Rhone-poulenc-textile

Rhovyl

Jacques Menault

Pierre Chion

Henry Rodier

Georges Achard

Gilbert Anouilh

Jean-Paul Sacre

Roger Thouvenot

The present invention relates to filaments based on a mixture of atactic polyvinyl chloride and postchlorinated polyvinyl chloride, and also to the process for their production. The filaments according to the present invention possess a residual shrinkage in boiling water of less than 2%, a modulus of elasticity of more than 3 kN/mm.sup.2 and a shrinkage stress, after shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C., which is greater than or equal to 1.6.multidot.10.sup.-2 g/dtex. The filaments are obtained by spinning and stretching in a manner which is in itself known, then continuous stabilization under tension, at a temperature between 105.degree. and 125.degree. C., in the presence of steam under pressure, for 1 to 3 seconds, and then shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C. The filaments according to the invention can be used, by themselves or blended with other filaments, for the production of woven fabrics, knitted fabrics and non-woven articles.

Yarns and fibers with good properties, based on a mixture of polyvinyl

Yarns and fibers based on atactic polyvinyl chloride possess a residual shrinkage in boiling water of less than 3%, a modulus of elasticity which is greater than or equal to 2 kN/mm.sup.2, an orientation index of the crystalline zones which is greater than or equal to 70%, an orientation index of the mesomorphic zones which is greater than or equal to 8%, and an orientation index of the amorphous zones which is greater than or equal to 5%. They are obtained by spinning and stretching in a known manner, then stabilization under tension at a temperature between 105.degree. and 130.degree. C., in the presence of steam under pressure, for 1 to 3 seconds, and then shrinkage in an aqueous fluid medium at a temperature between 98.degree. and 130.degree. C.

Process for production of yarns and fibers with good properties, based

The invention relates to a process for continuous dyeing of filaments based on atactic polyvinyl chloride in the course of their production. The undrawn filaments are impregnated with a composition containing at least one plastosoluble dye while they have a density of between 1.3 and 1.4 g/cm.sup.3, are fixed continuously in the presence of steam under pressure at a temperature of between 100.degree. and 120.degree. C. for 2 to 20 seconds, are drawn in a known manner, are then fixed under tension in the presence of steam under pressure at a temperature of between 100.degree. and 130.degree. C. for 1 to 20 seconds, and are then oiled and shrunk in a known manner. Such a process permits quick dyeing, on an industrial scale, with good color fastness.

Process for disperse dyeing dry-spun atactic polyvinyl chloride-based

The present invention relates to a process for continuous dyeing of filaments based on atactic polyvinyl chloride in the course of production. It comprises, in succession, the phases of drawing, impregnation of the filaments by padding while, at the time of the impregnation, the filaments have a density of between 1.3 and 1.4 g/cm.sup.3 (the filament roving having a water content of 10 to 30% by weight), of stabilization under tension in the presence of steam under pressure at a temperature between 100.degree. and 130.degree. C. for 2 to 20 seconds, and then oiling and shrinking in a known manner. Dyeing carried out in this manner is quick and makes it possible to produce colors having good fastness.

The present invention relates to new homogeneous solutions based on polyvinyl chloride, which can be shaped, the process for their preparation and the shaped articles obtained. For a polymer concentration of 15 to 35%, the solutions have an effective viscosity of between 15 and 2,000 poises in a solvent medium which has, at ambient temperature, a solubility parameter of between 8 and 11 and a dielectric constant of between 5 and 25, and which gives, with polyvinyl chloride, a variation in effective viscosity with temperature, represented by a curve d.rho./d.theta., which passes through a maximum absolute value. They are obtained by heating a composition of polyvinyl chloride in the solvent medium to a temperature which is at least 25.degree. C. higher than the average temperature corresponding to the maximum of the curve d.rho./d.theta.. The yarns and fibres obtained, which have good properties, can be used by themselves or in a blend for the production of woven fabrics, knitted fabrics, non-woven structures and the like.

Solutions based on polyvinyl chloride, the process for their preparation

The present invention relates to new polymer solutions which make it possible to obtain shaped articles such as yarns and fibres, films, sheets and the like. These solutions consist of cellulose having a degree of polymerization of at least 200, polyvinyl chloride, dimethyl sulphoxide and formaldehyde, the weight ratio cellulose/polyvinyl chloride being 0.05 to 0.5, preferably 0.1 to 0.5, the ratio formaldehyde/cellulose being 0.2 to 2 and the total polymer concentration being 6 to 20%, preferably 10 to 18%. Such solutions are particularly suitable for the manufacture of filaments consisting of fibrils substantially orientated along the axis of the fibre and closely interlaced, the cellulose macromolecules being partially involved in a crystal lattice characteristic of cellulose II. The filaments possess valuable properties for textile use.

Solutions, which can be shaped, from mixtures of cellulose and polyvinyl

New polymer solutions, processes for producing such solutions, shaped articles made from these solutions, and process of making such articles, are disclosed. The polymer solutions contain cellulose having a degree of polymerization of at least 200, an acrylonitrile polymer, dimethylsulphoxide and formaldehyde. The weight ratio of cellulose/acrylonitrile polymer is 0.05 to 1, preferably 0.1 to 1, the weight ratio of formaldehyde/cellulose is 0.2 to 2, and the total concentration of polymer in the solution is 12 to 30% by weight, preferably 18 to 26% by weight. The solutions of the present invention are particularly suitable for the production of filaments consisting of fibrils orientated approximately along the axis of the fibre and closely interwoven, with the cellulose macromolecules being partially involved in a crystal lattice characteristic of cellulose II. The filaments possess valuable properties for use in textiles, such as, for instance, in garments.

Cellulose-acrylonitrile polymer solutions, articles, and methods of

New polymer solutions, processes for producing such solutions, shaped articles made from these solutions, and process of making such articles, are disclosed. The polymer solutions contain cellulose having a degree of polymerization of at least 200, an acrylonitrile polymer, dimethylsulphoxide and formaldehyde. The weight ratio of cellulose/acrylonitrile polymer is 0.05 to 1, preferably 0.1 to 1, the weight ratio of formaldehyde/cellulose is 0.2 to 2, and the total concentration of polymer in the solution is 12 to 30% by weight, preferably 18 to 26% by weight. The solutions of the present invention are particularly suitable for the production of filaments consisting of fibrils orientated approximately along the axis of the fibre and closely interwoven, with the cellulose macromolecules being partially involved in a crystal lattice characteristics of cellulose II. The filaments possess valuable properties for use in textiles, such as, for instance, in garments.

Cellulose-polyacrylonitrile-DMSO-formaldehyde solutions, articles, and

The present invention relates to new polymer solutions which make it possible to produce shaped articles, such as yarns and fibres, films, sheets and the like. These solutions consist of cellulose having a degree of polymerisation of at least 200, polyamide-imide, dimethyl sulphoxide and formaldehyde, with a weight ratio cellulose/polyamide-imide of 0.05 to 1, preferably 0.1 to 1, a ratio formaldehyde/cellulose of 0.2 to 2 and a total concentration of 6 to 25%, preferably 15 to 20%. These solutions are particularly suitable for the production of filaments which consist of fibrils substantially orientated along the axis of the fibre and closely intersecting, the cellulose macromolecules being partially involved in a crystal lattice characteristic of cellulose II. The filaments possess valuable properties for use in textiles.

Solutions, which can be shaped, from mixtures of cellulose and

The present invention relates to two-component acrylic fibres and yarns and their process of preparation. They consist of two copolymers based on acrylonitrile, in which the proportion of plasticizing comonomer differs by between 4 and 15% and which contain a total number of milliequivalents of acid of at least 50 per kg of polymer; they comprise a mixture of monolaminar, bilaminar and multilaminar strands; they possess a crimp, the direction of which depends on the heat and/or mechanical treatments to which they have been subjected, component B, which contains the smaller proportion of plasticizing comonomer, being located on the inside of the helix formed by the filaments, after treatment, without tension, at a temperature which is below about 110.degree. C. and at least equal to ambient temperature, and being located on the outside of the helix after treatment under tension or after heat treatment at a temperature above 110.degree. C., and the contraction and the crimp spacing varying from one strand to the next and along one and the same strand. The yarns and fibres according to the invention can be used in all the known textile-converting techniques, namely stretch-breaking, converting, carding and the like.

Two-component mixed acrylic fibres wherein acrylic components have

Spinnable, shapable solutions of celluose are disclosed, wherein the solutions contain native cellulose in a mixture of dimethylsulphoxide (DMSO) and formaldehyde. The cellulose has a degree of polymerization (DP) of at least 400 and a concentration in the mixture of at least 6% by weight, based on the volume of DSMO. The formaldehyde/cellulose weight ratio is 0.2 to 2, and the solutions have a water content no greater than 5,000 ppm by weight. The solutions are obtained by dissolving the cellulose in a mixture of DMSO and formaldehyde, at a formaldehyde/cellulose weight ratio of at least 1, and thereafter the formaldehyde/cellulose weight ratio is reduced, if necessary, to the final level of about 0.2 to 2. The solutions can be converted into films, membranes, sponges, varnishes, paints, and especially into filaments, with the filaments being generally similar in properties to regenerated cellulose filaments.

Growing community of inventors

Charbonnieres-les-Bains, France

Jacques Menault