U.S. Radium Corporation

James J Mattis

Melvin Tecotzky

Rare earth oxysulfide phosphors with excellent optical properties and optimum particle size control for use as photoluminescent, cathodoluminescent and X-ray luminescent phosphors are prepared by treating a solution of at least one salt of a rare earth metal and a salt of a rare earth activator to form solid salts and thereafter heating the oxidic compound with a sulfidizing agent and a silicon sensitizer, preferably in the presence of a fluoride. The rare earth oxysulfide phosphors thus obtained contain from 10 to 1,000 p.p.m. silicon sensitizer and, if used, 20 to 500 p.p.m. fluoride, incorporated in the crystal lattice structure.

Silicon sensitized rare earth oxysulfide phosphors

Rare earth oxysulfide phosphors with excellent optical properties and optimum particle size control for use as cathodo-luminescent phosphors in cathode ray tubes are prepared by treating a solution of at least one salt of a rare earth metal and a salt of a rare earth activator to form solid salts and thereafter heating the oxidic compound with a sulfidizing agent and a silicon sensitizer, preferably in the presence of a fluoride. The rare earth oxysulfide phosphors thus obtained contain from 10 to 1,000 p.p.m. silicon sensitizer and, if used, 20 to 500 p.p.m. fluoride, incorporated in the crystal lattice structure.

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Long Valley, NJ, United States of America

James J Mattis