Lubrizol Advanced Materials, Inc.

Jacques P E J Horrion

Donald A Meltzer

Patrick E Mosier

Gilbert T Montague

The present invention discloses a semicrystalline, thermoplastic polyurethane which is comprised of the reaction product of (1) a hydrophobic polyol, (2) a polyisocyanate, and (3) a linear chain extender containing 5 carbon atoms or 7 to 12 carbon atoms; wherein the hydrophobic polyol has a number average molecular weight which is within the range of about 1,000 to about 4,000; wherein the semicrystalline, thermoplastic polyurethane has a weight average molecular weight which is within the range of 50,000 to 1,000,000; and wherein the semicrystalline, thermoplastic polyurethane has a melting point which is within the range of 80&#xb0; C. to 150&#xb0; C. This hydrophobic thermoplastic polyurethane offers a unique array of characteristics that are highly desirable for utilization in manufacturing a variety of products. For instance, it can be used in overmolding soft grips onto consumer products, in adhesives, and in protective coatings.

Hydrophobic thermoplastic polyurethane

The present invention relates to a soft, semicrystalline, thermoplastic elastomer composition which is comprised of (I) a hydrophobic thermoplastic block copolymer which is comprised of (I) the reaction product of (1) a hydrophobic polyol or polyamine, (2) a polyisocyanate or an aromatic dicarboxylic acid, and (3) a chain extender containing 2 to 20 carbon atoms, or the reaction product of (1) a hydrophobic polyol or polyamine, and (2) a carboxyl terminated telechelic polyamide sequence; wherein the hydrophobic polyol or polyamine has a number average molecular weight in the range of from 1,000 to 4,000 Daltons; wherein the hydrophobic thermoplastic block copolymer has a weight average molecular weight in the range of 50,000 to 1,000,000 Daltons; and (II) from 1 to 80 weight percent of a mineral oil, wherein the soft, semicrystalline, thermoplastic elastomer composition has a Shore A hardness which is within the range of 20 to 80.

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Tilff, Belgium

Jacques P E J Horrion