Standard Oil Company (indiana)

Ineos USA LLC

James A Kaduk

Alakananda A Bhattacharyya

James F Brazdil

Christos Paparizos

Catalytic compositions and processes are disclosed for economical conversions of lower alkane hydrocarbons. Broadly, the present invention discloses solid compositions containing mixed metal oxides that exhibit catalytic activity for ammoxidation of lower alkane hydrocarbons to produce an unsaturated nitrile in high yield. Generally, these solid oxide compositions comprise, as component elements, molybdenum (Mo), vanadium (V) niobium (Nb) and at least one active element selected from the group consisting of the elements having the ability to form positive ions. Mixed metal oxide catalytic compositions advantageously comprise one or more crystalline phases at least one of which phases has pre-determined unit cell volume and aspect ratio. Also described are methods for forming the improved catalysts having the desired crystalline structure and ammoxidation processes for conversion of lower alkanes.

Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons

A method for preparing synthetic cristobalite comprises (1) preparing a mixture containing sources for an oxide of silicon and for an oxide of boron, a base of an alkali or alkaline earth metal or precursor of such base, a polyhydric alcohol, and water; and (2) maintaining the mixture at suitable reaction conditions to effect formulation of the cristobalite, said reaction conditions comprising a reaction temperature within the range of about 30.degree. C. to about 300.degree. C., a pressure of at least the vapor pressure of water at the reaction temperature, and a reaction time that is sufficient to effect crystallization.

Synthetic cristobalite

A ferrierite crystalline aluminosilicate is prepared by (1) forming an aqueous mixture of an oxide of aluminum, an oxide of silicon, a metal cation and a beta-diketone as a template compound, (2) maintaining the pH of such mixture between 9 and 14, and (3) crystallizing the mixture.

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Naperville, IL, United States of America

James A Kaduk