Institut Francais Du Pe'trole

Institute Francais Du Petrole

Jacques Lallement

Maurice Born

Guy Parc

Bruno Delfort

Pierre Marchand

Bertrand Daoudal

Nicole Thevenin

Jean-Claude Hipeaux

Lucienne Briquet

Gabriel De Gaudemaris

Francoise Dixmier

Monique Prigent

Bertrand Daqudal

Colloidal products containing calcium barium and/or magnesium also

New sulfonated bismuth compounds and the preparation thereof are described. These new compounds can be represented by the following general formulae: ##STR1## where R.sub.1 represents a monovalent linear or branched aliphatic hydrocarbonaceous radical containing 8 to 36 atoms of carbon, and R.sub.2 represents an atom of hydrogen or a monovalent linear or branched aliphatic hydrocarbonaceous radical containing 8 to 36 atoms of carbon. These compounds, which possess surface-active and wear-fighting properties, are used as fuel additives. They can also serve as starting materials in the manufacture of overbased colloidal products usable as lubricant additives by carbonation of at least one calcium, barium, or magnesium oxide or hydroxide, the carbonate formed being kept as a colloidal dispersion in an organic medium by using at least one of the sulfonated bismuth compounds (I) and (II).

Sulfonated bismuth compounds

Colloidal products according to the invention are obtained by a method comprising a step (a) providing a colloidal product containing at least one alkaline earth metal carbonate in micelle form, optionally reacted with at least one compound selected from alkylsulphonic acids and alkylarylsulphonic acids and salts thereof and long chain aliphatic carboxylic acids and salts thereof such as to modify a proportion of up to 70% of the basicity reserve of the original colloidal product and a step (b) in which the residual basicity reserve is neutralized by at least one acid containing at least one element selected from boron, phosphorus and sulphur. These colloidal products can be used as wear resistance and extreme pressure additives in lubricants.

Colloidal products containing calcium and/or magnesium, as well as boron

Colloidal products are described which contain an element selected from sulphur, phosphorus and possibly boron, as well as an element chosen from metal alkalis, alkaline earth metals and zinc, micellized in at least one detergent agent. They can be obtained in micelle form by reaction of at least one mineral acid or organic acid, containing sulphur and/or phosphorus and possibly an acid containing boron, these acids being directly introduced or formed in situ with at least one basic derivative containing a alkali metal and/or an alkaline earth metal and/or zinc, in the presence of at least one surface active agent. The colloidal products can be used as wear resistance and extreme pressure additives for lubricants.

Colloidal products containing sulfur and/or phosphorus and/or boron,

Colloidal products containing calcium and/or magnesium plus sulfur and nitrogen are obtained by at least partial neutralization of the basicity reserve of at least one overbasic sulfonate charged with calcium carbonate and/or with magnesium carbonate dispersed within micelles. The neutralization is by means of at least one functional dicarboxylic acid of the formula: ##STR1## where each symbol a is a whole number from 1 to 8, x and z are each a number from 1 to 4, y is a whole number from 0 to 4 and n is 1 or 2. These products can be used as additives in lubricating oils.

Colloidal products containing calcium and/or magnesium, as well as

A description is given of colloidal sulphur products, their preparation and their use as additives in lubricating oils. These products result from the reaction on a superbasic detergent additive, optionally modified by reaction with a boron derivative, of a 'small size' sulphur carboxylic acid complying with the general formula

Surbased colloidal product containing organic sulfur and their use as

A composition of a thiophosphoretted additive obtained by reacting a sodium or a calcium sulfonate surbasified by sodium or calcium carbonate, showing 0.9 to 10 basic equivalents per kilogram, with a phosphorus sulfide used in such proportion that he ratio of molar phosphorus to the basic equivalent of the surbasified sulfonate ranges from 0.002 to 0.15; and contacting resultant reaction product of the surbasified sulfonate and the phosphorus sulfide with at least one active hydrogen compound which is water, an alcohol, a phenol, a carboxylic acid, an ester-acid, a mineral acid, a mineral base, an amine, an amide or a mercaptan.

New thiophosphoretted compounds, their preparation and their use as

Described are polysulfurized olefin compositions defined as being prepared by reaction of sulfur monochloride and/or dichloride with at least one monoolefin with 6 to 12 carbon atoms to form an addition product (or 'adduct'), then by reaction of said adduct with a mercaptate or mercaptate-polysulfide of an alkaline metal or ammonium, itself obtained, for example, by reaction of a mercaptan with an alkaline hydroxide or with ammonia then, if need be, with sulfur, preferably in an alcoholic medium. These polysulfurized olefin compositions can be used as extreme-pressure additives in gearing oils or in oils for use in metal-working.

Polysulfurized olefin compositions, their preparation and use as

A new class of antiwear and extreme-pressure additives consisting of thiophosphoretted compounds obtained by reactin gphosphorus sulfieds, especially phosphorus decasulfide P.sub.4 S.sub.10, with surbasic detergent additives, is described. The reaction product can be optionally treated by at least one active hydrogen compound: water, alcohol, phenol, acid, ammonia, amine, amide and/or mercaptan.

Thiophosphoretted compounds, their preparation and their use as

Polysulphurized olefin compositions used as additives for gear oils, cutting oils, and as sulphurizing agents in organic media are obtained by a process comprising:

Polysulphurized olefin compositions, their preparation and their use as

The invention relates to compounds of the metal dihydrocarbyl-dithiophosphyl-dithiophosphate type, their manufacture and use. These compounds can be represented by the general formula: ##STR1## wherein R is a monovalent substantially hydrocarbon-containing radical of 1 to 30 carbon atoms, X and Y are each a hydrogen atom or a monovalent substantially hydrocarbon-containing radical of 1 to 30 carbon atoms, M is a metal selected from zinc, cadmium, lead and antimony or an oxygen--and/or sulfur--containing molybdenum complex, and n is the valence of said metal M. The compounds according to the invention can be used as additives for lubricants wherein they act as a very efficient wear preventive.

Metal dihydrocarbyl-dithiophosphyl-dithiophosphates their manufacture

Compositions of olefin polysulfides having an increased solubility in mineral oils and in synthetic oils, particularly of the hydrogenated polyalphaolefin (P.A.O.) type, are disclosed. They are prepared more particularly by reacting a sulfur monochloride with a monoolefin (e.g. isobutene) so as to form an addition product, called an adduct, which is then reacted with an alkali metal or ammonium polysulfide, obtained, for example, by reacting a mercaptan with an alkali hydroxide or ammonia in the presence of elemental sulfur. These compositions of olefin polysulfides can be used as extreme-pressure additives in gear-oils or in metal-working oils.

Olefin polysulfide compositions their manufacture and use as additives

The invention relates to compounds of the metal dihydrocarbyl-dithiophosphyl-dithiophosphate type, their manufacture and use. These compounds can be represented by the general formula: ##STR1## wherein R is a monovalent substantially hydrocarbon-containing radical of 1 to 30 carbon atoms, X and Y are each a hydrogen atom or a monovalent substantially hydrocarbon-containing radical of 1 to 30 carbon atoms, M is a metal selected from zinc, cadmium, lead and antimony or an oxygen- and/or sulfur-containing molybdenum complex, and n is the valence of said metal M. The compounds according to the invention can be used as additives for lubricants wherein they act as a very efficient wear preventive.

New superbasic detergent additives are manufactured in two steps. The first step comprises the reaction of a sulfonic acid with an excess of oxide or hydroxide of lithium or group II A metal. The second step consists of carbonating the oxide or hydroxide in excess. The manufacture is conducted in the presence of a polyalkenylsuccinimide-amine salt.

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Aubervilliers, France

Jacques Lallement