United States Filter Corporation

Veolia Water Technologies, Inc.

Veolia Water Solutions & Technologies North America, Inc.

James F Rieke

Timothy J Rittof

Sebastien Bessenet

Timothy F Rittoff

Jinhai Feng

A method of producing potassium sulfate by employing sodium sulfate and potassium chloride sources is disclosed. The method includes a crystallization process that yields a mother liquor containing sulfate, sodium and chloride. The mother liquor is directed to an anion segregation unit that produces a reject or retentate rich in sulfate which is recycled and employed in the production of the potassium sulfate. Further, the anion segregation unit produces a permeate that is depleted in sulfate but includes sodium and chloride and is directed to a sodium chloride crystallizer for producing sodium chloride.

Method for producing potassium sulfate and sodium chloride from wastewater

A process is provided for recovering sodium chloride crystals and sodium carbonate decahydrate crystals from a concentrated brine that results from a gas mining operation where gas and produced water is recovered and the produced water constitutes a brine. An initial pre-concentration process is carried out where the brine is concentrated and in the process carbon dioxide is removed from the brine and at least some sodium bicarbonate is converted to sodium carbonate. In one process, the concentrated brine is directed to a sodium chloride crystallizer where the brine is heated and further concentrated to form sodium chloride crystals which are separated from the brine to yield a product and wherein the resulting brine is termed a first mother liquor. The first mother liquor is then directed to a sodium carbonate decahydrate crystallizer where the first mother liquor is cooled and concentrated resulting in the formation of sodium carbonate decahydrate crystals and a second mother liquor. The second mother liquor is split into two streams where one stream is directed back to the sodium chloride crystallizer while the other stream is wasted or further treated.

Selective salt recovery from mixed salt brine

Heat transfer in non-turbulent highly viscous mixed-phase flowing streams can be improved by altering flow characteristics using spiral-shaped elements to eliminate boundary phenomena. The spiral-shaped element promotes helical or spiral flow paths to reduce or eliminate temperature gradients associated with laminar flow characteristics.

Growing community of inventors

Naperville, IL, United States of America

James F Rieke