Arkema France

Atofina

Trinseo Europe Gmbh

Arkema Inc.

Jack J Reilly

Manuel A Garcia-Leiner

Mark A Aubart

David Shin-Ren Liu

Brian M Cromer

James Bradley

Jean Kryven

Florence Mehlmann

Ryan R Dirkx

Paul J Keating

Gary A Hall

Douglas R Dillon

Shi-Jun Yang

Jana Lamberson

Cedric Roy

Richard M Abel

Elizabeth E Grimes

Thomas DeMain

Sylvain Queruel

Leslie A Cohen

An acrylic alloy composition that can be 3-D printed by a material extrusion additive manufacturing process, an acrylic filament that has a very uniform diameter useful in the extrusion additive manufacturing process, acrylic articles made from the acrylic alloy composition by a material extrusion additive process, and a material extrusion additive manufacturing process for producing the acrylic articles. The acrylic alloy composition is an alloy of an acrylic polymer, and a low melt viscosity polymer, such as polylactic acid. The alloy may optionally be impact modified, preferably with hard core core-shell impact modifiers.

Dimensionally stable acrylic alloy for 3-d printing

A polymeric (meth) acrylic composition including polymeric silicone particles and optionally polymeric (meth)acrylic particles. The polymeric silicone particles have a weight average particle diameter between 1 μm and 10 μm and the optional polymeric (meth)acrylic particles have a weight average particle diameter between 20 μm and 100 μm. The polymeric (meth) acrylic composition may be in the form of a masterbatch. A process for making the (meth)acrylic composition including polymeric silicone particles and polymeric (meth)acrylic particles from a polymeric (meth) acrylic masterbatch composition including polymeric silicone particles and optionally polymeric (meth)acrylic particles is provided.

(Meth)acrylic polymer composition comprising particles, its method of preparation and its use as masterbatch

The invention relates to an acrylic light diffusing material providing spectral uniformity over the visible light range, defined herein as from 400 to 800 nm. The light diffusing material provides a uniform light transmission for light engines having two or more light sources with different spectral emission peaks. Due to its high hiding performance, the light diffusing material of the invention is especially useful with LED point light sources. The diffusing material contains a transparent polymer matrix and one or more types of diffusing materials, providing an optimal balance of spectral uniformity, light transmission, diffusion, and hiding performance.

High spectral uniformity acrylic light diffusion material

The invention relates to an acrylic alloy composition that can be 3-D printed by a material extrusion additive manufacturing process, to an acrylic filament that has a very uniform diameter useful in the extrusion additive manufacturing process, to acrylic articles made from the acrylic alloy composition by a material extrusion additive process, and to a material extrusion additive manufacturing process for producing the acrylic articles. The acrylic alloy composition is an alloy of an acrylic polymer, and a low melt viscosity polymer, such as polylactic acid. The alloy may optionally be impact modified, preferably with hard core core-shell impact modifiers.

Dimensionally stable acrylic alloy for 3-D printing

The invention relates to a translucent, white, light-diffusing thermoplastic composition containing both white pigment and refractive index-matched particles. The blend of pigment and particles provides a synergistic effect, resulting in a very high luminous transmission and good diffusion properties.

White light diffusing thermoplastic composition

The invention relates to multi-layer composites for use as a screen, having at least three layers, with an inner diffusing layer and at least one substrate layer on either side. The diffusing layer contains small particles having a narrow particle size distribution that are refractive-index mismatched with the polymer matrix. The multi-layer acrylic composition is useful as a projection screen.

Multi-layer screen composites

The present invention is directed to an article of manufacture having differently colored layers which, when viewed from the edge, change color depending on the angle of view. The articles can be used in decorative or eye-catching displays suitable for displaying information or promoting objects.

Article displaying edgewise, angular multi-chromatic characteristics

The invention relates to a novel acrylic impact sheet having bullet-resistant properties. The bullet-resistant sheet is composed of a copolymer of methyl methacrylate and a Calkyl methacrylate, plus impact modifiers that are refractive index matched or mismatched with the polymer matrix. The sheet provides very good bullet resisting performance, with better performance at the same thickness as current products, or the same performance at less thickness, thereby providing a product having better properties and/or less weight. The reduced weight of a bullet resistant acrylic sheet formulation will provide reduced raw material, transportation, and construction costs. Bullet resistant transparent glazing is an especially useful application for the invention.

Transparent bullet-resistant acrylic sheet

Disclosed is a polished translucent co-extruded sheet having utility as a light diffusing protective cover or sign face for light emitting diode (LED) light sources and other purposes. The sheet is comprised of (a) a particle layer containing particles having a mean particle size of about 4 to 100 microns and having a particle size distribution of between 1-110 microns, at a loading of 1 to 60% melt blended with a thermoplastic matrix, wherein the particle and matrix have refractive indices that differ by greater than 0.001 units of each other when measured in conformance with ASTM D 542; and (b) at least one substrate layer comprised of thermoplastic compositions, wherein the substrates have a refractive index within 0.2 units of the refractive index of the particle layer matrix when measured in conformance with ASTM D 542.

Light emitting diode signs and translucent plastic sheets used therein

Disclosed is a mar resistant transparent co-extruded sheet which is comprised of (a) a cap layer containing particles having a mean particle size of about 1 to 60 microns wherein 90% of the particles are less than 70 microns, at a loading of 0.1 to 18%, melt blended with an acrylic matrix, wherein the particle and matrix have refractive indices within 0.020 units when measured in conformance with ASTM D 542; and (b) a clear substrate layer comprised of an acrylic composition, wherein the substrate has a refractive index within 0.020 units of the refractive index of the cap layer matrix when measured in conformance with ASTM D 542; wherein the co-extruded product has (i) a luminous transmission (CIE tristimulus Y value) of greater than 90% when measuring spectral transmission data using a Macbeth&#xae; Color-Eye&#xae; 7000 spectrophotometer (Division of Kollmorgen Instruments Corporation), Illuminant C, and the 2&#xb0; standard observer, and calculating the CIE tristimulus Y value in conformance with ASTM E 308, and (ii) a haze of less than 16% when measured in conformance with ASTM D 1003, and at least one of (iii) or (iv), (iii) a 60&#xb0; gloss value measured on a 0.118 inch thick sample within 15 units of the 60&#xb0; gloss value measured on a 0.080 inch thick sample when measured using a micro-TRI-gloss meter made by BYK-Gardner GmbH in conformance with ASTM D 523 using a black felt backing, and (iv) a change in haze as measured in conformance with ASTM D 1044, after 500 revolutions using a 500 g load and CS10F wheel, of less than 25%.

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Blue Bell, PA, United States of America

Jack J Reilly