Dow Corning Corporation

Exxon Chemical Patents, Inc.

Exxonmobil Chemical Patents Inc.

Atlas Roofing Corporation

James Darryl Thornsberry

Robert H Blanpied

James Richardson Lattner

Steven E Silverberg

Leonel E Sanchez

C Harry McMullen

Tronze-I Dennis Wu

Lenin J Petroff

Michael Allen Stanga

Joseph S Steger

Gregory Islas

A rigid closed cell polyisocyanate-based foams is created by reacting at least one organic polyisocyanate with compounds having at least two active hydrogen atoms in the presence of an n-pentane blowing agent. When the foam is formed into a laminated board with facers, the foam formulation includes a sufficient amount of a common blend of cleaning solvent chemicals to cause a noticeable improvement in facer adhesion. The chemicals used to improve facer adhesion are a standard blend of industrial cleaning solvents called 'Di-Basic Esters' or DBE. The actual chemical compounds in one mode of this mixture are the methyl esters of about 59% glutaric acid, about 20% succinic acid, and about 21% adipic acid. The minimum rate of addition of the Di-Basic Esters'[DBE] thought to be effective may be less than about 0.5 parts per hundred parts of polyol (pphpp). The currently preferred embodiments use add-on rates within the range of about 0.5 to about 5.0 pphpp, with the currently most preferred range being from about 1.0 to about 3.0 pphpp. The blend of cleaning chemicals employed by the present invention surprisingly enhance the adhesion between the foam and the facer.

Thermosetting plastic foams and methods of production thereof using adhesion additives

A thermosetting plastic foam solid formed from the reaction product of: (a) either polyisocyanate or isocyanate-based foam; (b) a polyol-based foam; (c) a catalyst which is capable of promoting the thermosetting reaction between the polyisocyanate or isocyanate-based foam and the polyol-based foam; and (d) a blowing agent which comprises a high purity cyclopentane product, wherein the high purity cyclopentane product is about 95% or greater pure cyclopentane, and, optionally, (e) water and/or (f) liquid flame retardant.

Method of producing rigid foams and products produced therefrom

Thermosetting plastic foam

A thermosetting plastic foam solid formed from the reaction product of: (a) either polyisocyanate or isocyanate; (b) a polyol; (c) a catalyst which is capable of promoting the thermosetting reaction between the polyisocyanate or isocyanate and the polyol; and (d) a blowing agent comprised at least partially from a high purity cyclopentane product, wherein the high purity cyclopentane product is about 95% or greater pure cyclopentane, and, optionally, (e) water and/or (f) liquid flame retardant.

A thermosetting plastic foam solid is obtained using a blowing agent comprised at least partially from depolymerization of dicyclopentadiene into essentially pure cyclopentane. This unique hydrocarbon is miscible in polyester polyols, where others, such as extracted cyclopentane, are not. In a blend of 15 parts of liquid flame retardant per hundred parts polyester polyol, the mixture is both stable and has a suitably low viscosity.

An improved process is provided for the preparation of siloxane-oxyalkylene block copolymer surfactant compositions which utilize a hydrosilylation reaction with a phenyl ether as the reaction solvent and the use of a phenyl ether as a cold blend additive. Ethylene glycol phenyl ether is the preferred reaction solvent or cold blend additive.

Production of organopolysiloxane copolymers with a phenyl ether solvent

An improved process is provided for the preparation of siloxane-oxyalkylene block copolymer surfactant compositions which utilize a hydrosilylation reaction with a phenyl ether as the reaction solvent. The reaction solvent need not be removed from the block copolymer, particularly when the block copolymer is used as a surfactant for polyurethane foam formulations. Ethylene glycol phenyl ether is the preferred reaction solvent.

What is disclosed is a process for obtaining polyurethane foams having enhanced benefits. The invention disclosed herein provides a system flowability of the reacting foam mixture to give foams with an insulating capablity equal to the foams that are provided by chlorofluorocarbon blown system, while doing away with the chlorofluorocarbons.

Process for preparing rigid polyurethane and polyisocyanurate foams

The specification discloses a surfactant composition for rigid urethane, including isocyanurate foams which includes from about 15 to about 50% each of the following ingredients: (1) an organic surfactant; (2) a siloxane-polyoxyalkylene surfactant; and (3) one of water, C-1 to C-3 alcohol and mixtures thereof.

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Meridian, MS, United States of America

James Darryl Thornsberry