Minnesota Mining and Manufacturing Company

3m Innovative Properties Company

James A Klein

Brandt K Carter

Raymond L Lucking

Sheldon J Israel

James E Lasch

James M Kaczmarczik

James M Jonza

Timothy J Hebrink

Ta-Hua Yu

Edward J Kivel

Yufeng Liu

Daniel M Czuprynski

Presently described are multilayer optical films comprising an optical stack comprising at least one first birefringent optical layer; at least one (e.g. isotropic) second optical layer having a birefringence of less than 0.04 at 633 nm, and optionally at least one skin layer. The second layer, skin layer, or a combination thereof comprises a blend of at least one methyl methacrylate polymer and at least one styrene-acrylonitrile polymer.

Multilayer optical film layer comprising blend of methyl methacrylate polymer and styrene acrylonitrile polymer

A multilayer polyester film having at least 7 layers which comprises alternating layers of polyethylene terephthalate and polyethylene naphthalate. Biaxial orientation and subsequent restrained heat setting of these materials results in thin films with tensile moduli in both stretch directions well in excess of the values obtained with monolithic films of either material. In some embodiments, a slippery surface is imparted to the film without the use of conventional slip agents.

Multilayer polyester film

A multilayer polyester film, and a method for making the same, is provided. The film consists of alternating layers of polyethylene terephthalate and polyethylene naphthalate. Biaxial orientation and subsequent restrained heat setting of these materials results in thin films with tensile moduli in both stretch directions well in excess of the values obtained with monolithic films of either material. In some embodiments, a slippery surface is imparted to the film without the use of conventional slip agents.

A method for making multilayer polyester films is provided wherein a slippery surface is imparted to the film, without the use of slip agents, through appropriate crystallization and orientation of the film.

Method for making a multilayer polyester film having a low coefficient

A multilayer film is provided with a slippery surface layer by crystallization in an underlying layer which results in the deformation of an overlying surface layer without the use of particulate slip agents. The films may be formed by alternating layers of a naphthalene dicarboxylic acid polyester and a terephthalic acid polyester.

Multilayer polyester film with a low coefficient of friction

Method for making multilayer polyester film

Conformable marking sheet comprising a microporous thermoplastic polymer base sheet having a network of interconnected pores. The marking sheet has a low yield stress, making it conformable to rough surfaces. The pores of the base sheet can be filled with a diluent (wax) or they may have the diluent removed, for example by extraction. The construction may further comprise an adhesive on the bottom and a top marking indicium layer comprising a polymeric binder in which is partially embedded a multiplicity of retroflective lens elements, e.g., transparent microspheres.

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Minneapolis, MN, United States of America

James A Klein