Moltech Invent S.a.

James Jeng Liu

Jainagesh A Sekhar

Jean-Jacques R Duruz

Vittorio De Nora

A refractory boride body or coating made of a boride of titanium, chromium, vanadium, ziconium, hafnium, niobium, tantalum, molybednum and cerium is produced from a slurry of the refractory boride or a precursor in a collidal carrier preferably composed of two more different grades of the same colloidal carrier selected from colloidal alumina, yttria, ceria, thoria, zirconia, magnesia, lithia, monoaluminum phosphate and cerium acetate. The slurry can also comprise an organic additive selected from polyvinyl alcohol; polyacrylic acid; hydroxyy propyl methyl cellulose; polythylene glycol; ethylene glycol, butyl benzyl phthalate; ammonium polymethacrylate and mixtures thereof. The retractory boride body or coated body is useful as a component of aluminum electrowinning cells.

Slurry and method for producing refractory boride bodies and coatings for aluminium electrowinning cell apparatus

A method of protecting a cathode during the start-up procedure of an aluminum electrowinning cell where the cathode is optionally coated with an aluminium-wettable refractory material and when in use, aluminium is produced thereon. The start-up procedure comprises applying, before preheating the cell, one or more start-up layers in intimate contact on the aluminium-wettable refractory coating which form(s) a temporary protection against damage of chemical and/or mechanical origin to the aluminium-wettable coating; this temporary protection being eliminated before or during the initial normal cell operation. The temporary protection layers may be obtained from at least one pliable aluminium foil having a thickness of less than 0.1 mm and/or an applied aluminium-containing metallization, optionally in combination with inter alia a boron-containing solution, a polymer, a phosphates of aluminium-containing solution, or a colloid that gels while preheating the cell, or combinations thereof.

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Cincinnati, OH, United States of America

James Jeng Liu