Syracuse University

James A Schwarz

Robert William Pasco

Karol Putyera

Teresa J Bandosz

Jacek Jagiello

Somasundaram Subramanian

Joseph J Hutta

Rajiv K Agarwal

Kwabena A Amankwah

Michael S Heise

Christopher S Tucker

Joong S Noh

Yao-Jyh R Huang

Edward J Daniszewski

A method of making a microporous carbon material which includes providing a precursor selected from the group consisting of crystalline salts of aromatic sulfonates and nonporous polymeric salts. Prior to carbonization, the precursor is treated by ion exchange or other conventional processes to introduce a metal such as iron, nickel and cobalt into the precursor. Heat treatment of such composite precursors in the temperature range of 350.degree. to 850.degree. C. in an inert oxygen free atmosphere for a sufficient time promotes thermally induced hydrogen abstraction and rearrangement of BSUs which result in the formation of a composite, carbonaceous microporous material which contains a metal component, and has a pore size distribution in the range of about 4-15 .ANG. A. The structural and storage characteristics of the microporous carbon materials are also disclosed.

Composite microporous carbons for fuel gas storage

A method of making a microporous carbon material which includes providing a precursor selected from the group consisting of crystalline salts of aromatic sulfonates and nonporous polymeric salts. Heat treatment of such precursors in the temperature range of 350.degree. to 850.degree. C. in an inert oxygen free atmosphere for a sufficient time promotes thermally induced hydrogen abstraction and rearrangement of BSUs which result in the formation of a carbonaceous microporous material having a pore size distribution in the range of about 4-15 .ANG.. The structural and storage characteristics of the microporous carbon materials are also disclosed.

Microporous carbons for fuel gas storage

A highly microporous adsorbent material is formed as a composite of a natural or synthetic clay or clay-like mineral matrix intercalated with an active carbon. The mineral is prepared and selected to have a selected interlayer spacing between microcrystalline sheets. An organic polymeric precursor is contacted therewith to fill the matrix interstices. Then the precursor is polymerized and carbonized to yield the adsorbent material in which the carbon is intercalated into the mineral matrix. The mineral can be naturally occurring smectite or synthetic hydrotalcite.

Activated carbons molecularly engineered

Oxide supported metal catalysts have an additional metal present in intimate association with the metal catalyst to enhance catalytic activity. In a preferred mode, iridium or another Group VIII metal catalyst is supported on a titania, alumina, tungsten oxide, silica, or composite oxide support. Aluminum ions are readsorbed onto the support and catalyst, and reduced during calcination. The aluminum can be added as aluminum nitrate to the iridium impregnate solution, e.g. chloroiridic acid.

Process of making supported catalyst

Increasing the surface acidity of active carbons can lead to an increase in capacity for hydrogen adsorption. Increasing the surface basicity can facilitate methane adsorption. The treatment of carbons is most effective when the carbon source material is selected to have a low ash content i.e., below about 3%, and where the ash consists predominantly of alkali metals alkali earth, with only minimal amounts of transition metals and silicon. The carbon is washed in water or acid and then oxidized, e.g. in a stream of oxygen and an inert gas at an elevated temperature.

Selection and preparation of activated carbon for fuel gas storage

An extremely long-life, highly reproducible cathode is produced by preparing a porous sintered metal matrix, impregnating the matrix with a reagent containing a transition metal to modify the surface structure of the matrix, and then impregnating the surface-modified metal matrix with a barium-containing reagent to produce a cathode structure in which barium atoms are held in a metal-metal interaction with the transition metals and the surface of the matrix. In a preferred embodiment, the transition metal oxide is TiO.sub.2. This produces a barium/transition metal oxide surface structure which permits cathode operating temperatures on the order of 650 degrees C. The barium is stable and is retained on the surface of the metal matrix, so further dispensing is not required.

Impregnated thermionic cathode

Ceramic materials in the form of powdered .gamma.-Al.sub.2 O.sub.3 are surface modified by addition of the salts or oxides of nickel or tungsten prior to contact of the ceramic with polymer binder suspensions. The sintering and densification of said ceramic materials produces ceramic bodies substantially free from carbonaceous residues.

Process for forming sintered ceramic articles

The reliability and life cycle of a thin-film conductor is predicted accurately and directly by measuring changes in its resistivity during an interval in which its temperature is dynamically increased. A semiconductor wafer containing a number of integrated circuits, each of which contains the thin-film conductor, is placed on a test platform of a semiconductor test station, where probes are positioned to supply a constant current stress to the conductor and to measure the voltage across it. A ramp current is supplied to a resistive heating element on the test platform to effect a linear rise in temperature over a span of time to the thin-film conductor. Changes in the conductor resistivity with respect to temperature provide kinetic data related to electromigration damage in the conductor, and hence to reliability over time.

Dynamic testing of thin-film conductor

Hydrogen is stored at cold temperatures (room temperature to liquid nitrogen temperature) by sorption in a high unit surface area activated carbon storage medium. A minor amount of a transition metal is dispersed in the carbon, and this significantly increases the hydrogen occupancy of the available storage sites on the carbon. In a favorable embodiment, the storage medium is activated so as to maintain a quantity of water, which acts as a co-catalyst to further enhance the quantity of hydrogen that can be stored.

Metal assisted carbon cold storage of hydrogen

A thin film stripe that includes a conductive metal alloyed with at least one other element capable of chemically bonding with hydrogen and a compound formed by hydrogen chemically bonded with at least one other element in sufficient amounts to increase the stripe's resistance to electromigration failure at normal operating temperatures and pressures.

Hydrogen charged thin film conductor

A thin film conductive stripe having increased resistance to electromigration wherein a conductive element is alloyed with at least one other hydrogen storage element capable of accepting and holding hydrogen internally within the thin film stripe and the stripe is annealed in a hydrogen atmosphere to react hydrogen with the storage material to charge the stripe with hydrogen.

A method for controlling the adsorption of materials from an aqueous solution onto a support. Ingredients selected from three identified classes are added in controlled amounts to the solution to generate a desired concentration profile.

Method of controlling the distribution of a coating material upon the

A technique is described that permits direct and accurate evaluation of a thin film conductor's reliability which requires only a few hours to carry out. The technique involves a temperature ramp procedure which dynamically exposes a conductor operating under constant current stress to a linear (in time) rise in temperature. Changes in resistivity of the conductor provides kinetic data that is directly related to both the electromigration process and the reliability of the device.

Growing community of inventors

Fayetteville, NY, United States of America

James A Schwarz