Alliedsignal Inc.

Allied Corporation

Honeywell International Inc.

Allied Chemical Corporation

Hugh H. Rowan

James G. Neal

David W. Millure

Edward J. Buyalos

James G Neal

Hugh H Rowan

Edward J Buyalos

David W Millure

Jeffrey T Perkins

Phillip Leroy Mullins

John Armstrong Young

Stanley D Lazarus

Thomas Y-t Tam

Kalidas Chakravarti

Samir Z Abdalla

Hu Zhixuan

Hong-Jian J Sha

A polyester resin, a method for its preparation, the polyester prepared by the method, a method for manufacturing therefrom at increased productivity a dimensionally stable polyester yarn having a low fray count, and the yarn thereby produced. The polyester resin is prepared from high purity terephthalic acid having a particle size distribution described by a Weibull function with narrow ranges of characteristic size and shape factor. The polyester resin has a low filter-blinding index. The polyester yarn is useful for tires, industrial products and other applications.

Polyester resin and industrial yarn process

In a continuous process for the production of high strength polyester yarn with enhanced low shrinkage the improvement comprising maintaining the traveling yarn about a pair of heated draw rolls for a period of at least 0.25 seconds, maintaining the air temperature in the region about said traveling yarn for said period at a temperature of at least 220.degree. C., said draw rolls each having a surface temperature of at least 220.degree. C. and a substantial portion of its surface with a surface roughness value of at least 50 microinches, whereby said yarn is heated sufficiently to obtain a substantial relaxation between said heated draw rolls and said relaxation roll system, thereby providing enhanced low shrinkage. Polyethylene terephthalate industrial yarn having an intrinsic viscosity of at least 0.78, a dry heat shrinkage DIN.sub.177 of less than 2.0%, a dry heat shrinkage DIN.sub.200 of less than 4.5%, and a tenacity of at least 7.2 grams per denier is a part of the invention.

Production of high tenacity, low shrink polyester fiber

High strength polyester multifilament yarn of improved dimensional stability, which has the proper combination of an intrinsic viscosity of at least 0.90, relatively low work loss and a high degree of toughness, is incorporated as tire cord into a rubber tire for reinforcement to provide an important improvement in fatigue life and retained fatigue strength. The continuous melt-spin process comprises the steps of feeding prepolymer to a first finisher vessel to achieve at least 0.4 intrinsic viscosity transferring polymer to a second finisher vessel for a period sufficient to achieve an intrinsic viscosity of at least 0.95, and supplying this polymer to an extrusion spinnerette.

High strength polyester yarn for improved fatigue resistance

Process for producing high strength polyester yarn for improved fatigue

An improvement in a high speed process to produce high performance multi-end polyester yarn comprises extruding molten polyester from a spinnerette to form filaments, then cooling, lubricating and advancing the filaments to a forwarding roll system at the speed of from about 1000-4000 meters per minute so that a partially oriented yarn is produced, then feeding the filaments from the forwarding roll system to a first draw roll system to partially draw the yarn, then feeding the paritally drawn yarn to a second draw roll system having a draw point localizing device then feeding the filaments from the draw roll system to a conditioning roll system and finally taking up the filaments. The improvement is the use of matte finish on godet rolls having an arithmetic mean roll surface roughness value of from between about 35 microinches and about 120 microinches to feed and withdraw yarn to and from a draw point localizing device in the second draw roll system. This combination enables multiple ends of the filaments to be advanced through a single set of forwarding, drawing and conditioning rolls and yarn mechanical quality remains at a high level of acceptance.

Process for high speed, multi-end polyester high performance tire and

Process and apparatus for applying finish to yarn and confining finish are disclosed. The apparatus for applying finish features an applicator face which comprises the delivery area of a finish supply duct and the surface area of two primary arcs, one located on either side of the duct and curving in the general direction of yarn travel. The central angle subtended by each of the primary arcs ranges from about 2 to 9 degrees. The edge of each of the primary arcs remote from the duct terminates in a secondary arc which subtends a central angle of 30 to 60 degrees and with a radius length shorter than that of either primary arc. The apparatus for confining finish comprises a housing, plate and baffle(s). The housing substantially encloses a finish application device and has openings for yarn entrance and exit and for take-off of excess finish. The plate is mounted beneath the finish application device. The baffle(s) are disposed between the plate and the take-off opening. The plate and baffle(s) are oriented with respect to the housing such that any finish overflow and spray coming into contact therewith feed by gravity away from the traveling yarn to the take-off opening. The process comprises metering finish to an applicator face and simultaneously maintaining yarn in traveling contact with the entire length of the face and a portion of the edge thereof so that initial and last yarn-to-applicator contact is non-tangential to the applicator face.

Process and apparatus for applying and confining finish

High molecular weight linear condensation polyesters are stabilized against deterioration by heat by reacting the polyester in molten form with certain polycarbonates in the presence of a catalytic amount of a phosphonium compound selected from the group consisting of tetra-n-alkylphosphonium acetates and tetra-n-alkylphosphonium halides. For the purpose of this disclosure, polycarbonates are defined as linear polyesters of carbonic acid in which the carbonate groups recur in the polymer chain. In continuous production of the improved polyesters, it is preferred that the polycarbonate and catalyst be added to the process stream with mixing at a point to give 2 to 15 minutes reaction time under superatmospheric pressure before the polyester enters the last polycondensation reactor.

Production of thermally stabilized polyester

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Raleigh, NC, United States of America

James G Neal