Standard Oil Company (indiana)

Battelle Memorial Institute

Jack R Knox

Edward E Paschke

Robert S Whitmore, Jr

Michael M Schwartz

Vincent D McGinnis

Frank J Jelinek

The present invention is directed to improving thermoplastic and cross-linked polymeric networks. The inventive method comprises forming the polymeric network under gravitational conditions comprising from about 10.sup.-6 to about 10.sup.-2 g. Three modes of energy transfer have been recognized, inter alia, conduction, convection, and radiation. Polymeric networks formed under microgravity conditions (defined herein as gravitational conditions comprising from about 10.sup.-6 to about 10.sup.-2 g) do not obviate conduction and radiation modes of energy transfer. Convection energy transfer, however, is gravity dependent. Thus, convection currents can be suppressed in thermoplastic and cross-linked polymeric networks during network formation by forming the network under microgravity conditions. Suppression of convection currents reduces the incidences of voids in solvent cast thermoplastic polymeric membranes, which forms yet another aspect of the present invention. Particulate-filled thermoplastic and cross-linked polymeric networks will exhibit a more homogeneous distribution of particulates in the network by forming the network under microgravity conditions also, which forms yet a further aspect of the present invention.

Microgravity formation of polymeric networks

Compositions comprising a blend of a polyarylate and a poly(methylenebenzoate) wherein said polyarylate is derived from a dihydric phenol and an aromatic dicarboxylic acid, said poly(methylenebenzoate) comprises poly(p-methylenebenzoate), poly(m-methylenebenzoate) and mixtures thereof. These compositions have improved processability relative to the polyarylate, have improved weatherability relative to the poly(methylenebenzoate) and are transparent.

Poly (p- and m-methylenebenzoate) blends with polyarylates

Process and composition relating to novel, fine denier, homogeneous, curly synthetic fibers are set out. The process comprises orientation of a fiber-forming, slowly crystallizing, synthetic polymer composition in fiber form, generally after melt spinning, such orientation resulting from application of a longitudinal tensile force to said fiber above the crystallization temperature range and maintaining it at least through such range during a controlled, substantially axially symmetric cooling of the fiber. The novel fibers have a substantially axially symmetric, residual tensile force differential between their outer sheaths and inner portions, are generally of helical configuration and can exhibit more than about fifteen turns per linear centimeter.

Process for homogeneous curly synthetic polymer fibers

Process for producing homogeneous curly synthetic polymer fibers

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Naperville, IL, United States of America

Jack R Knox