Other

Vortec Corporation

Welko Industrial S.p.a.

Hnat, James G.

Schaffer, Mark A.

James G Hnat

Mark A Schaffer

Akshay Mathur

James C Simpson

Maurizio Sanavia

This invention relates to a process that utilizes high-temperature oxidation with controlled stoichiometry in the concentration of vanadium from carbonaceous feedstock materials containing vanadium, such as residues, ashes and soots resulting from the combustion or gasification of petroleum vacuum residuum, petroleum coke, kerogen from oil shale, and bituminous sand, e.g., tar sand or oil sand, or extra heavy oil or other carbonaceous feedstocks that contain vanadium. A preferred embodiment uses a counter-rotating vortex reactor and a cyclonic, entrained-flow reactor to rapidly heat and oxidize feedstock at temperatures in the range of about 2100&#xb0; F. to 2900&#xb0; F., resulting in a vapor stream with entrained, solid materials comprising the concentrated vanadium species. The entrained, vanadium-rich product solids may be removed from the high-temperature vapor stream by a high-temperature filter assembly, with or without the aid of a high-temperature cyclone separator which removes a portion of the vanadium-rich solids upstream of the filter. The filtered vapor stream may be stored or then ducted to suitable unit operations for possible oxidation and heat recovery, followed by entailed pollution control prior to its final discharge to the atmosphere.

Methods for the concentration of vanadium from carbonaceous feedstock materials

This invention relates to an apparatus and process that utilizes high-temperature oxidation and sublimation techniques for the recovery of molybdenum from spent catalysts or other feedstocks that contain molybdenum. A preferred embodiment uses a counter-rotating vortex reactor and a cyclonic entrained-flow reactor to rapidly heat and oxidize the spent catalyst feedstock, such as carbon, sulfur, and molybdenum compounds, at temperatures in the range of about 2100&#xb0; F. to 2900&#xb0; F., resulting in a gas-solid stream containing molybdenum trioxide vapor. A high-temperature cyclone separator is utilized to separate the residue from this stream before this stream is rapidly quenched to a temperature sufficient to effect the condensation of solid molybdenum trioxide without condensing arsenic or phosphoric oxides. The condensed molybdenum trioxide material is separated from this stream by passing through a high-temperature filtration system. The remaining gaseous stream is then ducted to suitable unit operations for possible further material reclamation and entailed pollution control prior to its final discharge to the atmosphere.

Method and apparatus for the recovery of molybdenum from spent catalysts

The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants.

Manufacture of ceramic tiles from fly ash

The present invention relates to a process of forming ceramic tiles having the appearance of tiles produced from clays. The process includes melting a material to form a glass melt, treating the glass melt to produce a solid glass product, grinding the solid glass product to produce glass particles having a particle size of less than 200 microns, mixing the glass particles with a first additive to form a glass powder mixture having a composition of 55 to 99 wt. % glass particles and 45-1 wt. % first additive, forming the glass powder mixture into tiles by dry pressing, where the tiles have a primary crystalline phase selected from the group consisting of nepheline, diopside, anorthite, wollastonite, melilite, merwinite, spinel, akermanite, gehlenite, crystalline phases based on iron substitutions in the crystalline phase, and mixtures thereof. The process includes a devitrifying step where the solid glass product is devitrified prior to the grinding step or the glass particles in the tile are devitrified after the forming step.

Manufacture of ceramic tiles from industrial waste

The present invention relates to a process for forming glass-ceramic tiles. Spent aluminum potliner containing carbonaceous material, fluorine, and glass forming materials is oxidized under conditions effective to combust the carbonaceous material and volatilize partially the fluorine in the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing fluorine.

Manufacture of ceramic tiles from spent aluminum potlining

An apparatus and method are disclosed for processing glass-making materials under oxidizing conditions, and for processing materials, such as hazardous or toxic wastes, or smelting under reducing conditions. As a glass-making apparatus the invention includes a cyclone melt reactor for forming a liquid glass melt and a combustion preheater for receiving the glass-making materials and combusting the fuel and oxidant therein to heat the glass batch materials to a temperature at least equal to the melt temperature of the glass batch material. The combustion preheater has an outlet connected to the glass melt reactor, and at least one inlet is provided into the combustion preheater for introducing oxidizing materials and for creating a well-stirred region within the combustion preheater means. Supplemental heat can be provided by introducing a heated transfer gas into the combustion preheater, and a fuel gasifier can be provided for producing a fuel gas before the fuel gas is injected into the combustion preheater. For processing materials under reducing conditions, the cyclone melt reactor is connected to a preheater/reducing chamber and preheated reducing gas is introduced into the reducing chamber in such a manner that a well-stirred region is created within the reducing chamber. Heated transfer gas from a supplemental heat source and reducing gas from a fuel gasifier can also be introduced into the reducing chamber.

Apparatus for heat processing glass batch materials

An apparatus and method are disclosed for processing glass-making materials under oxidizing conditions, and for processing materials, such as hazardous or toxic wastes, or smelting under reducing conditions. As a glass-making apparatus the invention includes a cyclone melt reactor for forming a liquid glass melt and a combustion preheater for receiving the glass-making materials and combusting the fuel and oxidant therein to heat the glass batch materials to a temperature at least equal to the melt temperature of the glass batch material. The combustion preheater has an outlet connected to the glass melt reactor, and at least one inlet is provided into the combustion preheater for introducing oxidizing materials and for creating a well-stirred region within the combustion preheater means. Supplemental heat can be provided by introducing a heated transfer gas into the combustion preheater, and a fuel gasifier can be provided for producing a fuel gas before the fuel gas is injected into the combustion preheater. For processing materials under reducing conditions, the cyclone melt reactor is connected to a preheater/reducing chamber and preheated reducing gas is introudced into the reducing chamber in such a manner that a well-stirred region is created within the reducing chamber. Heated transfer gas from a supplemental heat source and reducing gas from a fuel gasifier can also be introduced into the reducing chamber.

Method and apparatus for heat processing glass batch materials

A method of melting glass in a toroidal vortex reactor wherein first pulverized glass batch materials are entrained in an oxidant flow which creates a first gas-solids suspension. This first gas-solids suspension is heated in combusting fuel to form a heated suspension which is thereafter mixed with second glass forming ingredients, whereby a second gas-solids suspension is formed. The second gas-solids suspension is injected into the toroidal vortex reactor from a plurality of locations about the circumference thereof. The heated suspension particles in the reactor collide with each other and the wall of the reactor and form a glass layer which flows down the reactor wall and is withdrawn at the bottom thereof.

Process for melting glass in a toroidal vortex reactor

A method of melting glass in a vortex reactor wherein first pulverized glass batch materials are entrained and preheated in a suspension preheater thereby creating a first gas-solids suspension. This first gas-solids suspension is thereafter mixed with a second gas-solids suspension comprised of additional glass batch material in a vortex reactor. The first gas-solids suspension and the second gas-solids suspension are introduced into the vortex reactor through at least one injector assembly. The stoichiometry and heat release in the vortex reactor are controlled by adjusting the oxidant/fuel ratio in the suspension preheater and the vortex reactor. The heated suspension particles are mixed and distributed to the walls of the vortex reactor by fluid mechanically induced centrifugal forces with glass forming reactions occurring along the vortex reactor walls. The formed glass is rapidly refined and homogenized along the vortex reactor walls in a thin layer under the influence of gas dynamic shear forces. The rapidly refined formed glass is collected in a reservoir for final refining and homogenization and distribution to glass manufacturing facilities.

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Collegeville, PA, United States of America

James G Hnat