein the second washcoat region is arranged to contact the exhaust gas at the outlet end of the substrate and after contact of the exhaust gas with the first washcoat region.

An oxidation catalyst for treating an exhaust gas from a compression ignition engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt) and a first support material, wherein the first washcoat region is substantially free of a hydrocarbon adsorbent; a second washcoat region comprising platinum (Pt), palladium (Pd) and a second support material, wherein the second washcoat region has a ratio by mass of platinum (Pt) to palladium (Pd) of 4:1 to 1:1; a hydrocarbon adsorbent; and a substrate; wherein the first washcoat region is arranged to contact inlet exhaust gas before the hydrocarbon adsorbent, and the first washcoat region is arranged to contact inlet exhaust gas before the second washcoat region.

Oxidation catalyst for a compression ignition engine

An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising a first platinum group metal (PGM), a first support material and a NOstorage component; a second washcoat region comprising platinum (Pt), manganese (Mn) and a second support material; and a substrate having an inlet end and an outlet end.

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Royston, United Kingdom

James Leeland