US Government As Represented by the Secretary of the Army

James A Murfree, Jr

Pasquale Martignoni

William M Chew

Orval E Ayers

John F Phillips

William A Duncan

Walter W Wharton

Henry A Nappier

Edgar F Croomes

A process for producing a calcium chemical pump which includes reacting cium and anhydrous ammonia in a closed vessel that is cooled to a temperature below 0.degree. C. to form a solution of the calcium and anhydrous ammonia and then spraying the solution onto a rotating porous foamed substrate material in a closed container that has a vacuum pulled thereon, and the solution when sprayed causing the ammonia to flash and be evaporated and drawn off by the vacuum to cause the calcium to be deposited on the rotating porous foamed substrate material.

Supports and preparation process for the manufacture of a calcium

Disclosed is a detector for fumes of hydrazine and its derivatives, methydrazine (MMH) and 1,1-dimethylhydrazine (UDMH). The detector encompasses a means for generating heat when fumes of hydrazine or its derivatives are catalytically decomposed after coming in contact with the active ingredient of the detector. The means for generating heat includes the active ingredient, iridium, which is deposited within and upon a ceramic pellet. The pellet is fitted with a thermal responsive means responsive to the generated heat. An output signal proportional to the generated heat can be interpreted by a balanced electronic bridge. The electronic bridge is balanced by preparing an unimpregnated pellet in the same way as the impregnated pellet and putting it in the circuit as a reference. The reference, being the same size and shape and prepared in the same manner, compensates for changes in temperature and other changes in the circuit, thus allowing one to zero the instrument. When the impregnated pellet comes into contact with fumes of hydrazine, MMH or UDMH, an imbalance is caused. The potential difference may be monitored by a meter, recorder, bell signal, etc. Neither the heat nor the catalytic action depletes the iridium or its action upon fumes of hydrazine and its derivative compounds.

Detector for fumes of hydrazine and its derivatives

The use of a class or compounds known as amine-boranes and their derivati in solid propellants to produce or generate hydrogen or deuterium upon combustion.

Amine-boranes as hydrogen generating propellants

A catalyst bed containing alumina pellets on which an active catalyst metal selected from iridium, nickel, niobium, and molybdenium has been deposited is employed to decompose a compound selected from deuterohydrazine, deuteroammonia, hydrazine, and ammonia to yield ammonia free deuterium and nitrogen or hydrogen and nitrogen at a temperature required for immediate use in a DF or HF laser which uses F atoms as the fuel. The decomposition temperature of the catalyst bed is maintained by a hypergolic reaction produced from reacting a fuel selected from the group consisting of hydrazine, methylhydrazine, 1,2-dimethylhydrazine, and blends of the same with an oxidizer selected from the group consisting of inhibited red fuming nitric acid, dinitrogen tetroxide, chlorine trifluoride, and chlorine pentafluoride. A laser employing ammonia free decomposition products of hydrazine and ammonia produced at a temperature between about 500.degree. C. and 900.degree. C. operates at a higher power output. When NH.sub.3 is present in the H.sub.2 and diluent gas, N.sub.2, a decrease of 20% in the output is experienced for each 1-2% NH.sub.3 up to about 8% concentration.

Hydrogen gas generator from hydrazine/ammonia

A cyano compound fuel selected from the group consisting of dicyanoacetylene (DCA), tetracyanoethylene (TCE), and tetracyanoethylene oxide (TCEO) when reacted with an oxidizer compound selected from the group consisting of fluorine (F.sub.2), nitrogen trifluoride (NF.sub.3), chlorine trifluoride (ClF.sub.3), chlorine pentafluoride (ClF.sub.5), and tetrafluorohydrazine (N.sub.2 F.sub.4) produces the F.sup.. atom concentration required for either HF or DF lasers. The reaction is accomplished in the presence of a diluent gas selected from nitrogen and helium. No deactivation species are among the gaseous species produced which include CF.sub.4, F.sup.. atoms, and N.sub.2 ; therefore, deactivation of the excited molecules, either HF or DF, which are responsible for the lasing in a HF or DF laser is prevented. A higher performance of the laser device can be achieved.

Cyano compounds as fuels for HF or DF lasers

Disclosed are storable solid propellant compositions based on complex metal oron compounds of the general formula M(BH.sub.4).sub.x or M(BD.sub.4).sub.x, (where M equals a metal and x equals the valence of the metal M; M is an alkali metal or an alkaline earth metal; H is hydrogen, and D is deuterium) and ammonium salts of the general formula (NH.sub.4).sub.n Y or deuteroammonium salts of the general formula (ND.sub.4).sub.n Y (where Y represents an anion with a total charge of n; N is nitrogen, H is hydrogen, and D is deuterium) combined stoichiometrically or in varying molar ratios. The stoichiometric blend is employed in a method for producing hydrogen or deuterium that contains nitrogen as an inert diluent and is acceptable for use in HF/DF chemical lasers, the gas dynamic laser (GDL), or as a source to generate hydrogen containing an inert diluent.

Method for producing hydrogen or deuterium from storable solid

Solid propellants for generating hydrogen

The use of methoxylamine hydrochloride (CH.sub.3 ONH.sub.2. HCl) as an adive to exothermally decomposing liquid monopropellants such as hydrazine and hydrazine water mixtures to lower the freezing point of the monopropellants and thereby render the monopropellants usable in gas generators at very low temperatures.

Liquid monopropellant compositions including hydrazine and methoxylamine

The use of methoxylamine nitrate (CH.sub.3 ONH.sub.2.NHO.sub.3) as an addve to exothermally decomposing liquid monopropellants such as hydrazine and hydrazine water mixtures to lower the freezing points of the monopropellants and thereby render the monopropellants usable in gas generators at very low temperatures.

Monopropellant composition comprising hydrazine and methoxylamine nitrate

The use of methoxylamine perchlorate (CH.sub.3 ONH.sub.2.HClO.sub.4) as an dditive to exothermally decomposing liquid monopropellants such as hydrazine and hydrazine water mixtures to maintain energetic monopropellants and at the same time lower the freezing point of the monopropellants, thereby rendering the monopropellants usable in gas generators at very low temperatures.

Growing community of inventors

Huntsville, AL, United States of America

James A Murfree, Jr