Lg Chem, Ltd

Jae Min Suk

Yoo Vin Kim

Young Min Kim

Jin Hyoung Lee

Young Hwan Jeong

Su Jeong Han

Sun Haeng Chung

Jae Won Heo

Chang Hong Bak

Changhong Park

Young-Min Kim

Young-Hwan Jeong

Sujeong Han

Jaewon Heo

Jin-Hyoung Lee

A copolymer is prepared by graft-polymerizing 20 to 40% of an aromatic vinyl compound and 1 to 20% of a vinyl cyanide compound onto 50 to 70% of conjugated diene rubber latex having a solids content of 30 to 65% by weight, coagulating the latex by adding 0.04 to 0.27 parts by weight of a first nonionic polymer coagulant, and 0.47 to 1.65 parts by weight of a second cationic polymer coagulant or 0.73 to 3.35 parts by weight of a second anionic polymer coagulant to 100 parts by weight (based on solids) of the prepared graft copolymer latex. When the second coagulant is the cationic polymer coagulant, the total weight of coagulant is 0.7 to 1.7 parts by weight, and when the second coagulant is the anionic polymer coagulant, the total weight of coagulant is 0.97 to 3.37 parts by weight.

Method of preparing vinyl cyanide compound-conjugated diene compound-aromatic vinyl compound graft copolymer, and thermoplastic resin composition including graft copolymer

Provided is a method of preparing a diene-based rubber polymer, which includes: adding each of a diene-based monomer, a molecular-weight regulator, an initiator, and an emulsifier to a reactor a first time and carrying out polymerization; adding a molecular-weight regulator to the reactor a second time when a polymerization conversion rate of 48 to 72% is reached and carrying out polymerization; adding a diene-based monomer to the reactor a second time when a polymerization conversion rate of 63 to 77% is reached and carrying out polymerization; adding each of an initiator and an emulsifier to the reactor a second time when a polymerization conversion rate of 68 to 81% is reached and carrying out polymerization; and adding each of an initiator and an emulsifier to the reactor a third time when a polymerization conversion rate of 85 to 91% is reached and carrying out polymerization.

Method of preparing diene-based rubber polymer and method of preparing graft polymer including the diene-based rubber polymer

The present invention relates to a method for preparing a conjugated diene-based polymer, which includes a step of preparing a conjugated diene-based polymer by initiating and carrying out polymerization while continuously adding conjugated diene-based monomers to a reactor, and in which an emulsifier is dividedly added before the initiation of the polymerization and when a polymerization conversion rate of 31% to 80% is reached. More particularly, the present invention relates to: a method for preparing a conjugated diene-based polymer and a method for preparing a graft copolymer including the method for preparing a conjugated diene-based polymer, by which a total usage amount of an emulsifier can be reduced.

Method for preparing conjugated diene-based polymer and method for preparing graft copolymer comprising the same

A method of preparing a graft copolymer includes a step of performing coagulation by adding an acid coagulant to 100 parts by weight (based on solids) of graft copolymer latex prepared by graft-polymerizing an aromatic vinyl compound and a vinyl cyanide compound onto conjugated diene rubber latex; and a step of performing coagulation once more by adding a salt coagulant thereto. In a resulting graft copolymer, coagulation efficiency may be improved and the gloss of the prepared graft copolymer may be increased. In addition, since a b-value measured using a Hunter lab colorimeter and a b-value measured after being left at 250&#xb0; C. for 15 minutes are low, the graft copolymer may have excellent color characteristics. In addition, since heating loss is low and scorch time is long, the graft copolymer may have excellent processing characteristics.

Provided are a method of preparing a graft copolymer, a graft copolymer, and a thermoplastic resin molded article. The method of preparing a graft copolymer includes 1) adding a conjugated diene-based monomer and performing polymerization to prepare a conjugated diene-based polymer; and 2) adding the conjugated diene-based polymer, an aromatic vinyl monomer, and a vinyl cyan monomer and performing polymerization to prepare a graft copolymer, wherein an emulsifier having an APHA color value of 50 or less and a critical micelle concentration of 1 to 50 g/l is added, so that excellent polymerization stability, colorability, light resistance, and surface clarity are exhibited.

Method of preparing graft copolymer, graft copolymer, and thermoplastic resin molded article

A method of preparing a diene-based rubber latex, a method of preparing an ABS-based graft copolymer including the same, and a method of manufacturing an ABS-based injection-molded article include preparing an in-situ bimodal rubber latex, in which a small-diameter polymer and a large-diameter polymer are formed in a desired ratio, by controlling contents, addition time points, and types of reactants when a conjugated diene based monomer, a crosslinking agent with a long linear chain end, an emulsifier including a multimeric acid of an unsaturated fatty acid or a metal salt thereof, and a molecular weight regulator are polymerized.

Method of preparing diene-based rubber latex, method of preparing ABS-based graft copolymer and method of manufacturing injection-molded article

The present invention relates to a method of preparing an ABS-based resin composition and a method of manufacturing an ABS-based injection-molded article including the same. More particularly, the present invention provides a method of preparing an ABS-based resin composition using a multimeric acid of unsaturated fatty acid or a metal salt thereof, as an emulsifier, in a diene-based rubber latex polymerization step and an ABS-based graft polymerization step. In accordance with the present invention, when an ABS-based resin composition is prepared using a multimeric acid of unsaturated fatty acid or a metal salt thereof as an emulsifier, stability of polymerization is secured and surface characteristics, such as surface gloss or sharpness, of an ABS-based injection-molded article are improved.

Method of preparing ABS-based resin composition and method of manufacturing ABS-based injection-molded article including the same

The present invention relates to a method of preparing an ABS-based graft copolymer having improved impact strength and an ABS-based injection-molded article including the same. More particularly, the present invention provides an ABS-based copolymer resin having improved impact strength by optimizing structures of large-diameter diene-based rubber latex particles and a matrix structure between ABS-based copolymer particles and a SAN resin through introduction of a multimeric acid of an unsaturated fatty acid or a metal salt thereof as an emulsifier in a large-diameter diene-based rubber latex polymerization step and an ABS graft polymerization step.

Method of preparing ABS-based graft copolymer having improved impact strength and method of manufacturing ABS-based injection-molded article including the same

The present invention relates to a method for preparing large-sized diene-based rubber latex, and an acrylonitrile-butadiene-styrene graft copolymer comprising the same. More particularly, it relates to a method for preparing large-sized diene-based rubber latex having improved impact strength by controlling content and time of addition of a cross-linking agent and an emulsifier having critical micelle concentration (CMC) of 150 mg/L or less during preparation of the large-sized rubber latex, large-sized diene-based rubber latex prepared therefrom, and an acrylonitrile-butadiene-styrene graft copolymer and thermoplastic resin comprising the same.

Method for preparing diene-based rubber latex and acrylonitrile-butadiene-styrene graft copolymer comprising the same

The present invention relates to a thermoplastic polymer, a method of preparing the thermoplastic polymer, and a thermoplastic polymer composition including the thermoplastic polymer. More particularly, the present invention provides a thermoplastic polymer reducing the amount of gas generated in high-temperature extrusion and injection-molding processes to improve surface gloss and definition of a resin and provides superior latex stability when a chain-type fatty acid or a salt thereof having a specific branch group or functional group is included as an emulsifier during shell polymerization of a thermoplastic polymer including a core-shell structure, a method of preparing the thermoplastic polymer, and a thermoplastic polymer composition including the thermoplastic polymer.

Thermoplastic polymer, method of preparing thermoplastic polymer, and thermoplastic polymer composition including thermoplastic polymer

The present disclosure relates a method of preparing a rubbery polymer, a rubbery polymer, and a graft copolymer and thermoplastic resin composition including the rubbery polymer. In accordance with the present disclosure, a rubbery polymer, in which a large-diameter rubbery polymer and a small-diameter rubbery polymer are formed in a desired ratio by controlling the contents, addition time points, and types of a crosslinking agent, an emulsifier, and a molecular weight regulator when a conjugated diene monomer, the crosslinking agent, the molecular weight regulator, and the emulsifier are polymerized, and a graft copolymer and thermoplastic resin composition having excellent surface gloss and mechanical properties are provided.

Rubbery polymer, method of preparing the same, graft copolymer, and thermoplastic resin composition

The present invention relates to a method for preparing a diene-based rubber polymer having relatively low gel content and high swelling index while having high polymerization conversion rate, a diene-based rubber polymer prepared therefrom and an acrylonitrile-butadiene-styrene graft copolymer with a core-shell structure comprising the same as a core. Accordingly, the method for preparing a diene-based rubber polymer and the acrylonitrile-butadiene-styrene graft copolymer with a core-shell structure comprising the diene-based rubber polymer prepared therefrom can be easily applied to the industries requiring them, in particular, an impact reinforcing agent industry.

Method for preparing diene-based rubber polymer, diene-based rubber polymer prepared therefrom and acrylonitrile-butadiene-styrene graft copolymer of core-shell structure comprising the same

The present invention relates to a method for preparing an acrylonitrile-butadiene-styrene graft copolymer having improved impact strength, which comprises: a step of preparing diene-based rubber latex by adding an acrylate-based cross-linking agent (Step 1); and a step of inserting the same cross-linking agent with the acrylate-based cross-linking agent, an aromatic vinyl-based compound and a vinyl cyan-based compound to the diene-based rubber latex and then subjecting thereof to graft copolymerization (Step 2), an acrylonitrile-butadiene-styrene graft copolymer prepared by the method, and an acrylonitrile-butadiene-styrene thermoplastic resin comprising the same.

Method for preparing acrylonitrile-butadiene-styrene graft copolymer and acrylonitrile-butadiene-styrene thermoplastic resin comprising the same

The present invention relates to a method for preparing a diene-based rubber latex having improved impact strength, gloss and flexibility, diene-based rubber latex prepared therefrom, and an acrylonitrile-butadiene-styrene graft copolymer having improved impact strength and production yield while having reduced rubber solid content ratio by comprising the same.

Method for preparing large-size diene-based rubber latex and acrylonitrile-butadiene-styrene graft copolymer comprising the same

The present invention relates to a method for preparing an ABS graft copolymer. According to the present invention, provided is a method for preparing an ABS graft copolymer capable of improving surface gloss by inducing the formation of bimodal particles through the formation of existing ABS resin particles and ABS resin particles having a relatively small diameter.

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Daejeon, South Korea

Jae Min Suk