Electric Power Research Institute Incorporated

Other

James D Colley

Robert E Moser

James H Wilhelm

David R Owens

Oliver W Hargrove, Jr

Miriam Stohs

An efficient and cost-effective flue gas desulfurization apparatus for removing sulfur dioxide from waste gases is provided. The apparatus employs a substantially solids-free clear liquor scrubbing liquid and an, organic acid additive capable of maintaining a process pH of 4.5 to 6.0 under inhibited oxidation conditions in the absorber to accomplish sulfur dioxide removal while avoiding scale formation and encrustation. Calcium sulfite relative saturation is controlled to a desired low optimum level by maintaining the circulating calcium ion concentration at a corresponding, optimum low level. A smaller thickener unit area is required to produced calcium sulfite crystals with optimum settling and dewatering characteristics. A reactor system that promotes the formation of small, efficiently dewatered calcium sulfite solids is also provided.

Clear liquor organic acid flue gas desulfurization system

An efficient and cost-effective flue gas desulfurization process for removing sulfur dioxide from waste gases is provided. The process employs a substantially solids-free clear liquor scrubbing liquid and an organic acid additive capable of maintaining a process pH of 4.5 to 6.0 under inhibited oxidation conditions in the absorber to accomplish sulfur dioxide removal while avoiding scale formation and encrustation. Calcium sulfite relative saturation is controlled to a desired low optimum level by maintaining the circulating calcium ion concentration at a corresponding optimum low level. A smaller thickener unit area is required to produce calcium sulfite crystals with optimum settling and dewatering characteristics. A reactor system that promotes the formation of small, efficiently dewatered calcium sulfite solids is also provided.

Clear liquid acid flue gas desulfurization system

A flue gas desulfurization process and system employing a clear scrubbing liquor and an organic acid buffer conducted under forced oxidation conditions to produce a usable gypsum by-product without scrubber scaling and abrasion is provided. Calcium ion concentration and chloride concentration are suppressed to improve limestone utilization, reduce the consumption of organic acids and improve crystal growth. The FGD system includes a limestone reactor for precipitating gypsum separate from the scrubber system which allows the recovery of pure carbon dioxide and a clarifier/softener tank which allows the production of gypsum-free clear scrubbing liquor and a drier gypsum filter cake.

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Anchorage, KY, United States of America

James D Colley