Dow Global Technolgoies LLC

Dow Quimica Mexicana S.a. De C.v.

Jacquelyn A Degroot

Selim Bensason

Fabricio Arteaga Larios

Vivek Kalihari

Gert Johannes Claasen

Mehmet Demirors

Rajen M Patel

Barbara Bonavoglia

Teresa Plumley Karjala

Mridula Babli Kapur

Nicolas Cardoso Mazzola

Yijian Lin

David T Gillespie

Andy Cheng Chang

Sanjib Biswas

Carlos E Ruiz

Lisa S Madenjian

Jose V Saavedra

Jason C Brodil

Kate R Brown

Aleksandar Stoiljkovic

Wu Aik Yee

Chuan Yar Lai

Yutaka Maehara

Adriana Velasquez

Thor Gudmundsson

Arnaldo Lorenzo

Thor E Gardarsson

Pamela Y Smith

Arnaldo T Lorenzo

The present disclosure provides for a heat-shrinkable, biaxially stretched, multilayer thermoplastic film that includes at least a puncture resistant layer. The puncture resistant layer is formed with a polyethylene based plastomer having a density of 0.890 g/cmto 0.910 g/cmas measured in accordance with ASTM D-792, and a melt index (MI) as measured by ASTM D-1238 at 190° C./2.16 kg from 0.20 g/10 minutes to 1.5 g/10 minutes. The polyethylene based plastomer has a logMof an upper 25% of a GPC quadrant having a value of 5.1 to 5.7, an intermediate molecular weight distribution (Mw/Mn) of 2.5 to 3, a Mz/Mw value of 2 to 2.5, a Comonomer Distribution Constant value from 60 to 400 and a single SCBD peak between 40-85° C. with a mass fraction of less than 3% above 85° C. as determined by CEF, and a ZSVR value from 1.0 to 5.5. The multilayer thermoplastic film is biaxially stretched at a temperature of 60° C. to 120° C. with a blow-up ratio from 2:1 to 10:1.

Multilayer thermoplastic film with improved puncture resistance performance

A uniaxially-oriented ethylene-based polymeric film having at least one layer comprising at least 65 wt. %, based on total amount of materials present in the at least one layer, of a linear low density polyethylene which exhibits each of the following properties: a CDBI of at least 60%; a melt index, I2, measured according to ASTM D 1238 (2.16 kg @190&#xb0; C.), of 1.8 g/10 min to 10 g/10 min; a density of from 0.910 g/cc to 0.940 g/cc; and a Mw/Mn of less than 3.0.

Uniaxially-oriented polymeric films, and articles made therefrom

Disclosed herein is a film comprising a polymer blend, the polymer blend comprising a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190&#xb0; C. Disclosed herein too is a method of manufacturing a film comprising blending a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole to form a polymer blend; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190&#xb0; C.; and forming the polymer blend into a film.

Polyolefin based elastic compositions, methods of manufacturing thereof and articles comprising the same

Disclosed herein is a multilayer laminate comprising a film comprising an ethylene-based elastomer; a first non-woven layer in contact with a first surface of the film; and a second non-woven layer in contact with a second surface of the film; wherein the second surface of the film is opposedly disposed to the first surface of the film; wherein at least one of the first non-woven layer or the second non-woven layer comprises a non-woven web; and wherein the non-woven web is formed from a bicomponent fiber having a first component comprising an polyethylene-based polymer and a second component comprising a polymer having a melting point that is higher than the polyethylene-based polymer, wherein at least a portion of a surface of the bicomponent fiber comprises the first component.

Elastic laminates, method of manufacture thereof and articles comprising the same

A multilayer film including a core layer and two skin layers, wherein the core layer is positioned between the two skin layers, wherein the core layer includes a polyethylene composition including a high density polyethylene having a density of 0.930-0.965 g/cc and a melt index of 0.7-10.0 g/10 min, and wherein each skin layer independently includes a polypropylene composition including greater than 50 wt. %, based on the total weight of the polypropylene composition, of a propylene-based polymer.

Multilayer films, and articles made therefrom

A stretch-modified elastomeric multilayer film comprising a core layer comprising a first ethylene-&#x3b1;-olefin block copolymer, wherein the first ethylene-&#x3b1;-olefin block copolymer comprises at least 50 mol. % ethylene, has a melt index (I2) from 0.5 g/10 min to 5 g/10 min, and has a density of 0.850 g/cc to 0.890 g/cc, and at least one outer layer independently comprising a second ethylene-&#x3b1;-olefin block copolymer and from 2.5 to 30 wt. % of an antiblock agent, wherein the second ethylene-&#x3b1;-olefin block copolymer comprises at least 50 mol. % ethylene, has a melt index (I2) from 0.5 g/10 min to 25 g/10 min, and has a density of 0.850 g/cc to 0.890 g/cc, wherein the density of the first ethylene-&#x3b1;-olefin block copolymer is equal to or greater than the density of the second ethylene-&#x3b1;-olefin block copolymer.

Polyolefin-based elastic film structures, laminates and methods thereof

Disclosed herein is a cast film comprising a polyethylene composition comprising the reaction product of ethylene and optionally one or more alpha-olefin comonomers, wherein said polyethylene composition is characterized by the following properties: a melt index, I2, measured according to ASTM D1238 (2.16 kg, 190&#xb0; C.), of from 1 to 20 g/10 min; a density (measured according to ASTM D792) of from 0.935 to 0.970 g/cm3; a melt flow ratio, I/I, wherein Iis measured according to ASTM D1238 (10 kg, 190&#xb0; C.) of from 5.5 to 7.0; a molecular weight distribution (Mw/Mn) of from 2.2 to 3.5; and a vinyl unsaturation of greater than 0.12 vinyls per one thousand carbon atoms present in the backbone of the composition.

Cast films, and articles made therefrom

A multilayer polyethylene film comprising a core layer, a first outer layer, and a second outer layer, wherein the core layer is positioned between the first outer layer and the second outer layer, the core layer comprises a linear low density polyethylene and, optionally, a first low density polyethylene resin, and the first outer layer and the second outer layer independently comprise a polyethylene resin and, optionally, a second low density polyethylene resin, wherein the density of the linear low density polyethylene is less than the density of the polyethylene resin.

Mutilayer polyethylene films, and articles made therefrom

The instant invention provides bi-component fibers and fabrics made therefrom. The bi-component fiber according to the present invention comprises: (a) from 5 to 95 percent by weight of a first component comprising at least one or more first polymers, based on the total weight of the bi-component fiber; (b) from 5 to 95 percent by weight of a second component comprising at least an ethylene-based polymer composition, based on the total weight of the bicomponent fiber, wherein said ethylene-based polymer composition comprises; (i) less than or equal to 100 percent by weight of the units derived from ethylene; and (ii) less than 30 percent by weight of units derived from one or more &#x3b1;-olefin comonomers; wherein said ethylene-based polymer composition is characterized by having a Comonomer Distribution Constant in the range of from greater than from 100 to 400, a vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range from 1 to less than 2; a density in the range of 0.920 to 0.970 g/cm, a melt index (I) in the range of from 10 to 40 g/10 minutes, a molecular weight distribution (M/M) in the range of from 1.8 to 3.0, and a molecular weight distribution (M/M) in the range of from less than 2; and wherein said bi-component fiber has a denier per filament in the range of from 0.5 to 10 g/9000 m.

Bi-component fiber and fabrics made therefrom

The present disclosure is directed to a fiber that is composed of a polymeric blend including (i) 95 wt % to 99 wt % of a high density ethylene-based polymer having a Mw/Mn from 2.0 to 3.0 and (ii) from 5 wt % to 1 wt % of a low density ethylene-based polymer having a melt index from 5 g/10 min to 15 g/10 min. The fiber has a density from 1 denier to 2 denier and a 3% secant modulus from 8.5 g/denier to 20 g/denier.

Fiber comprising polyethylene blend

The instant invention provides nonwoven fabrics and staple or binder fibers prepared from an ethylene-based polymer having a Comonomer Distribution Constant in the range of from greater than from 100 to 400, a vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition; a zero shear viscosity ratio (ZSVR) in the range from 1 to less than 2; a density in the range of 0.930 to 0.970 g/cm3, a melt index (12) in the range of from 15 to 30 or from 10 to 50 g/10 minutes, a molecular weight distribution (Mw/Mn) in the range of from 2 to 3.5, and a molecular weight distribution (Mz/Mw) in the range of from less than 2.

Growing community of inventors

Sugar Land, TX, United States of America

Jacquelyn A Degroot